ChemicalBook >> CAS DataBase List >>(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

CAS No.
174810-09-4
Chemical Name:
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
Synonyms
(R,R)-TROST LIGAND(NAPHTHYL);(R,R)-DACH-naphthyl Trost ligand;(R,R)-DACH-naphthyl Trost ligand 95%;(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...;N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide);N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide);(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL);(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide;1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
CBNumber:
CB0725802
Molecular Formula:
C52H44N2O2P2
Molecular Weight:
790.87
MDL Number:
MFCD02684551
MOL File:
174810-09-4.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Properties

Melting point 224-231 °C
alpha 69o (C=1 IN METHANOL)
form Powder
pka 13.43±0.40(Predicted)
color off-white
optical activity [α]20/D +69.0°, c = 1 in methanol
InChIKey VXFKMKXTPXVEMU-AWSIMMLFSA-N
CAS DataBase Reference 174810-09-4

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H302-H315-H318-H361-H370-H372-H317-H402
Precautionary statements  P501-P273-P272-P260-P270-P202-P201-P264-P280-P302+P352-P308+P311-P362+P364-P333+P313-P301+P312+P330-P305+P351+P338+P310-P405
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
HS Code  2931499090

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692778 (R,R)-DACH-naphthyl Trost ligand 95% 174810-09-4 250mg $80.4 2024-03-01 Buy
Sigma-Aldrich 692778 (R,R)-DACH-naphthyl Trost ligand 95% 174810-09-4 1g $306.6 2024-03-01 Buy
Strem Chemicals 15-0963 (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand 174810-09-4 100mg $43 2024-03-01 Buy
Strem Chemicals 15-0963 (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand 174810-09-4 500mg $157 2024-03-01 Buy
Strem Chemicals 15-0963 (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand 174810-09-4 2g $499 2024-03-01 Buy
Product number Packaging Price Buy
692778 250mg $80.4 Buy
692778 1g $306.6 Buy
15-0963 100mg $43 Buy
15-0963 500mg $157 Buy
15-0963 2g $499 Buy

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Chemical Properties,Uses,Production

Reactions

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and fluorides nucleophiles. Reactions of 174810-09-4_1
Reactions of 174810-09-4_2

Chemical Properties

white to off-white powder

Uses

Trost Ligands for Asymmetric Allylic Alkylation

947-65-9
174810-09-4
Synthesis of (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) from METHYL 2-HYDROXY-1-NAPHTHOATE

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Preparation Products And Raw materials

Global( 85)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29882 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Shaanxi Dideu Medichem Co. Ltd
18192627656 1012@dideu.com China 3002 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com China 52849 58
Henan Alfa Chemical Co., Ltd
+86-18339805032; +8618339805032 alfa4@alfachem.cn China 13227 58
changzhou huayang technology co., ltd
+8615250961469 2571773637@qq.com China 9725 58
Labnetwork lnc.
+86-27-50766799 +8618062016861 contact@labnetwork.com China 19987 58

View Lastest Price from (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)   pictures 2020-03-16 (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)
174810-09-4
US $1.00-0.00 / KG 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) pictures 2019-08-09 (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
174810-09-4
US $1.00 / KG 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co
(R,R)-TROST LIGAND(NAPHTHYL) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand (R,R)-DACH-naphthyl Trost ligand (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (R,R)-DACH-Naphthyl Trost Ligand (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide) 1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- (R,R)-DACH-naphthyl Trost ligand 95% N,N'-(1R,2R)-Cyclohexane-1,2-diylbis[2-(diphenylphosphanyl)naphthalene-1-carboxamide] 2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph... N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% ?(R,R)-DACH-Naphthyl Trost Ligand 174810-09-4 Chiral Nitrogen DACH&Trost Series