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Manganese chloride

CAS No.
7773-01-5
Chemical Name:
Manganese chloride
Synonyms
MnCl2;MANGANESE(II) CHLORIDE;MANGANOUS CHLORIDE;MANGANESE DICHLORIDE;MANGANESE CHLORIDE ANHYDROUS;Manganese(II) chloride, anhydrous, ampuled under argon, 99.99% trace metals basis;Sacchite;scacchite;Mangatrace;anese(II) chL
CBNumber:
CB0128551
Molecular Formula:
Cl2Mn
Molecular Weight:
125.84
MDL Number:
MFCD00011114
MOL File:
7773-01-5.mol
MSDS File:
SDS
Last updated:2024-12-18 13:37:16

Manganese chloride Properties

Melting point 652 °C (lit.)
Boiling point 1190 °C
Density 2.98 g/mL at 25 °C (lit.)
vapor pressure 0Pa at 20℃
Flash point 1190°C
storage temp. 2-8°C
solubility H2O: soluble
form flakes
Specific Gravity 2.98
color Pink
Water Solubility 723 g/L (25 ºC)
Sensitive Hygroscopic
Crystal Structure CdCl2 type
crystal system Three sides
Merck 14,5728
Space group R3m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.3710.3711.7690901200.2098
Exposure limits ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
Stability Stable, but moisture sensitive. Incompatible with strong acids, reactive metals, hydrogen peroxide.
InChIKey GLFNIEUTAYBVOC-UHFFFAOYSA-L
CAS DataBase Reference 7773-01-5(CAS DataBase Reference)
FDA 21 CFR 184.1446; 582.5446; 582.80
SCOGS (Select Committee on GRAS Substances) Manganous chloride
EWG's Food Scores 2
FDA UNII QQE170PANO
NCI Drug Dictionary manganese chloride
NIST Chemistry Reference Manganese dichloride(7773-01-5)
EPA Substance Registry System Manganese chloride (MnCl2) (7773-01-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H318-H373-H411
Precautionary statements  P260-P273-P280-P301+P310-P305+P351+P338-P314
Hazard Codes  Xn
Risk Statements  22-52-48/22-25
Safety Statements  45-61-22-36
RIDADR  UN 3288 6.1/PG 3
WGK Germany  1
RTECS  OO9625000
TSCA  Yes
HazardClass  6.1
HS Code  28273990
Hazardous Substances Data 7773-01-5(Hazardous Substances Data)
Toxicity LD50 in mice, rats (mg/kg): 1330.0, 1470.0 orally; 126.0, 147.0 i.p.; 171.0, 92.6 i.v. (Singh, Junnarkar)
NFPA 704
0
3 1

Manganese chloride price More Price(47)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 48795 Manganese(II) chloride 0.1 M solution 7773-01-5 1mL $73.4 2024-03-01 Buy
Sigma-Aldrich 244589 Manganese(II) chloride powder and chunks, ≥99% trace metals basis 7773-01-5 10g $63.2 2024-03-01 Buy
Sigma-Aldrich 244589 Manganese(II) chloride powder and chunks, ≥99% trace metals basis 7773-01-5 50g $212 2024-03-01 Buy
Alfa Aesar 011868 Manganese(II) chloride, 97% 7773-01-5 2kg $74.65 2024-03-01 Buy
Alfa Aesar 011868 Manganese(II) chloride, 97% 7773-01-5 10kg $282 2023-06-20 Buy
Product number Packaging Price Buy
48795 1mL $73.4 Buy
244589 10g $63.2 Buy
244589 50g $212 Buy
011868 2kg $74.65 Buy
011868 10kg $282 Buy

Manganese chloride Chemical Properties,Uses,Production

Physical Properties

The anhydrous chloride is a pink solid; cubic crystals; deliquescent; density 2.977 g/cm3 at 25°C; melts at 650°C; vaporizes at 1,190°C; very soluble in water (~72g/100 mL at 25°C); soluble in alcohol; insoluble in ether.
The tetrahydrate has a rose color; monoclinic crystal structure; deliquescent; density 2.01 g/cm3; melts at 58°C; loses one molecule of water at 106°C and all water at 198°C; highly soluble in water (151 g/100mL at 8°C) and extremely soluble in boiling water (656 g/100mL at 100°C); soluble in ethanol; insoluble in ether.

