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849950-53-4

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849950-53-4 Structure

849950-53-4 Structure
IdentificationBack Directory
[Name]

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
[CAS]

849950-53-4
[Synonyms]

(S,S)-Ph-BPE-Rh
(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
[Molecular Formula]

C42H48BF4P2Rh
[MDL Number]

MFCD07369038
[MOL File]

849950-53-4.mol
[Molecular Weight]

804.49
Chemical PropertiesBack Directory
[form ]

crystal
[color ]

orange
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
Questions And AnswerBack Directory
[Reaction]

  1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
  2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
  3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
  4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins. 
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