Identification | Back Directory | [Name]
GERANYL PYROPHOSPHATE AMMONIUM 200 | [CAS]
763-10-0 | [Synonyms]
NEROLPYROPHOSPHATE Geranyl diphosphate Geranyl pyrophosphate GVVPGTZRZFNKDS-JXMROGBWSA-N GERANYL PYROPHOSPHATE AMMONIUM 200 geranyl pyrophosphate ammonium*200 ug/vial trans-3,7-dimethyl-2,6-octadienyl pyrophosphate (2E)-3,7-Dimethyl-2,6-octadiene-1-ol diphosphoric acid trans-3,7-Dimethyl-2,6-octadienyl pyrophosphate, GPP Diphosphoric acid,P-[(2E)-3,7-dimethyl-2,6-octadien-1-yl]- Diphosphoric acid α-[(2E)-3,7-dimethyl-2,6-octadienyl] ester [(2E)-3,7-dimethylocta-2,6-dienyl] phosphono hydrogen phosphate | [Molecular Formula]
C10H20O7P2 | [MDL Number]
MFCD00189726 | [MOL File]
763-10-0.mol | [Molecular Weight]
365.3 |
Hazard Information | Back Directory | [Definition]
ChEBI: Geranyl diphosphate is the diphosphate of the polyprenol compound geraniol. It has a role as an Escherichia coli metabolite and a mouse metabolite. It is functionally related to a geraniol. It is a conjugate acid of a geranyl diphosphate(3-). | [Biochem/physiol Actions]
Intermediate in terpene biosynthesis | [Purification Methods]
Purify the pyrophosphate by paper chromatography on Whatman No 3 MM paper in a system of isopropyl alcohol/isobutyl alcohol/ammonia/water (40:20:1:39), RF 0.77-0.82. Store it in the dark as the ammonium salt at 0o. The E-form crystallises in platelets from aqueous Me2CO, m ~120o. It dissolves in dry MeCN. Alternatively purify it through a column of Dowex AG 1x8(200-400mesh) equilibrated with 50mM NH4 formate, and elute with MeOH/H2O/NH4OH (95:5:05), then freeze-dry. [Dixit et al. J Org Chem 46 1967 1981, Beilstein 1 IV 3580.] |
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