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TRIMETHYLENE DI(THIOTOSYLATE)

CAS No.
3866-79-3
Chemical Name:
TRIMETHYLENE DI(THIOTOSYLATE)
Synonyms
NSC 82472;1,3-DI(P-TOSYLTHIO)PROPANE;TRIMETHYLENE DI(THIOTOSYLATE);1,3-Propanedithiol ditosylate;1,3-PROPANEDIYL DI(THIOTOSYLATE);1,3-Propanediylbis(tosyl sulfide);1,3-bis(p-toluenesulfonylthio)propane;Trimethylene di-p-toluenethiosulfonate;TRIMETHYLENE BIS(P-TOLUENETHIOSULFONATE);1,3-Propanedithiolebis(p-toluenesulfonate)
CBNumber:
CB0100135
Molecular Formula:
C17H20O4S4
Molecular Weight:
416.58
MDL Number:
MFCD00014918
MOL File:
3866-79-3.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02

TRIMETHYLENE DI(THIOTOSYLATE) Properties

Melting point 64-67 °C
Boiling point 592.3±60.0 °C(Predicted)
Density 1.340±0.06 g/cm3(Predicted)
form powder to crystal
color White to Almost white
BRN 2020157
CAS DataBase Reference 3866-79-3
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Safety Statements  22-24/25
WGK Germany  3
HS Code  2930.90.2900

TRIMETHYLENE DI(THIOTOSYLATE) price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D2390 Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene] >95.0%(HPLC) 3866-79-3 5g $65 2024-03-01 Buy
TCI Chemical D2390 Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene] >95.0%(HPLC) 3866-79-3 25g $197 2024-03-01 Buy
TRC T796183 TrimethyleneDi(thiotosylate) 3866-79-3 2.5g $85 2021-12-16 Buy
AK Scientific 9310AL Trimethylenedi(thiotosylate) 3866-79-3 5g $149 2021-12-16 Buy
Chem-Impex 37319 S,S-Trimethylenedi(p-toluenethiosulfonate),≥95%(HPLC) ≥95%(HPLC) 3866-79-3 5G $75.71 2021-12-16 Buy
Product number Packaging Price Buy
D2390 5g $65 Buy
D2390 25g $197 Buy
T796183 2.5g $85 Buy
9310AL 5g $149 Buy
37319 5G $75.71 Buy

TRIMETHYLENE DI(THIOTOSYLATE) Chemical Properties,Uses,Production

Uses

Trimethylene Di(thiotosylate) is used as a reactant in the enantioselective total synthesis of (-)-O-methylpallidinine, which is a naturally occurring morphinan alkaloid.

Reactions

1,3-Propanedithiol Bis(p-toluenesulfonate) could be used in the below reactions:
dithianylation and dithiolanylation of methylene groups adjacent to carbonyl; α,α-dithianyl cycloalkanones undergo oxidative ring scission; oxidation of ketones to 1,2-diketones can be achieved by α,α-dithianylation or dithiolanation of ketones followed by hydrolysis.

Synthesis

Treatment of potassium thiotosylate, itself made by the reaction of p-Toluenesulfonyl Chloride with Potassium Hydrogen Sulfide, with 1,3-dibromopropane or 1,2-dibromoethane in the presence of Potassium Iodide affords 1,3-propanedithiol bis(p-toluenesulfonate) and 1,2-ethanedithiol bis(p-toluenesulfonate), respectively.

TRIMETHYLENE DI(THIOTOSYLATE) Preparation Products And Raw materials

Raw materials

Preparation Products

TRIMETHYLENE DI(THIOTOSYLATE) Suppliers

Global( 67)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8804 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-18789408387 1057@dideu.com China 3889 58
Hebei Mujin Biotechnology Co.,Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12830 58
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29871 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Coresyn Pharmatech Co., Ltd.
+86-571-86626709 +86-18157142896 cbc@coresyn.com China 9984 58
Zibo Hangyu Biotechnology Development Co., Ltd
+86-0533-2185556 +8617865335152 Mandy@hangyubiotech.com China 10986 58
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 52924 58
Qingdao Dexin Chemical Co., Ltd
+86-15553333686 +86-15553333686 15553333686@qq.com China 3113 58

View Lastest Price from TRIMETHYLENE DI(THIOTOSYLATE) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TRIMETHYLENE DI(THIOTOSYLATE) pictures 2025-02-14 TRIMETHYLENE DI(THIOTOSYLATE)
3866-79-3
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mujin Biotechnology Co.,Ltd
TRIMETHYLENE DI(THIOTOSYLATE) pictures 2024-12-10 TRIMETHYLENE DI(THIOTOSYLATE)
3866-79-3
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Weibang Biotechnology Co., Ltd
TRIMETHYLENE DI(THIOTOSYLATE) pictures 2024-08-14 TRIMETHYLENE DI(THIOTOSYLATE)
3866-79-3
US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd
1,3-DI(P-TOSYLTHIO)PROPANE 1,3-PROPANEDIYL DI(THIOTOSYLATE) TRIMETHYLENE BIS(P-TOLUENETHIOSULFONATE) TRIMETHYLENE DI(THIOTOSYLATE) Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene] S,S'-Trimethylene di(p-toluenethiosulfonate) Benzenesulfonothioic acid, 4-methyl-, S,S-1,3-propanediyl ester 1,3-Di(p-tosylthio)propane, 1,3-Propanediyl di(thiotosylate), Trimethylene di(thiotosylate) 1,3-Propanedithiolebis(p-toluenesulfonate) 1,3-Propanediylbis(tosyl sulfide) p-Toluenesulfonothioic acid S-[3-[(4-methylphenyl)sulfonylthio]propyl] ester NSC 82472 Trimethylene di-p-toluenethiosulfonate Benzenesulfonothioicacid, 4-methyl-, S1,S1'-1,3-propanediyl ester 1,3-Di(p-tosylthio)propane 1,3-Propanediyl Di(thiotosylate) Trimethylene Bis(p-toluenethiosulfonate) 1-methyl-4-[3-(4-methylphenyl)sulfonylsulfanylpropylsulfanylsulfonyl]benzene 1-methyl-4-[3-[(4-methylphenyl)sulfonylthio]propylthio]sulfonyl-benzene 1,3-Bis(4-methylbenzenesulfonylthio)propane 1,3-Propanedithiol ditosylate 4-Methylbenzenesulfonothioic acid S1,S1'-1,3-propanediyl ester 1,3-bis(p-toluenesulfonylthio)propane TrimethyleneDi(thiotosylate)[ProtectingReagentforActiveMethylene]> 3866-79-3 CH3C6H4SO2SCH2CH2CH2SSO2C6H4CH3 C17H20O4S4 Protection & Derivatization Reagents (for Synthesis) Sulfur Compounds (for Synthesis) Building Blocks Organic Building Blocks Sulfur Compounds Tosylates Building Blocks Chemical Synthesis Organic Building Blocks Sulfur Compounds Tosylates Synthetic Organic Chemistry Protection & Derivatization Reagents (for Synthesis) Sulfur Compounds (for Synthesis) blocks BuildingBlocks