L(-)-10-Camphorsulfonyl chloride
- CAS No.
- 39262-22-1
- Chemical Name:
- L(-)-10-Camphorsulfonyl chloride
- Synonyms
- ((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride;(1R)-(-)-10-CamphorsuL;R)-()-10-CaMphorsulfony;L(-)Camphor sulfonyl chloride;(-)-10-CAMPHORSULFONYL CHLORIDE;(-)-10-Camphorsulfonyl Chloride;(-)-CAMPHOR-10-SULFONYL CHLORIDE;L(-)-10-CAMPHORSULFONYL CHLORIDE;(+)-camphor-10-sulfonyl chloride;L-(-)-1-Camphorsulfonyl chloride
- CBNumber:
- CB0356635
- Molecular Formula:
- C10H15ClO3S
- Molecular Weight:
- 250.74
- MDL Number:
- MFCD00064155
- MOL File:
- 39262-22-1.mol
- MSDS File:
- SDS
Melting point | 66-68 °C(lit.) |
---|---|
alpha | -33 º (c=3, chloroform) |
Boiling point | 349.4±15.0 °C(Predicted) |
Density | 1.331±0.06 g/cm3(Predicted) |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | Acetone, Dichloromethane, Ethyl Acetate, Methanol |
form | Solid |
color | White |
optical activity | [α]18/D 33°, c = 3 in chloroform |
Water Solubility | Decomposes |
Sensitive | Moisture Sensitive |
BRN | 3205975 |
InChIKey | BGABKEVTHIJBIW-UHFFFAOYSA-N |
CAS DataBase Reference | 39262-22-1(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
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Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 3261 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-21 | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29147090 | |||||||||
NFPA 704 |
|
L(-)-10-Camphorsulfonyl chloride price More Price(25)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 301949 | (1R)-(?)-10-Camphorsulfonyl chloride 97% | 39262-22-1 | 5g | $65.6 | 2023-01-07 | Buy |
TCI Chemical | C1308 | (-)-10-Camphorsulfonyl Chloride >98.0%(T) | 39262-22-1 | 5g | $42 | 2024-03-01 | Buy |
TCI Chemical | C1308 | (-)-10-Camphorsulfonyl Chloride >98.0%(T) | 39262-22-1 | 25g | $168 | 2024-03-01 | Buy |
TRC | C175070 | (1R)-(?)-10-Camphorsulfonyl chloride | 39262-22-1 | 10g | $415 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | HCH0415093 | (1R)-(-)-CAMPHOR-10-SULFONYL CHLORIDE 95.00% | 39262-22-1 | 2G | $825 | 2021-12-16 | Buy |
L(-)-10-Camphorsulfonyl chloride Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powde
Uses
L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation.
Uses
A chiral derivative of Camphor.
Purification Methods
If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]
L(-)-10-Camphorsulfonyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12460 | 58 |
Hebei Duling International Trade Co. LTD | +8617333973358 | sales01@hbduling.cn | China | 15437 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8827 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29826 | 58 |
SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34571 | 58 |
Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1026@dideu.com | China | 25859 | 58 |
View Lastest Price from L(-)-10-Camphorsulfonyl chloride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-06-06 | L(-)-10-Camphorsulfonyl chloride
39262-22-1
|
US $20.00-15.00 / kg | 1kg | 99% | 5000 Ton | Hebei Duling International Trade Co. LTD | ||
2023-08-31 | L(-)-10-Camphorsulfonyl chloride
39262-22-1
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | ||
2021-09-02 | L(-)-10-Camphorsulfonyl chloride
39262-22-1
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Guanlang Biotechnology Co., Ltd. |
- L(-)-10-Camphorsulfonyl chloride
39262-22-1
- US $20.00-15.00 / kg
- 99%
- Hebei Duling International Trade Co. LTD
- L(-)-10-Camphorsulfonyl chloride
39262-22-1
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
- L(-)-10-Camphorsulfonyl chloride
39262-22-1
- US $10.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.