Uses

Manganese(II) chloride is used in dyeing and printing textiles and as a disinfectant. It also is used in dry cell batteries; for the preparation of drying agents for paints and varnishes; as a catalyst in chlorination reactions; in the production of several manganese salts, including methylcyclopentadienylmanganese tricarbonyl used as a colorant for brick. In metallurgy, the compound is used as an alloying agent and is added to molten magnesium to produce magnesium-manganese alloys.

Preparation

Manganese(II) chloride is prepared by heating manganese(II) oxide, manganese dioxide, manganese(II) carbonate or manganese(II) hydroxide with hydrochloric acid:
MnO2 + 4HCl → MnCl2 + 2H2O + Cl2
MnCO3 + HCl → MnCl2 + H2O + CO2
When the product mixture is evaporated below 58°C, the tetrahydrate salt, MnCl2•4H2O is obtained.
Manganese(II) chloride is a by-product in the manufacture of chlorine from manganese dioxide and hydrochloric acid (the Weldon process).
Anhydrous chloride can be prepared by heating manganese(II) oxide or manganese(II) carbonate with dry hydrogen chloride; or by burning the metal in chlorine at 700°C to 1,000°C.
The anhydrous salt can also be obtained by slowly heating the tetrahydrate, MnCl2•4H2O in a rotary drier above 200°C or by dehydration in a stream of hydrogen chloride gas.

Reactions

Manganese(II) chloride forms double salts with alkali metal chlorides when mixed in stoichiometric amounts. Such double salts, which can decompose in water, may have compositions like KMnCl3 or K2MnCl4.
Manganese(II) chloride forms adducts with ammonia, hydroxylamine and many other nitrogen compounds. Many adducts are stable at ordinary temperatures. Examples are MnCl2•6NH3 and MnCl2•2NH2OH.
An aqueous solution can readily undergo double decomposition reactions with soluble salts of other metals, producing precipitates of insoluble salts of Mn(II) or other metals.

Description

Manganese, an essential nutrient, occurs in many foods of plant and animal origin. The naturally occurring manganese levels vary from about 2 0 ppm in nuts, cereals, dried fruits and non-leafy vegetables to less than 1 ppm in animal products. Manganous chloride tetrahydrate is pink translucent crystals which are very soluble in water.1 .

Chemical Properties

MnCl2 is rose-colored deliquescent crystals that are very soluble in water,and melts at 650°C and boils at 1190°C. The tetrahedral form, MnCI2.4H20 , melts at 58°C and loses its water at 198°C and is used as a catalyst in paints,dyes,pharmaceuticals, and fertilizers, and for various other purposes.

Uses

Used mainly in the production of dry cell batteries

Uses

A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.1 Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.2

Uses

Manganese chloride (MnCl2) is used in the pharmaceutical industry as a dietary supplement and is added to fertilizers.

Uses

Manganese Chloride is a source of manganese that functions as a nutrient and dietary supplement. it exists as crystals which are readily soluble in room temperature (22°c) water and are very soluble in hot water. see manganese.

General Description

Manganese (II) chloride (MnCl2) might play a key role in integrin activation. Manganese is indispensable for brain function and is an essential cofactor for several key enzymes like superoxide dismutase and enzymes involved in neurotransmitter synthesis. Manganese can modulate iron and calcium homeostasis. Manganese is also used in the magnetic resonance imaging to increase contrast while examining neuronal connections and brain cytoarchitecture. High levels of manganese is toxic to central nervous system and causes Parkinson′s like symptoms called as manganism. MnCl2 has been used in reverse transcription reaction mix to enhance the template-switching efficiency.

Safety Profile

Poison by intraperitoneal, subcutaneous, intramuscular, intravenous, and parenteral routes. Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. Explosive reaction when heated with zinc foil. Reacts violently with potassium or sodium. When heated to decomposition it emits toxic fumes of Cl-. See also MANGANESE COMPOUNDS and CHLORIDES.

Purification Methods

It crystallises from water (0.3mL/g) on cooling. The red-rose tetrahydrate melts at ~52o and forms the dihydrate salt which loses all its H2O at 198o to give MnCl2. It is soluble in EtOH.

