| Identification | Back Directory | [Name]
TRIMETHYL CIS,CIS-1,3,5-CYCLOHEXANETRICARBOXYLATE | [CAS]
6998-83-0 | [Synonyms]
TRIMETHYL CIS-1,3,5-CYCLOHEXANETRICARBOXYLATE
Trimethylcis-1,3,5-cyclohexanetricarboxylate,98%
1,3,5-Cyclohexanetricarboxylic acid trimethyl est
TRIMETHYL CIS,CIS-1,3,5-CYCLOHEXANETRICARBOXYLATE
trimethyl cis,cis-cyclohexane-1,3,5-tricarboxylate
1,3,5-Cyclohexanetricarboxylicacid, 1,3,5-trimethyl ester, (1a,3a,5a)-
1,3,5-Cyclohexanetricarboxylic acid, 1,3,5-trimethyl ester, (1α,3α,5α)-
(1alpha,3alpha,5alpha)-1,3,5-Cyclohexanetricarboxylic acid trimethyl ester | [Molecular Formula]
C12H18O6 | [MDL Number]
MFCD00134230 | [MOL File]
6998-83-0.mol | [Molecular Weight]
258.27 |
| Hazard Information | Back Directory | [Uses]
Used as Organic Building Blocks. | [Synthesis]
A mixture of 7.50 g (3.57 mmol) of trimesic acid, 1.0 g of 5% rhodium on alumina, and 150 mL of water was hydrogenated at 70 °C and 50 psi of H2. Uptake was complete in 48 h, and the filtrate was concentrated to give a white solid. Recrystallization from a 1:4 mixture of ethanol/toluene gave 4.50 g (20.8 mmol) of the Trimethyl cis,cis-1,3,5-cyclohexanetricarboxylate. Yield 58%. 1H NMR(500 MHz, CD3OD): δ 12.22 (br, 3H; 3COOH), 2.32 (tt, J= 3, 13 Hz; 3H, 3Hax′), 2.04 (d, J= 13 Hz, 3H; 3Heq), 1.19 (q, J= 13 Hz, 3H; 3Hax).
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Energy Chemical
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http://www.energy-chemical.com |
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SIGMA-RBI
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www.sigma-aldrich.com |
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