| Identification | Back Directory | [Name]
BIS(3,5-DIMETHYLPHENYL)PHOSPHINE | [CAS]
71360-06-0 | [Synonyms]
Bis(3,5-dimethyL
98% [(CH3)2C6H3]2PH
Bis(3,5-dimethylphenyl)
bis(3,5-dimethylphenyl)phosphane
Bis(3,5-dimethylphenyi)phosphine
BIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Phosphine, bis(3,5-dimethylphenyl)-
Bis(3,5-dimethylphenyl)phosphine,99%
Bis(3,5-dimethylphenyl)phosphine, 98% (10wt% in hexanes)
Bis(3,5-diMethylphenyl)phosphine, 98% (10% solution in hexanes) | [Molecular Formula]
C16H19P | [MDL Number]
MFCD01074629 | [MOL File]
71360-06-0.mol | [Molecular Weight]
242.3 |
| Chemical Properties | Back Directory | [Boiling point ]
368.8±42.0 °C(Predicted) | [density ]
1.017 g/mL at 25 °C | [refractive index ]
n20/D1.599 | [Fp ]
>110℃ | [form ]
liquid | [color ]
colorless | [Sensitive ]
air sensitive |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid | [Uses]
Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare:
- Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.
- The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.
- Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
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