ChemicalBook >> CAS DataBase List >>6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN

6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN

CAS No.
149646-83-3
Chemical Name:
6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
Synonyms
(R,R)-CHIRAPHITE;(2R,4R)-Chiraphite;6,6’-[(2R,4R)-Pentane-2,4-diylbis(oxy)]bis(4,8-di-tert-butyl-2,10-dimethoxydibenzo[d,f][1,3,2]dioxaphosphepine);6,6’-[(2R,4R)-Pentane-2,4-diylbis(oxy)]bis(4,8-di-tert-butyl-2,10-dimethoxydibenzo[d,f][1,3,2]dioxaphosphepine);6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN;(+)-6,6'-([(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin;(+)-6,6-([(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin];(+)-6,6'-{[(1r,3r)-1,3-dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin;(+)-6,6''-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin];Dibenzo[d,f][1,3,2]dioxaphosphepin, 6,6'-[[(1R,3R)-1,3-dimethyl-1,3-propanediyl]bis(oxy)]bis[4,8-bis(1,1-dimethylethyl)-2,10-dimethoxy-
CBNumber:
CB0188953
Molecular Formula:
C49H66O10P2
Molecular Weight:
876.99
MDL Number:
MFCD06798296
MOL File:
149646-83-3.mol
Last updated:2023-05-04 15:13:11

6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN Properties

alpha +35.4° (c 1.0, CH2Cl2)
Boiling point 816.6±65.0 °C(Predicted)
form Powder
color off-white
Sensitive air sensitive, moisture sensitive
CAS DataBase Reference 149646-83-3

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Risk Statements  36/37/38
Safety Statements  26-36/37/39

6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-1455 (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin], min. 95% (R,R)-Chiraphite 149646-83-3 100mg $102 2024-03-01 Buy
Strem Chemicals 15-1455 (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin], min. 95% (R,R)-Chiraphite 149646-83-3 500mg $412 2024-03-01 Buy
American Custom Chemicals Corporation ING0001105 (+)-6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(TERT-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN 95.00% 149646-83-3 100MG $625.78 2021-12-16 Buy
American Custom Chemicals Corporation ING0001105 (+)-6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(TERT-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN 95.00% 149646-83-3 500MG $865.9 2021-12-16 Buy
BLDpharm BD635816 (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin] 98% 149646-83-3 50mg $107 2021-12-16 Buy
Product number Packaging Price Buy
15-1455 100mg $102 Buy
15-1455 500mg $412 Buy
ING0001105 100MG $625.78 Buy
ING0001105 500MG $865.9 Buy
BD635816 50mg $107 Buy

6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN Chemical Properties,Uses,Production

Reaction

Useful catalyst for the asymmetric hydroformylation of olefins under mild conditions. High enantioand regioselectivities have been demonstrated for several prochiral vinylarenes, and a wide variety of functional groups can be tolerated. Reactions of 149646-83-3

6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN Preparation Products And Raw materials

Raw materials

Preparation Products

6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN Suppliers

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149646-83-3(6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN)Related Search:

6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN (R,R)-CHIRAPHITE (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin],min.95%(R,R)-Chiraphite 4,8-ditert-butyl-6-[(2R,4R)-4-(4,8-ditert-butyl-2,10-dimethoxybenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxypentan-2-yl]oxy-2,10-dimethoxybenzo[d][1,3,2]benzodioxaphosphepine (+)-6,6'-([(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin Dibenzo[d,f][1,3,2]dioxaphosphepin, 6,6'-[[(1R,3R)-1,3-dimethyl-1,3-propanediyl]bis(oxy)]bis[4,8-bis(1,1-dimethylethyl)-2,10-dimethoxy- (2R,4R)-Chiraphite (+)-6,6'-{[(1R,3R)-1,3-DiMethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-diMethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin] (R,R)-Chiraphite (+)-6,6-([(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin] (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin], (R,R)-Chiraphite 6,6’-[(2R,4R)-Pentane-2,4-diylbis(oxy)]bis(4,8-di-tert-butyl-2,10-dimethoxydibenzo[d,f][1,3,2]dioxaphosphepine) (+)-6,6'-{[(1r,3r)-1,3-dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin (+)-6,6''-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin] 6,6’-[(2R,4R)-Pentane-2,4-diylbis(oxy)]bis(4,8-di-tert-butyl-2,10-dimethoxydibenzo[d,f][1,3,2]dioxaphosphepine) 149646-83-3 C49H66O10P2 Chiral Phosphine