Manganese chloride Preparation Products And Raw materials

Global( 301)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8807 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-81148696 +86-15536356810 1022@dideu.com China 3882 58
Hebei Fengjia New Material Co., Ltd
+86-0311-87836622 +86-17333973358 sales06@hbduling.cn China 8051 58
Shandong Juchuang Chemical Co., LTD
+undefined15030412209 admin@juchuangchem.com China 387 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3002 58
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
+8615350851019 admin@86-ss.com China 1001 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Tianjin Zhongxin Chemtech Co., Ltd.
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Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58

View Lastest Price from Manganese chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Manganese Chloride pictures 2024-12-24 Manganese Chloride
7773-01-5
US $120.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
Manganese chloride pictures 2024-12-23 Manganese chloride
7773-01-5
US $990.00-800.00 / ton 1ton 99% 5000 HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Manganese chloride pictures 2024-10-28 Manganese chloride
7773-01-5
US $1.00 / KG 1KG 99% 10 mt Hebei Weibang Biotechnology Co., Ltd
  • Manganese chloride pictures
  • Manganese chloride
    7773-01-5
  • US $990.00-800.00 / ton
  • 99%
  • HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Manganese chloride Spectrum

Manganese(II) chloride anhydrous crystalline≥ 97% (Assay, metal basis) MANGANESE CHLORIDE scacchite MANGANESE(II) CHLORIDE, ANHYDROUS, BEADS , -10 MESH, 99.999% MANGANESE(II) CHLORIDE, ANHYDROUS, BEADS , -10 MESH, 99.99% MANGANESE(II) CHLORIDE, BEADS, 98% MANGANESE(II) CHLORIDE, FLAKES, 97% MANGANESE ATOMIC SPECTROSCOPY STD. CONC. 1.00 G MN, AMPOULE Manganese(II) chloride 0.1 M Solution MANGANESE(II) CHLORIDE, 99+% MANGANESE ATOMIC SPECTROSCOPY STD. CONC. 10.00 G MN, AMPOULE MANGANESE CHLORIDE 99%MIN MANGANESE (II) CHLORIDE ANHYDROUS 99.99% MANGANESE (II) CHLORIDE ANHYDROUS 99% MANGANESE (II) CHLORIDE, ULTRA DRY, 99.998% (METALS BASIS) MANGANESE CHLORIDE 4N Manganese(II)chloride,anhydrous,96.8% Manganese(II)chloride,ultradry,99.99%(metalsbasis) Manganese(II) chloride, anhydrous, 80 mesh, 99+% MANGANESE CHLORIDE ANHYDROUS, BEADS MANGANESE CHLORIDE ANHYDROUS, POWDER Manganese(II)chloride,anhydrous,97% manganese atomic spectroscopy standard concentrate 1.00 g mn manganese standard concentrate 10.00 g mn manganese(ii) chloride solution manganese(ii) chloride, ultra dry manganese(ii)chloride solution Manganese(II) chloride anhydrous, beads, -10 Mesh, 99.99% trace Metals basis Manganese(II) chloride anhydrous, beads, -10 Mesh, 99.999% trace Metals basis Manganese(II) chloride powder and chunks, >=99% trace Metals basis Additive Screening Solution 26/Fluka kit no 78374 Manganese atomic spectroscopy standard concentrate 10.00 g Mn Manganese cllloride Manganese Chloride (AS) Sacchite Manganese(II) chloride, anhydrous, 80 mesh Dichloromanganese(II) Manganese(II) dichloride Manganese(II) chloride,97% Manganese(II) chloride,99+%,anhydrous, 80 mesh MANGANESE(II) CHLORIDE FOR SYNTHESIS Manganese(II) chloride, anhydrous, 80 Mesh, 99+% 10GR Manganese(II) chloride, anhydrous, 80 Mesh, 99+% 50GR di-manganesechlorid Manganese bichloride Manganese bister Manganese chloride (MnCl2) Manganese(II) chloride (1:2) manganese(ii)chloride(1:2) manganesebichloride manganesechloride(mncl2) Manganous chloride, manganese dichloride Manganouschloride,anhydrous Mangatrace Manganese(II) chloride (1:2): (Manganous chloride) anese(II) chL Manganese(II) chloride anhydrous (99.995%-Mn) PURATREM manganese(2+):dichloride