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ChemicalBook >> CAS DataBase List >>1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate

1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate

1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate Structure
1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate structure
CAS No.
1194050-23-1
Chemical Name:
1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate
Synonyms
(S,S)-(+)-iPr-SpinPHOX/Ir(I);1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate;(1,2,5,6-η)-1,5-Cyclooctadiene][(4S)-2-[(5S)-6-(diphenylphosphino-κP)spiro[4.4]nona-1,6-dien-1-yl]-4,5-dihydro-4-(1-methylethyl)oxazole-κN3]-(+)-Iridium(I) Tetrakis[3,5-bis(trifluoromethyl)phenyl]bor;1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate, 97% (S,S)-(COD)Ir[iPr;[(1,2,5,6-η)-1,5-Cyclooctadiene][(4S)-2-[(5S)-6- (diphenylphosphino-κP)spiro[4.4]nona-1,6-dien-1-yl]-4,5- dihydro-4-(1-methylethyl)oxazole-κN3]-(+)-Iridium(I) Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate;1,5-CYCLOOCTADIENE{(4S)-(+)-2-[(5S)-6-(DIPHENYLPHOSPHINO)SPIRO[4.4]NONA-1.6-DIEN-1-YL]-4,5-DIHYDRO-4-(I-PROPYL)OXAZOLE}IRIDIUM(I)TETRAKIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]BORATE,97%(S,S)-(COD)IR[IPR-SPINPHOX]
CBNumber:
CB02709844
Molecular Formula:
C67H51BF24IrNOP
Molecular Weight:
1576.11
MDL Number:
MFCD25372947
MOL File:
1194050-23-1.mol
Last updated:2023-04-23 13:52:06
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1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate Properties

Melting point 201-203°C
alpha +77.6° (c 1.0, CHCl3)
form Powder
color red-orange
Sensitive air sensitive
CAS DataBase Reference 1194050-23-1

1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate Chemical Properties,Uses,Production

Reaction

Highly efficient catalyst for the enantioselective hydrogenation of a diverse class of ketimines and α,β-unsaturated substrates. Reactions of 1194050-23-1

1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate Preparation Products And Raw materials

Raw materials

Preparation Products

1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate Suppliers

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J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 7177 65
Greenherbs Science and Technology Development Co., Ltd. 010-61136123 pub02@greenherbs.com.cn China 4049 58
Beijing Minruida Technology Co., Ltd. 010-82387566 18001021521; sales@mreda.com.cn China 21450 58
Shenzhen Polymeri Biochemical Technology Co., Ltd. 400-+86-400-002-6226 sales@rrkchem.com China 56077 58
Energy Chemical 021-58432009 400-005-6266 marketing1@energy-chemical.com China 44843 58
Nantong Hanfang Biotechnology Co. , Ltd. 18616537568 hanfangpharma@126.com China 30968 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Daicel Chiral Technologies (China)CO.,LTD 65
Greenherbs Science and Technology Development Co., Ltd. 58
Beijing Minruida Technology Co., Ltd. 58
Shenzhen Polymeri Biochemical Technology Co., Ltd. 58
Energy Chemical 58
Nantong Hanfang Biotechnology Co. , Ltd. 58
1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate, 97% (S,S)-(COD)Ir[iPr [(1,2,5,6-η)-1,5-Cyclooctadiene][(4S)-2-[(5S)-6- (diphenylphosphino-κP)spiro[4.4]nona-1,6-dien-1-yl]-4,5- dihydro-4-(1-methylethyl)oxazole-κN3]-(+)-Iridium(I) Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate 1,5-CYCLOOCTADIENE{(4S)-(+)-2-[(5S)-6-(DIPHENYLPHOSPHINO)SPIRO[4.4]NONA-1.6-DIEN-1-YL]-4,5-DIHYDRO-4-(I-PROPYL)OXAZOLE}IRIDIUM(I)TETRAKIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]BORATE,97%(S,S)-(COD)IR[IPR-SPINPHOX] (S,S)-(+)-iPr-SpinPHOX/Ir(I) (1,2,5,6-η)-1,5-Cyclooctadiene][(4S)-2-[(5S)-6-(diphenylphosphino-κP)spiro[4.4]nona-1,6-dien-1-yl]-4,5-dihydro-4-(1-methylethyl)oxazole-κN3]-(+)-Iridium(I) Tetrakis[3,5-bis(trifluoromethyl)phenyl]bor 1,5-cyclooctadiene{(4S)-(+)-2-[(5S)-6-(diphenylphosphino)spiro[4.4]nona-1.6-dien-1-yl]-4,5-dihydro-4-(i-propyl)oxazole}iridiuM(I) tetrakis[3,5-bis(trifluoroMethyl)phenyl]borate 1194050-23-1 C67H54BF24IrNOP