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SEC-BUTYLLITHIUM

SEC-BUTYLLITHIUM Structure
SEC-BUTYLLITHIUM structure
CAS No.
598-30-1
Chemical Name:
SEC-BUTYLLITHIUM
Synonyms
S-BULI;S-BUTYLLITHIUM;butan-2-yllithiuM;sec-Butyllithium solution;sec-Butyllithium, 12% (ca 1.4M) in cyclohexane/hexane, packaed in resealable septum seal bottle;SEC-BUTYLLITHIUM;LITHIUM SEC-BUTYL;sec-Buthyllithium;LITHIUM-2-BUTANIDE;Para Butyl Lithium
CBNumber:
CB0461915
Molecular Formula:
C4H9Li
Molecular Weight:
64.06
MDL Number:
MFCD00009323
MOL File:
598-30-1.mol
MSDS File:
SDS
Last updated:2024-12-18 13:37:16
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SEC-BUTYLLITHIUM Properties

Density 0.769 g/mL at 25 °C
Flash point 1 °F
storage temp. 2-8°C
form Liquid
color Clear colorless
Sensitive Air & Moisture Sensitive
BRN 3587206
Exposure limits ACGIH: TWA 100 ppm
OSHA: TWA 300 ppm(1050 mg/m3)
NIOSH: IDLH 1300 ppm; TWA 300 ppm(1050 mg/m3)
InChIKey VATDYQWILMGLEW-UHFFFAOYSA-N
CAS DataBase Reference 598-30-1(CAS DataBase Reference)
FDA UNII 5YV3GII1TB
EPA Substance Registry System Lithium, (1-methylpropyl)- (598-30-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H225-H250-H260-H304-H314-H336-H410-H252-H318-H400
Precautionary statements  P301+P310a-P303+P361+P353-P305+P351+P338-P501a-P210-P222-P223-P231+P232-P370+P378-P422
Hazard Codes  F,C,N
Risk Statements  11-15-17-34-50/53-65-67-66-51/53-14/15
Safety Statements  26-36/37/39-43-45-60-61-62-33-16
RIDADR  UN 3394 4.2/PG 1
WGK Germany  2
F  1-10
TSCA  Yes
HazardClass  4.3
PackingGroup  I
HS Code  29319090
NFPA 704
4
3 2
W

SEC-BUTYLLITHIUM price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 195596 sec-Butyllithium solution 1.4M in cyclohexane 598-30-1 50ml $56 2024-03-01 Buy
Sigma-Aldrich 195596 sec-Butyllithium solution 1.4M in cyclohexane 598-30-1 4x25ml $86.1 2024-03-01 Buy
Strem Chemicals 93-0389 s-Butyllithium, 12% in cyclohexane (1.4M) 598-30-1 0.25mole $158 2024-03-01 Buy
Strem Chemicals 93-0389 s-Butyllithium, 12% in cyclohexane (1.4M) 598-30-1 1mole $473 2024-03-01 Buy
Sigma-Aldrich 195596 sec-Butyllithium solution 1.4M in cyclohexane 598-30-1 100ml $90.5 2024-03-01 Buy
Product number Packaging Price Buy
195596 50ml $56 Buy
195596 4x25ml $86.1 Buy
93-0389 0.25mole $158 Buy
93-0389 1mole $473 Buy
195596 100ml $90.5 Buy

SEC-BUTYLLITHIUM Chemical Properties,Uses,Production

Description

sec-Butyllithium. [598-30-1], sec-C4H9Li, Mr 64.06, is a spontaneously flammable, colorless, viscous liquid that forms tetramers in hydrocarbon solvents. It is commercially available only as 12 % solution in cyclohexane and methylcyclohexane. sec-Butyllithium is more nucleophilic and decomposes more readily than n-butyllithium. A 12 % solutionin cyclohexane at 20 ℃ undergoesthermal decomposition to the extent of 1.4 % of the active material per month. The thermal decomposition yields butene gas and LiH; the latter is insoluble and responsible for the increasing turbidity of secbutyllithium solutions on prolonged storage. Therefore solutions of sec-butyllithium must be kept cool during storage and transportation.

