| Identification | Back Directory | [Name]
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- | [CAS]
7428-60-6 | [Synonyms]
Tris(trimethylsilyl)silanol
Tris(trimethylsilyl)silanol >=95%
Hydroxy-tris(trimethylsilyl)silane
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- | [Molecular Formula]
C9H28OSi4 | [MDL Number]
MFCD00093727 | [MOL File]
7428-60-6.mol | [Molecular Weight]
264.66 |
| Hazard Information | Back Directory | [Uses]
Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225). |
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