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Piperonyl acetone

Piperonyl acetone Structure
Piperonyl acetone structure
CAS No.
55418-52-5
Chemical Name:
Piperonyl acetone
Synonyms
DULCINYL;4-(benzo[d][1,3]dioxol-5-yl)butan-2-one;PIPERONYLACETONE;FEMA 2701;HELIOTROPYL ACETONE;Piperonylacetone>Piperonyl acetone USP/EP/BP;4-(3,4-methylenedioxyphenyl)-2;3,4-METHYLENEDIOXYBENZYL ACETONE;4-(1,3-benzodioxol-5-yl)-2-butanon
CBNumber:
CB0328014
Molecular Formula:
C11H12O3
Molecular Weight:
192.21
MDL Number:
MFCD00016910
MOL File:
55418-52-5.mol
MSDS File:
SDS
Last updated:2024-06-22 07:31:40
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Piperonyl acetone Properties

Melting point 49-54 °C(lit.)
Boiling point 176 °C17 mm Hg(lit.)
Density 1.175±0.06 g/cm3(Predicted)
refractive index 1.52-1.522
FEMA 2701 | 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE
Flash point >230 °F
storage temp. 4°C
solubility Chloroform (Slightly), DMSO (Slightly)
form Solid
color Colourless crystals.
Odor at 10.00 % in dipropylene glycol. sweet raspberry heliotrope powdery cotton candy
Odor Type floral
JECFA Number 2048
BRN 169843
InChIKey TZJLGGWGVLADDN-UHFFFAOYSA-N
LogP 1.53
Substances Added to Food (formerly EAFUS) 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE
CAS DataBase Reference 55418-52-5(CAS DataBase Reference)
FDA UNII 081VVC9H34
NIST Chemistry Reference 4-(3,4-Methylenedioxyphenyl)-2-butanone(55418-52-5)
EPA Substance Registry System 2-Butanone, 4-(1,3-benzodioxol-5-yl)- (55418-52-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Safety Statements  22-24/25
WGK Germany  2
TSCA  Yes
HS Code  2914.19.0000
Toxicity The acute oral LD50 value in rats was reported as 4Og/kg and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Wohl, 1974).
NFPA 704
1
0 0

Piperonyl acetone price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich S114162 4-BENZO(1,3)DIOXOL-5-YL-BUTAN-2-ONE Aldrich 55418-52-5 100mg $179 2024-03-01 Buy
TCI Chemical P1089 Piperonylacetone >98.0%(GC) 55418-52-5 25g $123 2024-03-01 Buy
Alfa Aesar L06258 4-(3,4-Methylenedioxy)phenyl-2-butanone, 98% 55418-52-5 5g $42.65 2024-03-01 Buy
Alfa Aesar L06258 4-(3,4-Methylenedioxy)phenyl-2-butanone, 98% 55418-52-5 25g $153.65 2024-03-01 Buy
TRC P475345 PiperonylAcetone 55418-52-5 2.5g $75 2021-12-16 Buy
Product number Packaging Price Buy
S114162 100mg $179 Buy
P1089 25g $123 Buy
L06258 5g $42.65 Buy
L06258 25g $153.65 Buy
P475345 2.5g $75 Buy

Piperonyl acetone Chemical Properties,Uses,Production

Aroma

Intensely sweet, floral and very slightly woody-powdery odor reminiscent of the sweetfloral notes in Mimosa and Cassie. Also remotely reminiscent of Heliotrope.
The taste in dilutions below 50 ppm is sweet, somewhat fruity and "Cherry-pit"-like. Higher concentrations tend to show a somewhat bitter taste.

Uses in Perfume

For several decades well kept as a "secret" chemical this ketone is one of the most interest ing and successful condensation products from a perfumery point of view. Piperonyl acetone finds application in Lilac, Lily, Sweet Pea, Appleblossom, Mimosa, Cassie, Ylang-Ylang, Heliotrope, Carnation, etc. and is particularly interesting in lipstick perfumes, also because it blends well with lonones.
Piperonyl acetone finds use in flavor compositions for imitation Cherry ("pit flavor") in various fruit complexes. Occasionally as a modifier in Vanilla imitation. The concentration is about 8 to 45 ppm in finished products. The highest figures are usually in icecream, about 50 ppm.

Description

4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor. May be prepared by condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst.

Chemical Properties

4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor reminiscent of raspberry, cotton candy (i.e., candy floss) with a cassie, heliotrope association.

Occurrence

Has apparently not been reported to occur in nature.

Preparation

By condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst

Definition

ChEBI: 4-(3,4-Methylenedioxyphenyl)-2-butanone is a member of benzodioxoles.

Taste threshold values

Taste characteristics at 40 ppm: sweet, berry-like with spicy, jamy nuances

Metabolism

The oxygen-aromatic carbon link of aromatic ethers is generally biologically stable, and possible metabolites include the p-hydroxy derivative of the ether, the phenol or the p-hydroxyphenol (Williams, 1959). Ketones are not readily metabolized in the body. As a derivative of 2-butanone, piperonyl acetone might be expected to be partially reduced to the secondary alcohol and excreted as the glucuronide (Williams, 1959), since Saneyoshi (1911) isolated the glucuronide of 2-butanol from the urine of rabbits receiving methyl ethyl ketone.

