ChemicalBook--->CAS DataBase List--->919102-70-8

919102-70-8

919102-70-8 Structure

919102-70-8 Structure
IdentificationBack Directory
[Name]

Bode Catalyst 1
[CAS]

919102-70-8
[Synonyms]

98.0%(LC)
Bode Catalyst 1
Lacβ(1-4)Lac-β-C10>
GUECWMLEUCWYOS-OZYANKIXSA-M
Neu5Acα(2-6)GalβMPGlycoside>
GlcNAcβ(1-2)Manα-1-Ethylazide>
Gal[2346Ac]β(1-3)GlcN3[46Bzd]-β-MP>
3-(4-Nitrophenyl)-5-methyl-2-phenyltetrazolium Chloride >
4-Methoxyphenyl2,6-Bis-O-(4-methylbenzoyl)-β-D-galactopyranoside>
(1R,2R)-1,2-Bis(3,5-dimethylphenyl)-1,2-ethylenediamine Phosphate >
(1S,2S)-1,2-Bis(3,5-dimethylphenyl)-1,2-ethylenediamine Phosphate >
4-Methoxyphenyl3-O-Allyl-2-O-benzyl-4,6-O-benzylidene-β-D-galactopyranoside>
2-Acetamido-3-O-allyl-4,6-O-benzylidene-2-deoxy-beta-D-glucopyranosyl Azide >
4-Methoxyphenyl3-O-Allyl-6-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside>
4-Methoxyphenyl3,4-O-Isopropylidene-6-O-(4-methylbenzoyl)-β-D-galactopyranoside>
4-Methoxyphenyl3-O-Allyl-4,6-O-benzylidene-2-O-(4-methylbenzoyl)-β-D-galactopyranoside>
Succinimidyl6-[[7-(N,N-Dimethylaminosulfonyl)-2,1,3-benzoxadiazol-4-yl]amino]hexanoate>
(-)-(5aS,10bR)-5a,10b-Dihydro-2-mesityl-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride
6-Amino-1,3-naphthalenedisulfonic Acid Monosodium Salt Hydrate[for Determination of 1-Naphthol in 2-Naphthol]>
(-)-(5AS,10br)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium chloride
(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride
(-)-(5aS,10bR)-5a,10b-Dihydro-2-mesityl-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Bode Catalyst 1
[5a-S,10b-R]-2-(2,4,6-Trimethyl-phenyl)-2,5a,6,10b-tetrahydro-4H-5-oxa-2,3-diaza-10c-azonia-cyclopenta[c]fluorene chloride
(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H, 6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate
(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate
(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxaziniumChlorideMonohydrate>
(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate
[Molecular Formula]

C21H22ClN3OH2O
[MDL Number]

MFCD10566990
[MOL File]

919102-70-8.mol
[Molecular Weight]

367.88
Chemical PropertiesBack Directory
[Melting point ]

212-216 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

powder to crystal
[color ]

White to Light yellow
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P302+P352-P305+P351+P338
[HS Code ]

29349990
Hazard InformationBack Directory
[Uses]

(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H, 6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate can be used as an N-heterocyclic carbene (NHC) organocatalyst:
  • In the synthesis of tricyclic β-lactones by reacting 2-bromoenals with 1,3-diketones.
  • To functionalize the C2-position of 3-aminobenzofurans using 2-bromoenals as coupling partners.
  • In the synthesis of dihydroquinoxalines from substituted bisimines.
  • In the preparation of spiro-glutarimide derivatives by reacting cyclic β-ketoamides with α,β-unsaturated aldehydes.

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