Chemical Properties

sec-Butyllithium is a colorless crystalline solid or clear yellowish solution. It is more reactive than n-butyllithium. Its solutions are unstable and decompose about 10 to 15 times as fast as n-butyllithium under the same conditions.
sec-Butyllithium

Uses

sec-Butyllithium is used almost exclusively as a polymerization catalyst. It is more expensive than n-butyllithium and is used mainly because of its greater reactivity and faster polymerization initiation.

Preparation

sec-Butyllithium is produced by the reaction of sec-butyl chloride with lithium metal dispersion in hydrocarbon solvents. The lithium metal should contain catalytic amounts of up to 2 % sodium metal to attain a rapid reaction with the chloride and to minimize coupling. Massive substitution of sodium metal for lithium metal as is done in the preparation of n-butyllithium results in lower yields. Isopentane, hexane and cyclohexahe are typical solvents. Industrial and laboratory preparations are similar.

SEC-BUTYLLITHIUM Preparation Products And Raw materials

Raw materials

bis(1-methylpropyl)magnesium SEC-BUTYLMAGNESIUM CHLORIDE

Preparation Products

2-(TRIFLUOROMETHOXY)BENZAMIDE 2-(N,N-DIETHYLAMINOCARBONYL)PHENYLBORONIC ACID BENZOFURAN-5-BORONIC ACID 6-METHOXY-2-NAPHTHALENEBORONIC ACID Epristeride
DI-SEC-BUTYL SULFIDE 3,5-DIMETHYL-4-HEPTANONE 1H-INDAZOLE-4-CARBOXYLIC ACID 4-FLUORO-3-METHYLBENZOIC ACID 6-BROMO-2-PYRIDYL P-TOLYL KETONE

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SEC-BUTYLLITHIUM Suppliers

Global( 223)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12837 58
Hebei Yanxi Chemical Co., Ltd. 		+8617531190177 peter@yan-xi.com China 5857 58
Hebei Weibang Biotechnology Co., Ltd 		+8617732866630 bess@weibangbio.com China 18152 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 18751 58
Beijing Cooperate Pharmaceutical Co.,Ltd 		010-60279497 sales01@cooperate-pharm.com CHINA 1803 55
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58
Shenzhen Nexconn Pharmatechs Ltd 		+86-755-89396905 +86-15013857715 admin@nexconn.com China 10311 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
Chongqing Chemdad Co., Ltd 		+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
Hebei Yanxi Chemical Co., Ltd. 		58
Hebei Weibang Biotechnology Co., Ltd 		58
Shanghai Daken Advanced Materials Co.,Ltd 		58
Beijing Cooperate Pharmaceutical Co.,Ltd 		55
Henan Tianfu Chemical Co.,Ltd. 		55
career henan chemical co 		58
Shenzhen Nexconn Pharmatechs Ltd 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Chongqing Chemdad Co., Ltd 		58

View Lastest Price from SEC-BUTYLLITHIUM manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
SEC-BUTYLLITHIUM pictures 2024-10-25 SEC-BUTYLLITHIUM
598-30-1
 US $30.00-10.00 / KG 50KG 99% 500000kg Hebei Weibang Biotechnology Co., Ltd
SEC-BUTYLLITHIUM pictures 2024-10-25 SEC-BUTYLLITHIUM
598-30-1
 US $0.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
SEC-BUTYLLITHIUM pictures 2023-09-27 SEC-BUTYLLITHIUM
598-30-1
 US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
  • SEC-BUTYLLITHIUM pictures
  • SEC-BUTYLLITHIUM
    598-30-1
  • US $30.00-10.00 / KG
  • 99%
  • Hebei Weibang Biotechnology Co., Ltd

598-30-1(SEC-BUTYLLITHIUM)Related Search:

Tungsten hexacarbonyl sec-Butyllithium, 1.3M in cyclohexane, packaged under Argon in resealable ChemSeal bottles LITHIUM METHOXIDE 2-Butanol sec-Butylamine
Buntane-2-boronic acid DL-2-Octanol 2-Pentanol SEC-BUTYLBENZENE Sodium alkylbenzene sulfonate
Sodium phytate ISOBUTYLLITHIUM tert-Butyllithium Lithium bis(trimethylsilyl)amide (TRIMETHYLSILYL)METHYLLITHIUM
Aluminium tri-sec-butoxide SEC-BUTYLMAGNESIUM BROMIDE SEC-BUTYLMAGNESIUM CHLORIDE

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sec-Butyllithium, 1.0 M solution in Hexane, HySeal SEC-BUTYLLITHIUM LITHIUM-2-BUTANIDE LITHIUM SEC-BUTYL s-butyllithium（1.3M）in cyclonexane Sec-butyllithium 1.4M in cyclohexane sec-Butyllithium, 1.3M sol. in cyclohexane/hexane (92/8), AcroSeal sec-ButyllithiuM, 12% (ca 1.4M) in cyclohexane/hexane, packed in resealable septuM seal bottle sec-ButyllithiuM, 1.3 M solution in Cyclohexane/hexane, SpcSeal sec-ButyllithiuM solution 1.4M in cyclohexane sec-ButyllithiuM, 1.0 M solution in Hexane, SpcSeal (1-methylpropyl)-lithiu ButyllithiumincyclohexanecaMcolorlesslightyellow SEC-BUTYLLITHIUM SOLUTION, ~1.3 M IN CYC LOHEXANE SEC-BUTYLLITHIUM, 1.4M SOLUTION IN CYCLOHEXANE sec-Butyllithium,1Mincyclohexane sec-Butyllithium, 1.3M solution in cyclohexane/hexane (92/8) s-Butyllithium,11-12%incyclohexane(~1M) Lithium, (1-methylpropyl)- sec-butyllithium, 1.3m in cyclohexane, packaged under argon in resealable chemseal SEC-BUTYLLITHIUM,1.3MSOLUTIONINCYCLOHEXANE sec-Buthyllithium SEC-BUTYLLITHIUM: 12% (CA. 1.4M) SOL. IN CYCLOHEXANE S-BUTYLLITHIUM: 11-12% IN CYCLOHEXANE (CA. 1M) sec-Butyllithium, 1.3M in cyclohexane, packaged under Argon in resealable ChemSealTM bottles sec-Butyllithium, 12% (ca 1.4M) soln. in cyclohexane Lithium-2-butanide, s-BuLi s-Butyllithium, 12% in cyclohexane (1.4M) sec-Butyllithium1.3M sol. in cyclohexane/hexane (92/8)AcroSeal§3 (1-Methylpropyl)lithium 1-Methylpropyllithium sec-Butyllithium, 1.3M in cyclohexane, packaged under Argon in resealable ChemSeal^t bottles sec-Butyllithium,1.3M sol. in cyclohexane/hexane (92/8) sec-Butyllithium, solution in Hexane, HySeal SEC-BUTYLLITHIUM ISO 9001：2015 REACH Sec-BUTYLLITHIUM 1.5M IN CYLCOHEXANE Para Butyl Lithium S-BULI S-BUTYLLITHIUM butan-2-yllithiuM sec-Butyllithium solution sec-Butyllithium, 12% (ca 1.4M) in cyclohexane/hexane, packaed in resealable septum seal bottle 3-[Bis(trimethylsilyl)amino]phenylmagnesium Chloride 1.0 M in Tetrahydrofuran 598-30-1 C2H5CHCH3Li CH3CH2CHCH3Li Organolithium Organometallic Reagents Alkyl straight chain compounds Ionic Polymerization Initiators 25mL Sure/Seal Reagents Alkyl Chemical Synthesis Materials Science Organic Bases Organolithium Organometallic Reagents