Piperonyl acetone synthesis

139-85-5
55418-52-5
Synthesis of Piperonyl acetone from Protocatechualdehyde

Piperonyl acetone Preparation Products And Raw materials

Raw materials

2-Butanone, 4-(6-iodo-1,3-benzodioxol-5-yl)- 5(2H)-Isoxazolone, 4-(1,3-benzodioxol-5-ylmethyl)-3-methyl- (E)-4-(benzo[d][1,3]dioxol-6-yl)but-3-en-2-one Piperonyl alcohol Sulfuric acid
Ethyl acetate Methyl vinyl ketone Ethanol 3,4-METHYLENEDIOXYPHENYLBORONIC ACID Acetone
Piperonyl aldehyde Protocatechualdehyde

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Preparation Products

3,4-Methylenedioxyacetophenone

Piperonyl acetone Suppliers

Global( 140)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12460 58
Hebei Duling International Trade Co. LTD 		+8617333973358 sales01@hbduling.cn China 15437 58
Shandong Deshang Chemical Co., Ltd. 		+86-0531-8875-2665 +8613153039501 info@deshangchem.com China 518 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd. 		+86-19930503282 alice@crovellbio.com China 8827 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49391 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29826 58
Shaanxi Dideu Medichem Co. Ltd 		+86-29-87569266 15319487004 1015@dideu.com China 2613 58
TargetMol Chemicals Inc. 		+1-781-999-5354 +1-00000000000 marketing@targetmol.com United States 19892 58
Hefei TNJ Chemical Industry Co.,Ltd. 		0551-65418671 sales@tnjchem.com China 34571 58
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
Hebei Duling International Trade Co. LTD 		58
Shandong Deshang Chemical Co., Ltd. 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Hebei Guanlang Biotechnology Co., Ltd. 		58
CONIER CHEM AND PHARMA LIMITED 		58
career henan chemical co 		58
Shaanxi Dideu Medichem Co. Ltd 		58
TargetMol Chemicals Inc. 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58

View Lastest Price from Piperonyl acetone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Piperonyl acetone pictures 2024-07-22 Piperonyl acetone
55418-52-5
 US $8.00-5.30 / kg 1kg 99.99% 10 tons Shandong Deshang Chemical Co., Ltd.
Piperonyl acetone pictures 2024-05-30 Piperonyl acetone
55418-52-5
 US $220.00-200.00 / kg 1kg 99% 5000 tons Hebei Duling International Trade Co. LTD
Piperonyl acetone pictures 2023-08-24 Piperonyl acetone
55418-52-5
 US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
  • Piperonyl acetone pictures
  • Piperonyl acetone
    55418-52-5
  • US $8.00-5.30 / kg
  • 99.99%
  • Shandong Deshang Chemical Co., Ltd.
  • Piperonyl acetone pictures
  • Piperonyl acetone
    55418-52-5
  • US $220.00-200.00 / kg
  • 99%
  • Hebei Duling International Trade Co. LTD

Piperonyl acetone Spectrum

Piperonyl acetone(55418-52-5)MSPiperonyl acetone(55418-52-5)1HNMRPiperonyl acetone(55418-52-5)13CNMRPiperonyl acetone(55418-52-5)IR1Piperonyl acetone(55418-52-5)IR2

55418-52-5(Piperonyl acetone)Related Search:

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2-Butanone, 4-(1,3-benzodioxol-5-yl)- 4-(1,3-benzodioxol-5-yl)-2-butanon FEMA 2701 HELIOTROPYL ACETONE 3,4-METHYLENEDIOXYBENZYL ACETONE 4-BENZO[1,3]DIOXOL-5-YL-BUTAN-2-ONE 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE 4-(3,4-METHYLENDIOXYPHENYL)-2-BUTANONE 4-(1,3-BENZODIOXOL-5-YL)-2-BUTANONE 4-(1,3-Benzodioxol-5-yl)-2-butanone~3,4-(Methylenedioxy)benzylacetone 4-(1,3-benzodioxol-5-yl)butan-2-one 4-(3,4-methylenedioxyphenyl)-2 2-BUTANONE,4-(3,4-METHYLENEDIOXYPHENYL)- 4-(1,3-Benzodioxol-5-yl)butan-2-on 3 4-METHYLENEDIOXYBENZYL ACETONE 97% 4-[3,4-(Methylenebisoxy)phenyl]butan-2-one 4-(1,3-Benzodioxol-5-yl)-2-butanone 4-(3,4-Methylenedioxyphenyl)-2-butanone 4-(2H-1,3-benzodioxol-5-yl)butan-2-one Piperonylacetone> Piperonyl acetone USP/EP/BP Factory supply Piperonyl acetone CAS 55418-52-5 high quality PIPERONYLACETONE DULCINYL 4-(benzo[d][1,3]dioxol-5-yl)butan-2-one 55418-52-5 Cd1H12O3 Aromatic Ketones (substituted)