S-Methyl methanethiolsulfonate
- CAS No.
- 2949-92-0
- Chemical Name:
- S-Methyl methanethiolsulfonate
- Synonyms
- S-Methyl methanesulfonothioate;METHYL METHANETHIOLSULFONATE;S-METHYL METHANETHIOSULFONATE;METHYL METHANETHIOSULFONATE;S-METHYL METHANETHIOSULPHONATE;(methanesulfonylsulfanyl)methane;NSC 21545;dimethyl thiosulfonate;Neticonazole Impurity 14;Methanethiosulfonylmethyl
- CBNumber:
- CB0331614
- Molecular Formula:
- C2H6O2S2
- Molecular Weight:
- 126.2
- MDL Number:
- MFCD00007565
- MOL File:
- 2949-92-0.mol
- MSDS File:
- SDS
Melting point | 117.0-119.0 °C |
---|---|
Boiling point | 69-71 °C0.4 mm Hg(lit.) |
Density | 1.337 g/mL at 25 °C(lit.) |
refractive index |
n |
Flash point | 190 °F |
storage temp. | 2-8°C |
solubility | chloroform: soluble750mg + 5 ml Chloroformmg/mL, colorless to light greenish-yellow |
form | clear liquid |
color | Colorless to Red to Green |
Odor | at 0.10 % in propylene glycol. sulfurous pungent roasted |
Odor Type | sulfurous |
BRN | 1446059 |
Stability | Water Sensitive |
InChIKey | XYONNSVDNIRXKZ-UHFFFAOYSA-N |
LogP | 0.247 (est) |
CAS DataBase Reference | 2949-92-0(CAS DataBase Reference) |
EWG's Food Scores | 1 |
FDA UNII | 0906Z2356U |
NIST Chemistry Reference | S-methyl methanethiosulphonate(2949-92-0) |
EPA Substance Registry System | Methanesulfonothioic acid, S-methyl ester (2949-92-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS06,GHS07 |
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Signal word | Danger | |||||||||
Hazard statements | H227-H301+H311+H331-H315-H319 | |||||||||
Precautionary statements | P210-P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P403+P233-P405-P501 | |||||||||
Hazard Codes | Xi,Xn | |||||||||
Risk Statements | 36-36/37/38-20/21/22 | |||||||||
Safety Statements | 26-36/37/39 | |||||||||
RIDADR | 3334 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | PB2765000 | |||||||||
F | 13 | |||||||||
HazardClass | IRRITANT | |||||||||
PackingGroup | III | |||||||||
HS Code | 29309090 | |||||||||
Toxicity | mouse,LD50,intraperitoneal,9110ug/kg (9.11mg/kg),Toxicology and Applied Pharmacology. Vol. 72, Pg. 513, 1984. | |||||||||
NFPA 704 |
|
S-Methyl methanethiolsulfonate price More Price(14)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 208795 | S-Methyl methanethiosulfonate 97% | 2949-92-0 | 1g | $42.7 | 2024-03-01 | Buy |
Sigma-Aldrich | 208795 | S-Methyl methanethiosulfonate 97% | 2949-92-0 | 10g | $232 | 2024-03-01 | Buy |
TCI Chemical | M1382 | S-Methyl Methanethiosulfonate >97.0%(GC) | 2949-92-0 | 5g | $76 | 2024-03-01 | Buy |
TCI Chemical | M1382 | S-Methyl Methanethiosulfonate >97.0%(GC) | 2949-92-0 | 25g | $249 | 2024-03-01 | Buy |
Sigma-Aldrich | 64306 | S-Methyl methanethiosulfonate purum, ≥98.0% (GC) | 2949-92-0 | 1ml | $45.7 | 2024-03-01 | Buy |
S-Methyl methanethiolsulfonate Chemical Properties,Uses,Production
Chemical Properties
Light Yellow Liquid
Uses
S-Methyl methanethiosulfonate was used as sulfenylating agent for β-keto sulfoxides, methylene compounds, half-esters of malonic acids and aryl Grignard reagents. It was also used as a reagent to trap the natural thiol-disulfide state of the proteins.
Uses
S-Methyl methanethiolsulfonate is used for the rapid and selective modification of sulfhydryl groups of enzymes and it is also useful for mapping the pore-lining regions of the ryanodine receptor.
Uses
carbonyl reactive homobifunctional cross-linking reagent cleavable with periodate
Definition
ChEBI: A sulfonic acid derivative obtained by condensaton of methanesulfonic acid with methanethiol.
Synthesis Reference(s)
The Journal of Organic Chemistry, 49, p. 2281, 1984 DOI: 10.1021/jo00186a039
Synthetic Communications, 20, p. 365, 1990 DOI: 10.1080/00397919008052777
General Description
Interaction of S-methyl methanethiosulfonate (MMTS) with dipalmitoylphosphatidylcholine (DPPC) bilayers has been investigated by FTIR and surface-enhanced Raman spectroscopy.
Purification Methods
Purify it by fractional distillation under reduced pressure, IR: 1350, 750 cm-1 . [Applegate et al. J Org Chem 38 943 1973, Beilstein 4 IV 31.]
S-Methyl methanethiolsulfonate Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Hi-Tech Chemistry Corp | 0519-86626038 | yuhh@hitechem.com | CHINA | 810 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
Nanjing jinheyou Trading Co., Ltd. | 15705188088 | admin@jheyou.com | CHINA | 1268 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29811 | 58 |
Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8838 | 58 |
TargetMol Chemicals Inc. | +1-781-999-5354 +1-00000000000 | marketing@targetmol.com | United States | 32161 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
Alfa Chemistry | info@alfa-chemistry.com | United States | 2344 | 58 |
View Lastest Price from S-Methyl methanethiolsulfonate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-19 | S-Methyl methanesulfonothioate
2949-92-0
|
US $55.00-30.00 / mg | 99.59% | 10g | TargetMol Chemicals Inc. | |||
2024-04-02 | MMTS [Methyl methanethiolsulfonate]
2949-92-0
|
US $0.00 / g | 100g | >95.00% | 100g | Xian confluore Biological Technology Co., Ltd. | ||
2022-09-15 | S-Methyl methanethiolsulfonate
2949-92-0
|
US $0.00-0.00 / kg | 1kg | 98% | 10Ton | Henan Aochuang Chemical Co.,Ltd. |
- S-Methyl methanesulfonothioate
2949-92-0
- US $55.00-30.00 / mg
- 99.59%
- TargetMol Chemicals Inc.
- MMTS [Methyl methanethiolsulfonate]
2949-92-0
- US $0.00 / g
- >95.00%
- Xian confluore Biological Technology Co., Ltd.
- S-Methyl methanethiolsulfonate
2949-92-0
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.