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885701-71-3

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885701-71-3 Structure

885701-71-3 Structure
IdentificationBack Directory
[Name]

Phenyl-[(S)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy
[CAS]

885701-71-3
[Synonyms]

Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,10,11,12,13-tetrahydro-5-phenoxy-, (11aS)-
Phenyl-[(S)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy
[Molecular Formula]

C23H17O3P
[MDL Number]

MFCD08459341
[MOL File]

885701-71-3.mol
[Molecular Weight]

372.353
Chemical PropertiesBack Directory
[Melting point ]

102-103°C
[alpha ]

-213° (c 0.5, CH2Cl2)
[form ]

solid
[color ]

white
[Sensitive ]

moisture sensitive
[CAS DataBase Reference]

885701-71-3
Questions And AnswerBack Directory
[Reaction]

  1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
  2. Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
  3. Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
  4. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
  5. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides. 
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