ChemicalBook >> CAS DataBase List >>(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
- CAS No.
- 38345-66-3
- Chemical Name:
- (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
- Synonyms
- chirald;Oxiphene;D-OXYPHENE;chirald tm;CHIRALD(R);DEXTROOXYPHENE;α-(+)-Oxyphene;Darvon alcohol;Einecs 253-893-6;Mosher'S reagent
- CBNumber:
- CB0251222
- Molecular Formula:
- C19H25NO
- Molecular Weight:
- 283.41
- MDL Number:
- MFCD00066214
- MOL File:
- 38345-66-3.mol
- MSDS File:
- SDS
Last updated:2023-05-04 15:12:56
Melting point | 54-56 °C(lit.) |
---|---|
alpha | 21 +8.2° (c = 10 in ethanol) |
Boiling point | bp0.1 mm 138-139° |
Flash point | >230 °F |
optical activity | [α]21/D +8.2°, c = 10 in ethanol |
Merck | 13,2070 |
BRN | 2384178 |
FDA UNII | 5917USS6PV |
EPA Substance Registry System | Benzeneethanol, ?-[(1R)-2-(dimethylamino)-1-methylethyl]-?-phenyl-, (?S)- (38345-66-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302 |
Precautionary statements | P264-P270-P301+P312-P330-P501 |
WGK Germany | 3 |
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL price More Price(4)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 227404 | Chirald? 99% | 38345-66-3 | 50g | $1070 | 2023-06-20 | Buy |
Sigma-Aldrich | 227404 | Chirald? 99% | 38345-66-3 | 10g | $431 | 2022-05-15 | Buy |
American Custom Chemicals Corporation | CCH0007188 | (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL 95.00% | 38345-66-3 | 5MG | $504.8 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | CCH0007188 | (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL 95.00% | 38345-66-3 | 10G | $1575 | 2021-12-16 | Buy |
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Chemical Properties,Uses,Production
Uses
Reducing reagent in organic synthesis.
Purification Methods
Purify the hydrochloride by dissolving 1.5g in 13.5 mL of 5N HCl, heat to boiling and evaporate in a vacuum. Recrystallise the hydrochloride three times from MeOH/EtOAc giving m 189-190o, []D -33.7o (c 1, H2O) {enantiomer has +34.2o}. The hydrochloride in the minimum volume of water is basified with aqueous 5N NaOH and extracted with Et2O. The extract is dried (K2CO3) and evaporated, leaving a residue which is stored in a desiccator over solid KOH as a low melting solid. It can be recovered using these procedures from asymmetric reductions with LAH, and re-used. [Pohland & Sullivan J Am Chem Soc 77 3400 1955, Sullivan et al. J Org Chem 28 2483 1963, Beilstein 13 IV 2221.]
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 31)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29881 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
Zhejiang J&C Biological Technology Co.,Limited | +1-2135480471 +1-2135480471 | sales@sarms4muscle.com | China | 10473 | 58 |
changzhou huayang technology co., ltd | +8615250961469 | 2571773637@qq.com | China | 9725 | 58 |
Hebei Miaoyin Technology Co.,Ltd | +86-17367732028 +86-17367732028 | kathy@hbyinsheng.com | China | 3512 | 58 |
Zhengzhou Anbu Chem Co.,Ltd | +86-0371-88006763; +8615988602810 | sales@anbuchem.com | China | 2998 | 58 |
Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 52925 | 58 |
Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44688 | 61 |
Shanghai T&W Pharmaceutical Co., Ltd. | +86 21 61551611 | China | 9891 | 58 | |
MINKESH (SHANGHAI) CO., LTD. | +86-021-20980300 +86-13167252998 | sales@minkesh.com | China | 76 | 55 |
View Lastest Price from (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2019-07-06 | (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
38345-66-3
|
US $1.00 / kg | 1kg | 95%-99% | 10kg | Career Henan Chemical Co |
- (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
38345-66-3
- US $1.00 / kg
- 95%-99%
- Career Henan Chemical Co
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL Spectrum
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)MS(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)1HNMR(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)IR1(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)IR2(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)Raman
38345-66-3((2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL)Related Search:
2-S-3-R-plus-4-dimethylamino-1-2-*diphenyl-3-meth
chirald
[S-(R*,S*)]-alpha-[2-(dimethylamino)-1-methylethyl]-alpha-phenylphenethyl alcohol
DEXTROOXYPHENE
chirald tm
D-OXYPHENE
(2S,3R)-4-(DIMETHYLAMINO)-3-METHYL-1,2-DIPHENYLBUTAN-2-OL, TOLUENE SOLUTION
Dextrocarbinol base, (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol, (2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol
Dextrocarbinol base, (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol
(2S,3R)-1,2-Diphenyl-3-methyl-4-(dimethylamino)-2-butanol
(αS)-α-[(1R)-2-(Dimethylamino)-1-methylethyl]-α-phenylbenzeneethanol
(αS)-α-Phenyl-α-[(R)-1-(dimethylaminomethyl)ethyl]benzeneethanol
α-(+)-Oxyphene
Darvon alcohol
Einecs 253-893-6
Mosher'S reagent
Oxiphene
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
(2S,3R)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
(+)-(2S,3R)-4-DIMETHYLAMINO-3-METHYL-1,2-DIPHENYL-2-BUTANOL
DEXTROCARBINOL BASE
CHIRALD(R)
(2S,3R)-4-(dimethylamino)-3-methyl-1,2-diphenylbutan-2-ol
(2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol, (2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol, Dextrocarbinol base
(2S,3R)-4-(Dimethylamino)-1,2-diphe
Benzeneethanol, α-[(1R)-2-(dimethylamino)-1-methylethyl]-α-phenyl-, (αS)-
Dextropropoxyphene EP Impurity A
Propoxyphene USP Related Compound A
(2S,3R)-4-(dimethylamino)-1,2-diphenyl-3-methyl-butan-2-ol (oxyphene),
Dextropropoxyphene Hydrochloride EP Impurity A
Codeine Phosphate Impurity 14
38345-66-3
Organic Building Blocks
Chiral Building Blocks
Asymmetric Synthesis
Amino Alcohols