17β,23β-Epoxyveratraman-3β,11β-diol
- CAS No.
- 20226-97-5
- Chemical Name:
- 17β,23β-Epoxyveratraman-3β,11β-diol
- Synonyms
- Veratrobasine;17β,23β-Epoxyveratraman-3β,11β-diol;Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridine]-3,11-diol, 1,2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11,11a,11b-octadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11R,11aS,11bR)-
- CBNumber:
- CB02341349
- Molecular Formula:
- C27H41NO3
- Molecular Weight:
- 427.62
- MDL Number:
- MOL File:
- 20226-97-5.mol
17β,23β-Epoxyveratraman-3β,11β-diol Chemical Properties,Uses,Production
Description
A steroidal alkaloid of Veratrum album, the base crystallizes as colourless prisms. It has [α]20D - 126° (c 0.65, pyridine) and - 76.6° (c 0.58, EtOH). The sulphate yields colourless crystals from aqueous EtOH, m.p. 250-3°C (dec.); [α]20D° - 175° (c 0.22, 75% EtOH) and the acetyl derivative forms prisms from Me2CO with one mole of solvent. The structure has been confirmed by the total synthesis of the alkaloid.
References
Kutney et al., Intrasci. Chem. Rep., 4, 265 (1970)
17β,23β-Epoxyveratraman-3β,11β-diol Preparation Products And Raw materials
Raw materials
Preparation Products
17β,23β-Epoxyveratraman-3β,11β-diol
Veratrobasine
Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridine]-3,11-diol, 1,2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11,11a,11b-octadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11R,11aS,11bR)-
20226-97-5