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METHYL OXALYL CHLORIDE

CAS No.
5781-53-3
Chemical Name:
METHYL OXALYL CHLORIDE
Synonyms
Methyl 2-chloro-2-oxoacetate;METHYL CHLOROOXOACETATE;Methyl (Chlorocarbonyl)formate;METHYL CHLOROGLYOXYLATE;MONO-METHYL OXALYL CHLORIDE;Kelex-103;orocarbonyL;Methyl Oxalyl Choride;Methyleoxalyl chloride;METHYL OXALYL CHLORIDE
CBNumber:
CB0177645
Molecular Formula:
C3H3ClO3
Molecular Weight:
122.51
MDL Number:
MFCD00000705
MOL File:
5781-53-3.mol
MSDS File:
SDS
Last updated:2024-08-17 21:30:02

METHYL OXALYL CHLORIDE Properties

Boiling point 118-120 °C (lit.)
Density 1.332 g/mL at 25 °C (lit.)
refractive index n20/D 1.419(lit.)
Flash point 116 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Ethyl Acetate
form Liquid
color Clear
Odor Acrid
Water Solubility Miscible with water.
Sensitive Moisture Sensitive
BRN 1071541
Stability Hygroscopic
InChIKey ZXUQEPZWVQIOJE-UHFFFAOYSA-N
CAS DataBase Reference 5781-53-3(CAS DataBase Reference)
FDA UNII 42Z6XG83RQ
EPA Substance Registry System Acetic acid, chlorooxo-, methyl ester (5781-53-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H226-H314-H335
Precautionary statements  P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  C,F
Risk Statements  34-37-10-36-14
Safety Statements  26-36/37/39-45-16
RIDADR  UN 2920 8/PG 2
WGK Germany  3
9-21
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29171900
NFPA 704
2
3 0
W

METHYL OXALYL CHLORIDE price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 151440 Methyl chlorooxoacetate 96% 5781-53-3 5g $56 2024-03-01 Buy
Sigma-Aldrich 151440 Methyl chlorooxoacetate 96% 5781-53-3 10g $93.5 2024-03-01 Buy
TCI Chemical C1561 Methyl Chloroglyoxylate >98.0%(GC)(T) 5781-53-3 25g $116 2024-03-01 Buy
TCI Chemical C1561 Methyl Chloroglyoxylate >98.0%(GC)(T) 5781-53-3 250g $459 2024-03-01 Buy
Alfa Aesar L13258 Methyl oxalyl chloride, 97% 5781-53-3 5g $44.5 2024-03-01 Buy
Product number Packaging Price Buy
151440 5g $56 Buy
151440 10g $93.5 Buy
C1561 25g $116 Buy
C1561 250g $459 Buy
L13258 5g $44.5 Buy

METHYL OXALYL CHLORIDE Chemical Properties,Uses,Production

Uses

Methyl oxalyl chloride is an important organic intermediate (building block) to synthetize substituted methyl oxalyl products. It can be used for regioselective synthesis of fused coumarins, cyclization to form substituted isoxazoles and heterocycles, intramolecular Wittig reactions, silyl enol ether acylation, and iron-mediated cleavage of C-C bonds.

Chemical Properties

CLEAR LIQUID

Uses

Reactant involved in:

  • Regioselective synthesis of fused coumarins
  • Cyclization to form substituted isoxazoles and heterocycles
  • Intramolecular Wittig reactions
  • Silyl enol ether acylation
  • Iron-mediated cleavage of C-C bonds

Uses

Methyl oxalyl chloride is used as a synthetic reagent. It serves as a reagent in the synthesis of fused coumarins, substituted isoxazoles and heterocycles. Further, it is used in intramolecular Wittig reactions, and iron-mediated cleavage of C-C bonds.

67-56-1
79-37-8
5781-53-3
Synthesis of METHYL OXALYL CHLORIDE from Methanol and Oxalyl chloride
Global( 260)Suppliers
Supplier Tel Email Country ProdList Advantage
Ningxia Jinhua Chemical Co.,Ltd
025-52279164 info@nxjhchem.com China 79 58
Zhejiang Kinso Technology Co., LTD.
+8619857958369 sales@kinsopharma.com China 54 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12840 58
airuikechemical co., ltd.
+undefined86-15315557071 sales02@sdzhonghuimaterial.com China 983 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18779 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32957 60
Anhui Royal Chemical Co., Ltd.
+86-25-86655873 +8613962173137 marketing@royal-chem.com China 193 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29884 58
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8812 58

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  • Feb 18,2020

View Lastest Price from METHYL OXALYL CHLORIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl Oxalyl Chloride pictures 2024-10-15 Methyl Oxalyl Chloride
5781-53-3
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
Methyl Oxalyl Choride pictures 2024-08-17 Methyl Oxalyl Choride
5781-53-3
US $6.00 / kg 1kg 0.99 10000 Hebei Fengjia New Material Co., Ltd
Methyl oxalyl chloride pictures 2024-07-12 Methyl oxalyl chloride
5781-53-3
US $0.00-0.00 / KG 1KG 99% 10000kg Zhejiang Kinso Technology Co., LTD.
CHLOROGLYOXYLIC ACID METHYL ESTER METHYL CHLOROFORMYLFORMATE METHYL CHLOROGLYOXALATE METHYL OXALYL CHLORIDE Acetic acid,2-chloro-2-oxo-, Methyl ester Oxalyl chloride MonoMethyl ester Grass single Methyl chloride Methyl chlorooxoacetate 96% Acetic acid, chlorooxo-, methyl ester Methyl chloroglyoxylate for synthesis Methyleoxalyl chloride chlorogyloxylicacidmethylester chlorooxo-aceticacimethylester METHYL CHLOROOXOACETATE,96% Methyloxalylchloride,97% Oxalic acid monomethyl ester chloride Methyl chloroglyoxalate, Methyl oxalyl chloride, Monomethyl oxalyl chloride Methyl chloroglyoxalate, Methyl oxalyl chloride (Oxalic acid 1-methyl) chloride 2-Chloroglyoxylic acid methyl ester 2-Oxo-2-chloroacetic acid methyl ester Chlorooxoacetic acid methyl ester Oxochloroacetic acid methyl ester Methyl oxalyl chloride ,98% Methyl chlorooxoacetate ,97% Chloroglyoxylic Acid Methyl Ester Methyl Oxalyl Chloride Methyl Oxalyl Choride orocarbonyL Methyl Chloroglyoxylate > Chloroglyoxylic Acid Methyl Ester,>98% MONO-METHYL OXALYL CHLORIDE METHYL CHLOROGLYOXYLATE METHYL CHLOROOXOACETATE Methyl 2-chloro-2-oxoacetate Methyl (Chlorocarbonyl)formate Kelex-103 Foscarbidopa Impurity 9 5781-53-3 C3H3ClO3 ClCOCOOCH3 ACID CHLORIDE Synthetic Reagents Others Oxidation Organics