| Identification | Back Directory | [Name]
6,7',12-Trimethoxy-2,2'-dimethylthalman-6'-ol | [CAS]
7682-65-7 | [Synonyms]
Thalmine
6,7',12-Trimethoxy-2,2'-dimethylthalman-6'-ol | [Molecular Formula]
C35H36N2O6 | [MOL File]
7682-65-7.mol | [Molecular Weight]
580.677 |
| Hazard Information | Back Directory | [Description]
This alkaloid from Thalictrum minus was originally given the empirical formula
C2oH2303N, later altered to that given above. It forms colourless crystals from
a mixture of CHC13 and EtOH and is laevorotatory with [α]D - 64.5°. The salts
and derivatives are crystalline but normally decompose before melting: the
hydrochloride, m.p. 147-157°C (dec.); perchlorate, decomposing at 238-241°C
and the methiodide, decomposing at 250°C. The o-acetate has [α]D - 219°.
Three methoxyl groups, a phenolic hydroxyl group and two methylimino
groups are present | [Definition]
ChEBI: Thalmine is a member of isoquinolines and a bisbenzylisoquinoline alkaloid. | [References]
Yunusov, Progressov.,J. Gen. Chem., USSR, 20, 1151 (1950)
Telezhenetskaya, Ismailov, Yunusov., Khim. Prir. Soedin., 2, 107 (1966)
Baldas et ai., Tetrahedron Lett., 6315 (1968) |
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