| Identification | Back Directory | [Name]
(E,Z)-1-Methoxy-2-methyl-3- (trimethylsilyloxy)-1,3-pentadiene | [CAS]
72486-93-2 | [Synonyms]
TRANS-1-METHOXY-2-METHYL-3-(TRIMETHYLSI&
(1E 3Z)-1-METHOXY-2-METHYL-3-(TRIMETHYL&
[(1-(2-Methoxy-1-methylvinyl)propenyloxy]trimethylsilan
1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene
(1e,3z)-1-methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene
(1e,3z)-1-methoxy-2-methyl-3-[(trimethylsilyl)oxy]-penta-1,3-diene
Silane, [[(1Z)-1-[(1E)-2-methoxy-1-methylethenyl]-1-propen-1-yl]oxy]trimethyl-
[(1-(2-Methoxy-1-methylvinyl)propenyloxy]trimethylsilan, (1E,3Z)-1-Methoxy-2-methyl-3-[(trimethylsilyl)oxy]-penta-1,3-diene | [Molecular Formula]
C10H20O2Si | [MDL Number]
MFCD10567404 | [MOL File]
72486-93-2.mol | [Molecular Weight]
200.35 |
| Chemical Properties | Back Directory | [Boiling point ]
65 °C/6 mmHg (lit.) | [density ]
0.899 g/mL at 25 °C (lit.) | [refractive index ]
n20/D 1.4650(lit.) | [Fp ]
178 °F | [storage temp. ]
2-8°C |
| Hazard Information | Back Directory | [Uses]
(1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene used as a reactant for:Preparation of migrastatin analog as cell migration inhibitor for treatment of tumor metastasis2Preparation of dihydropyridinones by chlorosilane-promoted aza-Diels-Alder addition3Synthesis on non-proteinogenic amino esters via stereoselective Lewis acid-catalyzed aza-Diels-Alder cycloaddition with conjugated (cyclo)dienes4 | [Uses]
Danishefsky diene used as a reactant for:
Preparation of migrastatin analog as cell migration inhibitor for treatment of tumor metastasis
Preparation of dihydropyridinones by chlorosilane-promoted aza-Diels-Alder addition
Synthesis on non-proteinogenic amino esters via stereoselective Lewis acid-catalyzed aza-Diels-Alder cycloaddition with conjugated (cyclo)dienes | [Synthesis]
(1E,3Z)-1-Methoxy-2-Methyl-3-(triMethylsilyloxy)-1,3-pentadiene is prepared in multigram quantities as a colorless or slightly yellow liquid from 3- pentanone and ethyl formate via a three-step procedure (ca. 40% overall yield). |
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Energy Chemical
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021-021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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Sigma-Aldrich
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021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
SIGMA-RBI
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800 736 3690 (Orders) |
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www.sigma-aldrich.com |
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