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828927-96-4

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828927-96-4 Structure

828927-96-4 Structure
IdentificationBack Directory
[Name]

(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[?-1-PHENYLETHYL]-1-PHTHALAZINAMINE,(S)-N-PINAP
[CAS]

828927-96-4
[Synonyms]

(1S)-4-[2-(diphenylphosphino)-1-naphthalenyl]-N-[(1R)-1-phenylethyl]-1-Phthalazinamine
(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine
(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[?-1-PHENYLETHYL]-1-PHTHALAZINAMINE,(S)-N-PINAP
(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinaMine (R,S)-N-PINAP
(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine,min.97%(S)-N-PINAP
(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,S)-N-PINAP
[Molecular Formula]

C38H30N3P
[MDL Number]

MFCD09264274
[MOL File]

828927-96-4.mol
[Molecular Weight]

559.65
Chemical PropertiesBack Directory
[Melting point ]

>210°C
[alpha ]

-162° (c 0.54, CHCl3)
[form ]

crystal
[color ]

colorless
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
Questions And AnswerBack Directory
[Reactions]

  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777,15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. 
  2. With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.
  3. With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media. 
Reactions of 828927-96-4
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