ChemicalBook >> CAS DataBase List >>BUPIRIMATE

BUPIRIMATE

CAS No.
41483-43-6
Chemical Name:
BUPIRIMATE
Synonyms
-4-ol;pp588;NIMROD;nimrodt;BUPIRIMATE;BUPIRAMATE;Bupirimate 25%;Bupirimate Standard;Nimrod (Bupirimate);Atrazine Impurity 8
CBNumber:
CB0310530
Molecular Formula:
C13H24N4O3S
Molecular Weight:
316.42
MDL Number:
MFCD00055518
MOL File:
41483-43-6.mol
MSDS File:
SDS
Last updated:2024-07-31 17:39:26

BUPIRIMATE Properties

Melting point 50-51°
Boiling point 463.2±55.0 °C(Predicted)
Density 1.2120 (rough estimate)
vapor pressure 1.0 x 10-4 Pa at 25 °C
refractive index 1.6200 (estimate)
Flash point 100 °C
storage temp. 0-6°C
solubility Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
form Solid
pka 5
Water Solubility 22 mg l-1 (pH 5.2), 18 mg l-1 (pH 7.3), 17 mg l-1 (pH 9.3) at 25 °C
color White to Pale Beige
Merck 13,1482
BRN 758056
InChIKey DSKJPMWIHSOYEA-UHFFFAOYSA-N
LogP 2.700
FDA UNII MCJ121RIOI
EPA Substance Registry System Bupirimate (41483-43-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08,GHS09
Signal word  Warning
Hazard statements  H312-H317-H351-H410
Precautionary statements  P202-P261-P273-P280-P302+P352+P312-P308+P313
Hazard Codes  Xn
Risk Statements  21
Safety Statements  36/37
WGK Germany  2
RTECS  WO5970000
Toxicity LD50 orally in rats: 4000 mg/kg (Finney)

BUPIRIMATE price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 31510 Bupirimate PESTANAL 41483-43-6 250mg $76.7 2024-03-01 Buy
TRC B689635 Bupirimate,90% 41483-43-6 1g $405 2021-12-16 Buy
Usbiological 162966 Bupirimate 41483-43-6 1g $418 2021-12-16 Buy
AK Scientific M129 Bupirimate 41483-43-6 250mg $106 2021-12-16 Buy
Product number Packaging Price Buy
31510 250mg $76.7 Buy
B689635 1g $405 Buy
162966 1g $418 Buy
M129 250mg $106 Buy

BUPIRIMATE Chemical Properties,Uses,Production

Uses

Bupirimate is a systemic fungicide that provides protective and curative control of powdery mildew (Podosphaera leucotricha) mainly in pome fruits, stone fruits and glasshouse roses. Other uses include berries, vines and cucurbits.

Uses

Fungicide.

Uses

Bupirimate is a pyrimidine based fungicide with protective and curative activity for the control of fungal diseases by interfearing with nucleic acid synthesis.

Definition

ChEBI: A member of the class of aminopyrimidines that is 2-ethylaminopyrimidine carrying methyl, butyl and dimethylaminosulfooxy substituents at posiitons 4, 5 and 6 respectively.

Metabolic pathway

Bupirimate degrades rapidly when exposed to sunlight. Minimal penetration of bupirimate residues in treated apples was observed. Degradation of bupirimate in/on fruit surfaces was mainly due to photolytic processes. Metabolism in plants and animals is similar and includes the initial cleavage of the dimethylsulfamate-pyrimidine linkage to yield ethirimol which is also an active fungicide. Numerous degradation products were generated from N-dealkylation, hydroxylation and conjugation reactions and the opening of the pyrimidine ring (Scheme 1).

Degradation

Bupirimate (1) is stable in dilute alkaline solution, but readily hydrolysed in dilute acidic solution. Bupirimate was rapidly decomposed in aqueous solution when exposed to sunlight (Hassall, 1982). Cleavage of the dimethylsulfamate-pyrimidine linkage yielded ethirimol [5-butyl-2- ethylamino-6-methylpyrimidin-4-ol (2)] as the major product. Ethirimol, an active fungicide, was degraded slowly under these test conditions. Four additional minor products were also detected. Three of these products were identified aS isomers of bupirimate, resulting from the migration of the dimethylsulfamate moiety to the various nitrogen molecules (compounds 3, 4 and 5; Cavell and Lincoln, 1974; Teal and Skidmore, 1976).

