Identification | Back Directory | [Name]
Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane | [CAS]
861445-91-2 | [Synonyms]
Tris(trimethylsilyl)silyl vinyl ether 2-(Ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane Trisilane, 2-(ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane | [Molecular Formula]
C11H30OSi4 | [MDL Number]
MFCD11656064 | [MOL File]
861445-91-2.mol | [Molecular Weight]
290.7 |
Hazard Information | Back Directory | [Uses]
Super Silyl Protecting Groups
Used for:
- Diastereoselective [2+2] cyclizations
- Cross-Aldol cascade reaction
- Diastereoselective sequential reactions for generating polyols
- Accessing distinct diastereomers and 4-component reactions
- Supersilyl-directed aldol reactions
- Strong electron-donating effect of the supersilyl group operates only in the α-position and not in the β-position
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