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759-24-0

759-24-0 Structure

759-24-0 Structure
IdentificationBack Directory
[Name]

DIETHYL TERT-BUTYLMALONATE
[CAS]

759-24-0
[EINECS(EC#)]

212-067-5
[Molecular Formula]

C11H20O4
[MDL Number]

MFCD00009152
[MOL File]

759-24-0.mol
[Molecular Weight]

216.27
Chemical PropertiesBack Directory
[Boiling point ]

102-104 °C11 mm Hg(lit.)
[density ]

1.014 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.425(lit.)
[Fp ]

195 °F
[Water Solubility ]

Immiscible with water.
[BRN ]

1781709
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H227
[Precautionary statements ]

P210e-P280a-P370+P378a-P403+P235-P501a
[Safety Statements ]

23-24/25
[WGK Germany ]

3
Spectrum DetailBack Directory
[Spectrum Detail]

DIETHYL TERT-BUTYLMALONATE(759-24-0)1HNMR
DIETHYL TERT-BUTYLMALONATE(759-24-0)Raman
DIETHYL TERT-BUTYLMALONATE(759-24-0)IR
DIETHYL TERT-BUTYLMALONATE(759-24-0)FT-IR
Hazard InformationBack Directory
[Purification Methods]

Dissolve it in Et2O, wash with aqueous NaHCO3, H2O, dry (MgSO4), filter, evaporate and distil the residue. Identify by hydrolysis to the acid and determine the neutralisation equivalent (theor: 80.0). The acid has m 155-157o effervescence [Hauser et al. J Am Chem Soc 64 2715 1942, Bush & Beauchamp J Am Chem Soc 75 2949 1953]. [Beilstein 2 IV 2027.]
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