Methanol-d4 | 811-98-3

Methanol-d4 Properties

Melting point	-99 °C
Boiling point	65.4 °C(lit.)
Density	0.888 g/mL at 25 °C(lit.)
vapor pressure	129 hPa (20 °C)
refractive index	n20/D 1.326(lit.)
Flash point	52 °F
storage temp.	no restrictions.
solubility	Chloroform (Slightly), Water (Slightly)
form	Liquid
color	Colorless
Specific Gravity	0.89
explosive limit	5.5-36.5%(V)
Water Solubility	Miscible with water, ethanol, ether, acetone and chloroform.
BRN	1733278
Exposure limits	ACGIH: TWA 200 ppm; STEL 250 ppm (Skin) OSHA: TWA 200 ppm(260 mg/m3) NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3)
Stability	Stable. Incompatible with moisture, acids, acid chlorides, acid anhydrides, oxidizing agents, reducing agents, alkali metals. Highly flammable.
InChIKey	OKKJLVBELUTLKV-MZCSYVLQSA-N
CAS DataBase Reference	811-98-3(CAS DataBase Reference)
EPA Substance Registry System	Methanol-d4 (811-98-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS06,GHS08

Signal word

Danger

Hazard statements

H225-H301+H311+H331-H370

Precautionary statements

P210-P233-P280-P301+P310-P303+P361+P353-P304+P340+P311

Hazard Codes

F,T

Risk Statements

11-23/24/25-39/23/24/25

Safety Statements

7-16-36/37-45

RIDADR

UN 1230 3/PG 2

WGK Germany

1

RTECS

PC1400000

F

10-21

Autoignition Temperature

440 °C

TSCA

Yes

HazardClass

3

PackingGroup

II

HS Code

28459000

Toxicity

LD50 orally in Rabbit: 5628 mg/kg LD50 dermal Rabbit 17100 mg/kg

NFPA 704

	3
1		0

Methanol-d4 price More Price(86)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	444758	Methanol-d4 "100%", 99.96 atom % D	811-98-3	1g	$38.48	2024-03-01	Buy
Sigma-Aldrich	444758	Methanol-d4 "100%", 99.96 atom % D	811-98-3	10g	$526	2024-03-01	Buy
Sigma-Aldrich	151947	Methanol-d4 ≥99.8 atom % D	811-98-3	1g	$34.3	2024-03-01	Buy
Sigma-Aldrich	151947	Methanol-d4 ≥99.8 atom % D	811-98-3	10g	$170	2024-03-01	Buy
Sigma-Aldrich	151947	Methanol-d4 ≥99.8 atom % D	811-98-3	50g	$649	2024-03-01	Buy

Product number	Packaging	Price	Buy
444758	1g	$38.48	Buy
444758	10g	$526	Buy
151947	1g	$34.3	Buy
151947	10g	$170	Buy
151947	50g	$649	Buy

Methanol-d4 Chemical Properties,Uses,Production

Synthesis

A preparation method for providing per-deuterated methanol is provided, specifically: opening the valve of deuterium gas and carbon monoxide, and controlling the volume ratio to be 1:1 to carry out premixing (deuterium gas and carbon monoxide are respectively 2kg and 14kg, a total of 16kg). Under the pressure of 5.5MPa, at a speed of 2L/s, through the catalyst bed layer of gold oxide: platinum oxide: rhodium oxide = 1:3:2 (mass ratio) at 210~380℃, after continuous circulation reaction for 24 hours, in The per-deuterated methanol reaction solution was obtained from the separation kettle, and the obtained reaction solution was rectified to give Methanol-d4: 3.2 kg, yield 35.5%, purity 99.8%.

Chemical Properties

colourless liquid

Uses

Methanol-d4 may be used as a solvent to analyze the rate of exchange of methoxyl group in camphor and norcamphor dimethyl ketals.

Application

Methyl Alcohol-d4 is the labeled analog of methyl alcohol, a common laboratory solvent used primarily in spectroscopic techniques (UV/VIS, NMR, IR).

