ChemicalBook--->CAS DataBase List--->621-64-7

621-64-7

621-64-7 Structure

621-64-7 Structure
IdentificationBack Directory
[Name]

N-NITROSODI-N-PROPYLAMINE
[CAS]

621-64-7
[Synonyms]

DPNA
NSC 133
rcrawastenumberu111
DIPROPYLNITROSAMINE
nitrosodipropylamin
Nitrosodipropylamine
nitrous dipropylamide
Di-n-prpylnitrosamine
N-NITROSODIPROPYLAMINE
Rcra waste number U111
n-nitroso-dipropylamin
dipropyl-nitroso-amine
Di-N-propylnitrosamine
Di-n-propylnitrosoamine
N-Nitroso-N-propylamine
N,N-Dipropylnitrosamine
Nitrosodi-n-propylamine
N-Nitrosodipropylamine>
n-nitroso-n-di-propylamin
N,N-dipropylnitrous amide
Dipropylamine, N-nitroso-
N-NITROSODI-N-PROPYLAMINE
N-Nitrosodi-n-propylanime
N-nitroso-N-dipropylamine
n,n-di-n-propylnitrosamine
2-Oxo-1,1-dipropylhydrazine
N,N-Dipropyl-N-nitrosoamine
N-Nitroso-N-di-n-propylaMine
Propylamine, N-nitroso-N-di-
n-nitroso-n-propyl-propanamin
n-nitroso-n-propyl-1-propanamin
Propanamine, N-nitroso-N-propyl-
N-Nitroso-n-propyl-1-propanamine
N-Nitrosodipropylamine (1mg/1ml)
N-Propanamine,N-propyl-N-nitroso-
1-Propanamine, N-nitorso-N-propyl-
1-Propanamine, N-nitroso-N-propyl-
n-nitrosodi-n-propylamine solution
N-NITROSODI-N-PROPYLAMINE, 100MG, NEAT
N-Nitrosodi-n-propylamine 1g [621-64-7]
N-Nitrosodi-n-propylamine @5.0 mg/mL in MeOH
N-Nitrosodi-n-propylamineSolution,1mg/L,25ml
N-Nitrosodi-n-propylamineSolution,100mg/L,1ml
N-Nitrosodi-n-propylamineSolution,5,000mg/L,1ml
N-Nitrosodi-n-propylamineSolution,1,000mg/L,1ml
N-NITROSODI-N-PROPYLAMINE, 1X1ML, MEOH 5 000UG/ML
N-Nitrosodi-N-propylamine? N-nitrosodipropylamine
N-Nitrosodi-n-propylamine@2.5 mg/mL in Dichloromethane
N-Nitrosodi-n-propylamine@100 μg/mL in Dichloromethane
N-Nitroso-di-n-propylamine Solution in Methanol, 100μg/mL
Dipropylnitrosamine N-Nitrosodi-n-propylamine N-nitroso-n-propyl-1-propanamine
[EINECS(EC#)]

210-698-0
[Molecular Formula]

C6H14N2O
[MDL Number]

MFCD00013891
[MOL File]

621-64-7.mol
[Molecular Weight]

130.19
Chemical PropertiesBack Directory
[Appearance]

N-nitrosodi-N-propylamine is a yellow liquid.
[Boiling point ]

113 °C / 40mmHg
[density ]

0.92
[refractive index ]

1.4468 (589.3 nm 20℃)
[Fp ]

10 °C
[storage temp. ]

2-8°C
[solubility ]

Very soluble in ethanol and ether (quoted, Keith and Walters, 1992)
[form ]

neat
[pka]

-3.18±0.70(Predicted)
[color ]

Yellow to gold colored liquid
[Water Solubility ]

9,900 mg/L at 25 °C (Mirvish et al., 1976)
[IARC]

2B (Vol. 17, Sup 7) 1987
[EPA Substance Registry System]

N-Nitrosodi-n-propylamine (621-64-7)
Hazard InformationBack Directory
[Chemical Properties]

Yellow Oil
[General Description]

Clear to pale yellow liquid.
[Reactivity Profile]

N-NITROSODI-N-PROPYLAMINE is a nitrated amine derivative. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: Toxic.
[Fire Hazard]

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.
[Potential Exposure]

N-nitrosodi-N-propylamine is used in the manufacture of plastics, resins, rubber, and synthetic textiles. There is no evidence that N-nitrosodi-N-propylamine exists naturally in soil, air, food, or water. Small quantities of N-nitrosodi-N-propylamine are inadvertently produced during some manufacturing processes; as an impurity in some commercially available dinitroaniline based weed killers, and during the manufacture of some rubber products. However, according to Sax, some similar N-nitroso compounds are formed in the environment and absorbed from precursors in food, water, or air; from tobacco; and from naturally occurring compounds.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard Class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Sensitive to UV light.
[Waste Disposal]

N-Nitrosodi-N-propylamine may be destroyed by high temperature incineration in an incinerator equipped with an nitrogen oxide scrubber. Chemical treatment methods may also be used to destroy N-nitrosodi-N-propylamine. These methods involve (a) denitrosation by reaction with 3% hydrobromic acid in glacial acetic acid; (b) oxidation by reaction with potassium permanganate-sulfuric acid; or (c) extraction of the nitrosamine from the waste using dichloromethane and subsequent reaction with triethyloxonium tetrafluoroborate (TOEF). Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
[Uses]

N-Nitrosodi-n-propylamine is used in small quantities in laboratory research. It has no known commercial use (IARC 1978, ATSDR 1989, HSDB 2009).
[Uses]

Research chemical; impurity in herbicides treflan, isopropalin, and trifluralin; contaminant in wastewater from chemical factories and production of cheese and brandy and other liquors. N-nitrosamines are frequently produced during rubber processing and may be airborne in the workplace.
[Definition]

ChEBI: N-Nitrosodi-n-propylamine is a nitroso compound.
[Carcinogenicity]

N-Nitrosodi-n-propylamine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
[Environmental Fate]

Chemical/Physical. N-Nitroso-n-propylamine will not hydrolyze because it does not contain a hydrolyzable functional group (Kollig, 1993).
At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 24, 13, 7.4, and 4.0 mg/g, respectively (Dobbs and Cohen, 1980).
Safety DataBack Directory
[Hazard Codes ]

T,N,F
[Risk Statements ]

45-22-51/53-39/23/24/25-23/24/25-11
[Safety Statements ]

53-45-61-36/37-16
[RIDADR ]

2810
[WGK Germany ]

3
[RTECS ]

JL9700000
[HS Code ]

2921.29.0055
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Safety Profile]

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic data. Moderately toxic by ingestion and subcutaneous routes. An experimental teratogen. Human mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITROSAMINES.
[Hazardous Substances Data]

621-64-7(Hazardous Substances Data)
[Toxicity]

Acute oral LD50 for rats 480 mg/kg (quoted, RTECS, 1985).
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