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83622-41-7

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83622-41-7 Structure

83622-41-7 Structure
IdentificationBack Directory
[Name]

1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl-
[CAS]

83622-41-7
[Synonyms]

Dichloromethyl pinacolboronate
Pinacol (dichloromethyl) boronate
Pinacol (dichloromethyl) boronate >=95%
(Dichloromethyl)boronic Acid Pinacol Ester
2-(dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl-
2-(Dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane（WS203860）
[Molecular Formula]

C7H13BCl2O2
[MDL Number]

MFCD27976342
[MOL File]

83622-41-7.mol
[Molecular Weight]

210.89
Chemical PropertiesBack Directory
[Boiling point ]

103 °C(Press: 20 Torr)
[density ]

1.1423
[refractive index ]

n/D 1.4511
[form ]

liquid
Hazard InformationBack Directory
[Uses]

Pinacol (dichloromethyl) boronate is a general reagent that was employed by Prof. Greg C. Fu and coworkers to achieve the iterative synthesis of asymmetric (secondary) alkyl boronate esters. These can be further derivatized through a growing suite of chemical transformations developed in the last decade (cross coupling, oxidation, amination, halogenation) that proceed with stereochemical fidelity.
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