Definition

ChEBI: Methanol-d4 is a deuterated compound that is methanol in which all four hydrogen atoms are replaced by deuterium. It is commonly used as a solvent in NMR spectroscopy. It has a role as an amphiprotic solvent.

General Description

Methanol-d₄ (CD₃OD) is a deuterated NMR solvent used for NMR-based research and analyses. It has the highest isotopic enrichment and will not interfere with the desired level of detection.
The absolute infrared absorption intensities of CD3OD have been reported between 8000 and 350cm^-1.

Synthesis

2131312313

Methanol-d4 Preparation Products And Raw materials

Raw materials

Preparation Products

TETRAHYDROFURAN-D8 ETHANOL-D 4-Methylbenzyl acetate KISVAASFGZJBCY-BMSJAHLVSA-N Methyl Salicylate-d3

3-Methyl-d3-indole

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Methanol-d4 Suppliers

Global( 235)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Mojin Biotechnology Co., Ltd	+86 13288715578 +8613288715578	sales@hbmojin.com	China	12840	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	7514	58
Hebei Fengjia New Material Co., Ltd	+86-0311-87836622 +86-17333973358	sales06@hbduling.cn	China	8053	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20287	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29884	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49374	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5600	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9636	58

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Shanghai UCHEM Inc.	58
Hebei Fengjia New Material Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Richest Group Ltd	58
Antai Fine Chemical Technology Co.,Limited	58

View Lastest Price from Methanol-d4 manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-01	Methanol-D4 811-98-3	US $54.00-606.00 / g	5g	0.99	25kg	Shanghai UCHEM Inc.
2024-10-24	Methanol-d4 811-98-3	US $0.00-0.00 / mg			10g	TargetMol Chemicals Inc.
2024-10-22	Methanol-d4 811-98-3	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd

Methanol-D4
811-98-3
US $54.00-606.00 / g
0.99
Shanghai UCHEM Inc.

Methanol-d4
811-98-3
US $0.00-0.00 / mg
TargetMol Chemicals Inc.

Methanol-d4
811-98-3
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

Methanol-d4 Spectrum

Methanol-d4(811-98-3)MS Methanol-d4(811-98-3)¹HNMR Methanol-d4(811-98-3)¹³CNMR Methanol-d4(811-98-3)IR1 Methanol-d4(811-98-3)Raman

811-98-3(Methanol-d4)Related Search:

Methanol-d4 METHANOL-D 18-CROWN-6-METHANOL (1,5-DIMETHYL-1H-PYRAZOL-3-YL)METHANOL 1,1,1-DIPHENYL-(N-METHYL-PYRROLINE-2YL)-METHANOL

1-AMINOCYCLOPROPYL-METHANOL (1,4-DIMETHYL-2-PIPERAZINYL)METHANOL,(1,4-DIMETHYLPIPERAZIN-2-YL)METHANOL (1-AMINOMETHYL-CYCLOHEXYL)-METHANOL (1-[(4-NITROPHENYL)SULFONYL]-3-PIPERIDINYL)METHANOL [1-(4-FLUOROBENZYL)PYRROLIDIN-2-YL]METHANOL

[1-(4-TRIFLUOROMETHYL-PHENYL)-CYCLOPROPYL]-METHANOL [1-(4-METHYLBENZYL)-1H-BENZIMIDAZOL-2-YL]METHANOL (1-AMINO-2,3-DIHYDRO-1H-BENZO[F]CHROMEN-2-YL)METHANOL HYDROCHLORIDE,(1-AMINO-2,3-DIHYDRO-1H-BENZO[F]CHROMEN-2-YL)-METHANOL HCL [1-(4-FLUORO-PHENYL)-CYCLOPROPYL]-METHANOL METHANOL-13C-D4

