ChemicalBook--->CAS DataBase List--->83585-61-9

83585-61-9

83585-61-9 Structure

83585-61-9 Structure
IdentificationBack Directory
[Name]

2-(AMINOMETHYL)-18-CROWN-6
[CAS]

83585-61-9
[Synonyms]

2-(AMINOMETHYL)-18-CROWN-6
2-AMinoMethyl-18-crown-6 95%
1,4,7,10,13,16-hexaoxacyclooctadecane-2-methanamine
[Molecular Formula]

C13H27NO6
[MDL Number]

MFCD00191741
[MOL File]

83585-61-9.mol
[Molecular Weight]

293.36
Chemical PropertiesBack Directory
[Boiling point ]

135 °C/0.08 mmHg (lit.)
[density ]

1.126 g/mL at 25 °C (lit.)
[refractive index ]

n20/D 1.479(lit.)
[Fp ]

113 °C
[pka]

9.11±0.29(Predicted)
[BRN ]

4184588
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

2-Aminomethyl-18-crown-6 (AM-18-C-6) can be used to prepare:
  • AM-18-C-6 bonded Merrifield peptide resin, which is used to study the absorption and the isotopic effect of magnesium.
  • Schiff base of gossypol with aminomethyl crown ether for complexation of monovalent cations.
  • Crown tagged triarylphosphine by reacting with triphenylphosphine carboxylic acid. These tagged triarylphosphine reagents are used in Mitsunobu and Heck reactions for the removal of phosphine derived by-products.
  • 1,16-hexadecanoyl-bis-(2-aminomethyl)-18-crown-6 (bola A-16), which is utilized as a vesicular carrier in a drug delivery system.

Spectrum DetailBack Directory
[Spectrum Detail]

2-(AMINOMETHYL)-18-CROWN-6(83585-61-9)FT-IR
2-(AMINOMETHYL)-18-CROWN-6(83585-61-9)Raman
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