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(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole structure

CAS No.: 148461-16-9

Chemical Name:: (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole

Synonyms: (S)-t-BuPHOX;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97%;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline,98%;(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole;(S)-4-(tert-Butyl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole;(S)-4-(tert-butyl)-2-(2-(diphenylphosphanyl)phenyl)-4,5-dihydrooxazole;(S)-4-(tert-butyl)-2-(2-(diphenylphosphaneyl)phenyl)-4,5-dihydrooxazole;2-[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]phenyl]-diphenylphosphane;(4S)-4-tert-butyl-2-[2-(diphenylphosphanyl)phenyl]-4,5-dihydro-1,3-oxazole

CBNumber:: CB02093048

Molecular Formula:: C25H26NOP

Molecular Weight:: 387.45

MDL Number:: MFCD09998277

MOL File:: 148461-16-9.mol

MSDS File:: SDS

Last updated:2024-04-03 15:02:13

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(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Properties

Melting point	111-116 °C
Boiling point	498.9±28.0 °C(Predicted)
storage temp.	-20°C
pka	4.44±0.70(Predicted)
optical activity	[α]22/D -57.0°, c = 1 in chloroform
InChI	InChI=1S/C25H26NOP/c1-25(2,3)23-18-27-24(26-23)21-16-10-11-17-22(21)28(19-12-6-4-7-13-19)20-14-8-5-9-15-20/h4-17,23H,18H2,1-3H3/t23-/m1/s1
InChIKey	DMOLTNKQLUAXPI-HSZRJFAPSA-N
SMILES	O1C[C@H](C(C)(C)C)N=C1C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P280-P301+P312-P302+P352-P305+P351+P338
Safety Statements	24/25
WGK Germany	3
HS Code	29319090

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole price More Price(24)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	688495	(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97%	148461-16-9	500mg	$414	2024-03-01	Buy
Sigma-Aldrich	688495	(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97%	148461-16-9	100mg	$83.7	2023-06-20	Buy
TRC	B789620	(S)-t-BuPHOX	148461-16-9	10mg	$150	2021-12-16	Buy
TRC	B789620	(S)-t-BuPHOX	148461-16-9	50mg	$695	2021-12-16	Buy
ChemScene	CS-0029503	(S)-t-BuPHOX ≥97.0%	148461-16-9	250mg	$199	2021-12-16	Buy

Product number	Packaging	Price	Buy
688495	500mg	$414	Buy
688495	100mg	$83.7	Buy
B789620	10mg	$150	Buy
B789620	50mg	$695	Buy
CS-0029503	250mg	$199	Buy

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Chemical Properties,Uses,Production

Uses

(S)-4-Tert-Butyl-2-(2-(Diphenylphosphino)Phenyl)-4,5-Dihydrooxazole (cas# 148461-16-9) is a useful research chemical.

Chemical Properties

Colorless solid

Uses

(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline can be used as a ligand for enantioselective Heck reaction without any C=C double bond migration byproduct. It can also be used in a rhodium(I)-catalyzed enantioselective desymmetrization reaction of meso-3,5-dimethyl glutaric anhydride, to form substituted syn-deoxypolypropionate fragments in a single transformation.

General Description

The product is a phosphinooxazoline (PHOX) ligand introduced by Pfaltz and coworkers. These non-symmetrical modular P,N-ligands are particularly useful in cases where double bond migration leads to undesired products or mixtures of isomers.

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Preparation Products And Raw materials

Raw materials

Preparation Products

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Suppliers

Global( 64)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18779	58
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	laboratory@coreychem.com	China	30240	58
RR Scientific LLC	+86-13917743231	sales@rrscientific.com	United States	878	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	57505	58
Amadis Chemical Company Limited	571-89925085	sales@amadischem.com	China	131957	58
Soochow Chirally Material Science and Technology Co.,Ltd	0512-66834346 17751187418	szkrl2022@126.com	China	660	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	94657	76
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44689	61
Daicel Chiral Technologies (China)CO.,LTD	021-50460086-9 15921403865	han_yajun@dctc.daicel.com	China	7191	65
Tianjin Derchemist Science & Technology Co., Ltd.	22-58627059 13920586291	zdcomcon@126.com	China	3401	50

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
Career Henan Chemica Co	58
RR Scientific LLC	58
Aladdin Scientific	58
Amadis Chemical Company Limited	58
Soochow Chirally Material Science and Technology Co.,Ltd	58
J & K SCIENTIFIC LTD.	76
Energy Chemical	61
Daicel Chiral Technologies (China)CO.,LTD	65
Tianjin Derchemist Science & Technology Co., Ltd.	50

View Lastest Price from (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2021-07-02	(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 148461-16-9	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline
148461-16-9
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

148461-16-9((4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole)Related Search:

tert-Butyl methyl ether Diphenyl-t-Butylsilanol (S)-4-benzyl-2-(quinolin-2-yl)-4,5-dihydrooxazole (4R)-4-(1,1-diMethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-Oxazole

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline (4S)-4-(1,1-Dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole (S)-4-(tert-Butyl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole (4S)-4-(1,1-Dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole,99%e.e. (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline,98% (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97% Oxazole, 4-(1,1-dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-, (4S)- 2-[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]phenyl]-diphenylphosphane (S)-4-(tert-butyl)-2-(2-(diphenylphosphanyl)phenyl)-4,5-dihydrooxazole (S)-4-(tert-butyl)-2-(2-(diphenylphosphaneyl)phenyl)-4,5-dihydrooxazole (S)-t-BuPHOX (4S)-4-tert-butyl-2-[2-(diphenylphosphanyl)phenyl]-4,5-dihydro-1,3-oxazole 148461-16-9 C25H26NOP Chiral Phosphine PHOX Series