TMS (1-[5-(TRIFLUOROMETHYL)PYRIDIN-2-YL]PIPERIDIN-4-YL)METHANOL (1,4-DIOXA-SPIRO[4.5]DEC-8-YL)-METHANOL

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Methanol-d4, 99.5 atom % D, for NMR Methanol-d4, 99.6+ atom % D, for NMR Methanol-d4, 99.8 atom % D, for NMR Methanol-d4, contains 0.03% V/V % TMS, 99.8 atom % D, for NMR Methanol-d4, packaged in 0.50 ml ampules, 100.0 atom % D, for NMR Methanol-d4, packaged in 0.75 ml ampules, 100.0 atom % D, for NMR 99.96 atom % D, 99% (CP) Methanol-d4 99 atom % D Methanol-d4 99.8 atom % D, contains 0.05 % (v/v) TMS 4X GC BUFFER I (10 X 1.5 ML) (2H4)methanol METHANOL-D4, 100.0 ATOM % D (1PK=10 X 0.25ML) METHANOL-D4 , 99.8 + ATOM % D (1PK=5 X 0.5ML) METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D (CON TAINS 1% V/V TMS) Methanol-D₄ METHANOL-D4, 99.8 + ATOM % D (1PK=10 X 1ML) METHYL-D3 ALCOHOL-D, 100.0 ATOM % D METHYL-D3 ALCOHOL-D, 99.8+ATOM % D (SEPTUM VIALS) METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D (CON TAINS 0.03% V/V TMS) METHYL-12C-D3 ALCOHOL-D, 99.95 ATOM % 12 C, 99.5 ATOM % D METHYL ALCOHOL-D4+0.05% TMS (V/V) (~0.7 METHYL-D3 ALCOHOL-D, 99.8 ATOM % D, ANH& METHANOL-D4, 99.8 ATOM % D METHYL-D3 ALCOHOL-D, 99+ ATOM % D METHYL-D3 ALCOHOL-D, 99.95 ATOM % D (1PK =10 X 0.5ML) METHYL-D3 ALCOHOL-D, 99.8 ATOM % D (CONT METHYL-D3 ALCOHOL-D, 100 ATOM % D(CONTAINS 0.03% V/V TMS) METHANOL-D(4) VIAL WITH 10 ML >99.95 ( METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D, AN& METHANOL-D4, 99.8 + ATOM % D (1PK=10 X 0.75ML) METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D (CON TAINS 0.1% V/V TMS) METHYL-D3 ALCOHOL-D, 99.8 + ATOM % D (0.0 3% V/V TMS, 1PK=10 X 1ML) Methanol-d4, isotopic purity 99.5+% Methanol-d4,99.8%(Isotopic) Methanol-d4,99.8%(Isotopic),contains0.05%v/vTMS Methanol-d4, 100.0 atom % D, for NMR Methanol-d4 99.8atom%D (0.75mL*10) ACETIC ANHYDRIDE SOLUTION R1 PHE CALCIUM NITRATE TETRAHYDRATE GRAN HYDROXYDE CUPRIETHYLE SOL. PHE SOLUTION IC MORPHOLINE 1G/L IN H2O Methyl-d3 alcohol-d,99.5 atom Methanol-d4, contains 0.05% TMS, 99.8% Isotopic METHANOL-D4, >=99.8 ATOM % D, CONTAINS & MethanolD4>99.8%(+0.03%tms) MethanolD4>99.8%10x0.75ml MethanolD4>99.96%10x0.75ml MethanolD4>99.8%10X0.6ml Tetradeuterio-methanol Methanol-D4 "100%" >99.95 Atom % D Methanol-D4 >99.5 Atom % D Methanol-d4, 100%(Isotopic) Methyl-d3 alcohol d, Tetradeuteromethanol (1,1,1,O-2H4)Methanol (O-2H,2H3)Methanol Methanol-d4,for NMR,packaged in 0.50 ml ampules, 100.0 atom % D Methanol-d4,for NMR,contains 0.03 v/v% TMS, 99.8% atom% D Methanol-d4,for NMR,packaged in 0.75 ml ampules, 99.8 atom % D