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(R)-MOP

(R)-MOP structure

CAS No.: 145964-33-6

Chemical Name:: (R)-MOP

Synonyms: (R)-MOP;R-MOP >=94%;(R)-(+)-MOP;98% (R)-MOP;99% (R)-MOP;(R)-(+)-2-(DiphenyL;phosphino)-2'-methoxy-1,1'-binaphthyL;(S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL

CBNumber:: CB0180962

Molecular Formula:: C33H25OP

Molecular Weight:: 468.52

MDL Number:: MFCD00269686

MOL File:: 145964-33-6.mol

MSDS File:: SDS

Last updated:2023-06-08 17:06:33

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(R)-MOP Properties

Melting point	177-179°C
alpha	+67° ±2° (c 1, toluene)
Boiling point	584.1±38.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
solubility	almost transparency in Toluene
form	Powder
color	white
optical activity	[α]20/D +94°, c = 0.5 in chloroform
Sensitive	air sensitive
CAS DataBase Reference	145964-33-6(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS05,GHS07
Signal word	Danger
Hazard statements	H302-H315-H318-H335
Precautionary statements	P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P330-P332+P313-P362-P403+P233-P405-P501
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
HS Code	2931.90.6000

(R)-MOP price More Price(31)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	D2774	(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl >98.0%(GC)	145964-33-6	1g	$699	2024-03-01	Buy
TCI Chemical	D2774	(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl >98.0%(GC)	145964-33-6	100mg	$144	2024-03-01	Buy
Strem Chemicals	15-1775	(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP	145964-33-6	100mg	$99	2024-03-01	Buy
Strem Chemicals	15-1775	(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP	145964-33-6	500mg	$396	2024-03-01	Buy
TRC	R600000	(R)-MOP	145964-33-6	100mg	$220	2021-12-16	Buy

Product number	Packaging	Price	Buy
D2774	1g	$699	Buy
D2774	100mg	$144	Buy
15-1775	100mg	$99	Buy
15-1775	500mg	$396	Buy
R600000	100mg	$220	Buy

(R)-MOP Chemical Properties,Uses,Production

Uses

(R)-MOP is used as a catalyst in the preparation of chiral tetrahydrobenzofuranone alkylideneboronates and oxindoles. Also used as a catalyst in the total synthesis of Oseltamivir Phosphate (O701000); an orally active inhibitor of influenza virus neuraminidase and an antiviral drug.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Ligand used in palladium-catalyzed asymmetric hydrosilylation of olefins, palladium-catalyzed reduction of allylic esters, rhodium-catalyzed asymmetric addition reactions, and asymmetric amination reactions catalyzed by copper(I) complexes.

Reactions

1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters.
3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes.
4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins.
5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction.
Reactions of 145964-33-6

General Description

R-MOP is a phosphine ligand with a bis-naphthalene backbone.

(R)-MOP Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-MOP Suppliers

Global( 118)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	403	58
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29880	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49374	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5600	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	China	52849	58
Zhuoer Chemical Co., Ltd	02120970332; +8613524231522	sales@zhuoerchem.com	China	2904	58
changzhou huayang technology co., ltd	+8615250961469	2571773637@qq.com	China	9725	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418684 +8618949823763	sales@tnjchem.com	China	25356	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49734	58

Supplier	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	58
career henan chemical co	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Richest Group Ltd	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Zhuoer Chemical Co., Ltd	58
changzhou huayang technology co., ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	58

View Lastest Price from (R)-MOP manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2021-08-12	(R)-MOP 145964-33-6	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2021-07-02	(R)-(+)-2-Diphenylphosphino-2"-methoxy-1,1"-binaphthyl 145964-33-6	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2019-08-09	(R)-MOP 145964-33-6	US $1.00 / KG	1KG	98%	1kg,5kg,100kg	Career Henan Chemical Co

(R)-MOP
145964-33-6
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(R)-(+)-2-Diphenylphosphino-2"-methoxy-1,1"-binaphthyl
145964-33-6
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(R)-MOP
145964-33-6
US $1.00 / KG
98%
Career Henan Chemical Co

145964-33-6((R)-MOP)Related Search:

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4-MOP,5-MOP 1,1'-BINAPHTHYL 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine MOP ANTI-MOP3, HUMAN, 15AA NEAR CT

ANTI-MOP3 MOP3, HUMAN, 15AA NEAR CT MOUSE ANTI-8-METHOXYPSORALEN (8MOP) MONOADDUCTS ANTI-MOP3, 22AA NEAR NT MOP4, HUMAN, 15AA INTERNAL DOMAIN

ANTI-MOP4, HUMAN, 15AA INTERNAL DOMAIN MOP3, 22AA NEAR NT ANTI-MOP4

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R-MOP >=94% [(R)-2'-Methoxy[1,1'-binaphthalen]-2-yl]diphenylphosphine,99%e.e. (R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL (S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL (R)-(+)-MOP (R)-MOP (S)-(-)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL (S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL (R)-(+)-2-(diphenylphosphino)-2’-methoxy-21,1’-binaphthyl(r-mop) (R)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl (R)-MOP (R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl,99%(R)-MOP (R)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine 98% (R)-MOP [(1R)-2'-METHOXY[1,1'-BINAPHTHALEN]-2-YL]DIPHENYL-PHOSPHINE Phosphine, [(1R)-2'-methoxy[1,1'-binaphthalen]-2-yl]diphenyl- phosphino)-2'-methoxy-1,1'-binaphthyL 99% (R)-MOP (R)-(+)-2-(DiphenyL (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl> (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl (R)-(2’-Methoxy-[1,1’-binaphthalen]-2-yl)diphenylphosphine (R)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl (R)-MOP 145964-33-6 Chiral Phosphine API intermediates Chiral Reagents