Staphisagnine

CAS No.
60723-40-2
Chemical Name:
Staphisagnine
Synonyms
Staphisagnine;Spiro[8bH,14cH-8a,13-methano-6,14b-propano-5H,10H-cyclopropa[4a,5][1]benzopyrano[8,7-h]oxazolo[2,3-a]isoquinoline-10,9'(10'H)-[8,11]methano[10a,3,6a][1]propanyl[3]ylidene[8H]indeno[2,1-b]azocine], 1',2,2',3,3',4',5',6,6',6a,6'b,7,7',8,11,11',11'a,12,13,13a-eicosahydro-12'-methoxy-1',3',6-trimethyl-,...
CBNumber:
CB02289560
Molecular Formula:
C44H62N2O3
Molecular Weight:
666.99
MDL Number:
MOL File:
60723-40-2.mol

Staphisagnine Properties

Density 1.29±0.1 g/cm3(Predicted)
pka 9.32±0.70(Predicted)

Staphisagnine Chemical Properties,Uses,Production

Description

A further complex alkaloid of the diterpenoid class isolated from the seeds of Delphinium staphisagria, this base is obtained as a resin that cannot be crystallized. It has a specific rotation of [α]25D - 104.5° (c 2.0, C6H6 ) and the structure has been determined primarily on the basis of spectroscopic determinations.

References

Pelletier, Djarmati, Mody, Tetrahedron Lett., 1749 (1976)

Staphisagnine Preparation Products And Raw materials

Raw materials

Preparation Products

Staphisagnine Spiro[8bH,14cH-8a,13-methano-6,14b-propano-5H,10H-cyclopropa[4a,5][1]benzopyrano[8,7-h]oxazolo[2,3-a]isoquinoline-10,9'(10'H)-[8,11]methano[10a,3,6a][1]propanyl[3]ylidene[8H]indeno[2,1-b]azocine], 1',2,2',3,3',4',5',6,6',6a,6'b,7,7',8,11,11',11'a,12,13,13a-eicosahydro-12'-methoxy-1',3',6-trimethyl-,... 60723-40-2 C44H62N2O3