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1194050-21-9

中文名称 (1,2,5,6-η)-1,5-环辛二烯][(4S)-2-[(5S)-6-(二苯基膦-κP)螺[4.4]壬-1,6-二烯-1-基]-4,5-二氢-4-苯基恶唑-κN3]-(+)-铱(I)四[3,5-二(三氟甲基)苯基]硼酸酯
CAS 1194050-21-9
分子式 C70H52BF24IrNOP
1194050-21-9 结构式 1194050-21-9 结构式

基本信息

中文别名
1,5-CYCLOOCTADIENE{(4S)-(+)-2-[(5S)-6-(DIPHENYLPHOSPHINO)SPIRO[4.4]NONA-1.6-DIEN-1-YL]-4,5-DIHYDRO-4-PHENYLOXAZOLE}IRIDIUM(I)TETRAKIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]BORATE,97%(S,S)-(COD)IR[PH-SPINPHOX]
英文别名
(S,S)-(+)-Ph-SpinPHOX/Ir(I)
[(1,2,5,6-η)-1,5-Cyclooctadiene][(4S)-2-[(5S)-6- (diphenylphosphino-κP)spiro[4.4]nona-1,6-dien-1-yl]-4,5- dihydro-4-phenyloxazole-κN3]-(+)-Iridium(I) Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
1,5-Cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-phenyloxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate, 97% (S,S)-(COD)Ir[Ph-Spin
[(1,2,5,6-η)-1,5-Cyclooctadiene][(4S)-2-[(5S)-6-(diphenylphosphino-κP)spiro[4.4]nona-1,6-dien-1-yl]-4,5-dihydro-4-phenyloxazole-κN3]-(+)-Iridium(I) Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate,99%e.e.

物理化学性质

熔点197-198°C
比旋光度+97.2° (c 1.0, CHCl3)
形态粉末
颜色橙色
敏感性空气敏感
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