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999-90-6

999-90-6 Structure

999-90-6 Structure
IdentificationBack Directory
[Name]

S-TERT-BUTYL THIOACETATE
[CAS]

999-90-6
[Synonyms]

CH3C(O)SC(CH3)3
S-TERT-BUTYL THIOACETATE
S-tert-Butyl thioacetate 98%
S-(tert-Butyl) ethanethioate
Thioacetic acid S-tert-butyl ester
Thioacetic acid S-(tert-butyl) ester
Ethanethioic acid S-tert-butyl ester
Ethanethioic acid, S-(1,1-dimethylethyl) ester
[Molecular Formula]

C6H12OS
[MDL Number]

MFCD00042941
[MOL File]

999-90-6.mol
[Molecular Weight]

132.22
Chemical PropertiesBack Directory
[Boiling point ]

135-136 °C(lit.)
[density ]

0.927 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.453(lit.)
[Fp ]

93 °F
[BRN ]

1740436
[LogP]

2.133 (est)
Safety DataBack Directory
[Risk Statements ]

10
[Safety Statements ]

23-24/25
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[F ]

9-13
[HazardClass ]

3.2
[PackingGroup ]

III
Hazard InformationBack Directory
[Uses]

S-tert-Butyl thioacetate may be used for the preparation of vinyloxyborane derivative.
[General Description]

S-tert-Butyl thioacetate is a thioester.
[Purification Methods]

Dissolve it in CHCl3 (EtOH-free), wash with H2O, 10% H2SO4, saturated aqueous NaHCO3 (care CO2 liberated), H2O again, dry over Drierite and anhydrous K2CO3, and fractionate under reduced pressure. [Rylander & Tarbell J Am Chem Soc 72 3021 1950, Beilstein 2 IV 546.]
Spectrum DetailBack Directory
[Spectrum Detail]

S-TERT-BUTYL THIOACETATE(999-90-6)MS
S-TERT-BUTYL THIOACETATE(999-90-6)IR1
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