13360-57-1
23947-60-6
41483-43-6
Synthesis of BUPIRIMATE from Dimethylsulfamoyl chloride and ETHIRIMOL

BUPIRIMATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 120)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaanxi Dideu Medichem Co. Ltd
18192627656 1012@dideu.com China 3002 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12840 58
Qingdao Trust Agri Chemical Co.,Ltd
+8613573296305 aroma@qdtrustagri.com China 301 58
Henan Bao Enluo International TradeCo.,LTD
+86-17331933971 +86-17331933971 deasea125996@gmail.com China 2472 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8812 58
Xiamen AmoyChem Co., Ltd
+86-86-5926051114 +8618959220845 sales@amoychem.com China 6383 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29811 58

View Lastest Price from BUPIRIMATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
bupirimate pictures 2024-08-27 bupirimate
41483-43-6
US $0.00 / kg 1kg 99 20tons qingdao trust agri chemical co.,ltd
mersalyl pictures 2024-07-17 mersalyl
41483-43-6
US $1.00-100.00 / KG 1KG 95% 300KG Shaanxi Dideu Medichem Co. Ltd
1-5-ANHYDRO-D-MANNITOL CRYSTALLINE pictures 2024-07-17 1-5-ANHYDRO-D-MANNITOL CRYSTALLINE
41483-43-6
US $1.00-100.00 / KG 1KG 95% 200000KG Shaanxi Dideu Medichem Co. Ltd
  • bupirimate pictures
  • bupirimate
    41483-43-6
  • US $0.00 / kg
  • 99
  • qingdao trust agri chemical co.,ltd
  • mersalyl pictures
  • mersalyl
    41483-43-6
  • US $1.00-100.00 / KG
  • 95%
  • Shaanxi Dideu Medichem Co. Ltd
BUPIRIMATE PESTANAL, 250 MG Sulfamic acid, dimethyl-, 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl ester bupirimate (bsi,iso,ansi) BUPIRAMATE 5-Butyl-2-ethylamino-6-methylpyrimidin-4-yl dimethylsulfamate 5-BUTYL-2-ETHYLAMINO-6-METHYLPYRIMIDIN-4-YL-DIMETHYLSULPHAMATE BUPIRIMATE Dimethylsulfamic acid 5-butyl-2-ethylamino-6-methylpyrimidin-4-yl ester N,N-Dimethylamidosulfuric acid 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl ester N,N-Dimethylsulfamic acid 5-butyl-2-(ethylamino)-6-methylpyrimidin-4-yl ester NIMROD 2-aethylamino-5-butyl-4-yl-dimethylsulfamat -4-ol dimethyl-sulfamicaci5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinylester dimethylsulfamicacid5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinylester n,n-dimethyl-sulfamicaciesterwith5-butyl-2-ethylamino-6-methylpyrimidin nimrodt pp588 Bupirimate 25% Bupirimate @100 μg/mL in Methanol Bupirimate Standard BupirimateSolution,100mg/L,1ml Bupirimate@1000 μg/mL in Methanol Sulfamic acid, N,N-dimethyl-, 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl ester Nimrod (Bupirimate) Ethyl phenol sulfonate Atrazine Impurity 8 Bupirimate in Acetone Bupirimate 10 μg/ml Ethyl acetate Bupirimate 10.0 μg/ml Acetonitrile Bupirimate 100 μg/ml Ethyl acetate C10850000 Bupirimate XA10850000ALBupirimatE100μg/mLin Acetonitril 41483-43-6 41983-43-6 BI - BZBuilding Blocks PyrimidinesPesticides A-BAlphabetic Alpha sort B Fungicides Heterocyclic Building Blocks Pesticides&Metabolites Pyrimidines