(16ξ,19E)-1,2,19,20-Tetradehydro-17-hydroxycuran-16-carboxylic acid methyl ester

(16ξ,19E)-1,2,19,20-Tetradehydro-17-hydroxycuran-16-carboxylic acid methyl ester structure

CAS No.: 23924-90-5

Chemical Name:: (16ξ,19E)-1,2,19,20-Tetradehydro-17-hydroxycuran-16-carboxylic acid methyl ester

Synonyms: Preakuammicine;(16ξ,19E)-1,2,19,20-Tetradehydro-17-hydroxycuran-16-carboxylic acid methyl ester;Curan-16-carboxylic acid, 1,2,19,20-tetradehydro-17-hydroxy-, methyl ester, (16ξ,19E)- (9CI)

CBNumber:: CB02371999

Molecular Formula:: C21H24N2O3

Molecular Weight:: 352.43

MDL Number:

MOL File:: 23924-90-5.mol

Request For Quotation

(16ξ,19E)-1,2,19,20-Tetradehydro-17-hydroxycuran-16-carboxylic acid methyl ester Properties

Boiling point	500.6±50.0 °C(Predicted)
Density	1.39±0.1 g/cm3(Predicted)
pka	14.38±0.10(Predicted)

(16ξ,19E)-1,2,19,20-Tetradehydro-17-hydroxycuran-16-carboxylic acid methyl ester Chemical Properties,Uses,Production

Description

This alkaloid occurs in the seedlings of Vinca r03ea. On treatment with NaOMe it affords Akuammicine (q.v.). Reduction with NaBH4 yields a mixture of akuammicine and stemmadenine.

References

Scott, Qureshi.,J. Arner. Chern. Soc., 91, 5874 (1969)

(16ξ,19E)-1,2,19,20-Tetradehydro-17-hydroxycuran-16-carboxylic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

(16ξ,19E)-1,2,19,20-Tetradehydro-17-hydroxycuran-16-carboxylic acid methyl ester Preakuammicine Curan-16-carboxylic acid, 1,2,19,20-tetradehydro-17-hydroxy-, methyl ester, (16ξ,19E)- (9CI) 23924-90-5