Perfluorooctanesulfonic acid
- CAS No.
- 1763-23-1
- Chemical Name:
- Perfluorooctanesulfonic acid
- Synonyms
- PFOS;PERFLUOROOCTANESULFONIC ACID;PERFLUOROOCTANESULFONIC ACID;PERFLUOROOCTANESULFONATE;PFOSA;Perfluoro(octane-1-sulfonic acid);Perfluorooctane sulfonic acid,100 ug/mL in MeOH;1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Heptadecafluorooctane-1-sulfonic acid;EF 101;HeptadecafL
- CBNumber:
- CB0745383
- Molecular Formula:
- C8HF17O3S
- Molecular Weight:
- 500.13
- MDL Number:
- MFCD00042454
- MOL File:
- 1763-23-1.mol
Melting point | 90 °C |
---|---|
Boiling point | 260 °C |
Density | 1.25 |
Flash point | 11 °C |
storage temp. | 2-8°C |
solubility | Ethanol: 10 mg/ml |
pka | -3.27±0.50(Predicted) |
BRN | 1813859 |
CAS DataBase Reference | 1763-23-1(CAS DataBase Reference) |
FDA UNII | 9H2MAI21CL |
Proposition 65 List | Perfluorooctane sulfonate (PFOS) |
EPA Substance Registry System | Perfluorooctane sulfonic acid (1763-23-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07,GHS08,GHS09 |
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Signal word | Danger | |||||||||
Hazard statements | H302-H351-H360D-H362-H372-H411 | |||||||||
Precautionary statements | P201-P202-P263-P273-P301+P312-P308+P313 | |||||||||
Hazard Codes | C,N,T,F | |||||||||
Risk Statements | 34-57-51/53-22-39/23/24/25-23/24/25-11-64-48/25-40-20/22-61 | |||||||||
Safety Statements | 26-36/37/39-45-61-36/37-16-7-53 | |||||||||
RIDADR | UN 3265 8/PG 2 | |||||||||
WGK Germany | - | |||||||||
RTECS | RG9701600 | |||||||||
Hazard Note | Corrosive | |||||||||
HS Code | 29049090 | |||||||||
NFPA 704 |
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Perfluorooctanesulfonic acid price More Price(9)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 33607 | Heptadecafluorooctanesulfonic acid solution 100 μg/mL in methanol, analytical standard | 1763-23-1 | 1ml | $127 | 2024-03-01 | Buy |
Sigma-Aldrich | 77283 | Heptadecafluorooctanesulfonic acid solution ~40% in H | 1763-23-1 | 10ml | $146 | 2023-06-20 | Buy |
Sigma-Aldrich | 77283 | Heptadecafluorooctanesulfonic acid solution ~40% in H | 1763-23-1 | 50ml | $550 | 2024-03-01 | Buy |
Matrix Scientific | 099842 | 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Heptadecafluoro-octane-1-sulfonic acid 95+% | 1763-23-1 | 5g | $609 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | HCH0026163 | HEPTADECAFLUOROOCTANESULFONIC ACID 95.00% | 1763-23-1 | 1G | $629.48 | 2021-12-16 | Buy |
Perfluorooctanesulfonic acid Chemical Properties,Uses,Production
Description
Perfluorooctanesulfonic acid or perfluorooctane sulfonate (PFOS), is a man-made fluorosurfactant and global pollutant. It is a very useful catalyst in chemical industry. It can catalyze the Intramolecular Hydroamination of Olefinic Sulfonamides in Fluorous Biphase System (FBS)1. It can also catalyze ring-opening reactions of methylenecyclopropanes with aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide2. It is useful in the nitroaldol reaction in fluorous media, which is an important improvement of the chemo-selective addition of aldehyde3.
Chemical Properties
Perfluorooctane sulfonate can exist as a liquid or a powder. It is soluble in water (NTP, 2013). Perfluorooctane sulfonate has the ability to react with strong oxidizing agents. Upon decomposition, PFOS can form carbon oxides, sulfur oxides, and hydrogen fluoride. Additional information related to the physical and chemical properties of PFOS are not currently available.
Uses
Perfluorooctane sulfonate (PFOS, 1-octanesulfonic acid, heptadecafluorooctanesulfonic acid, perfluorooctanesulfonic acid, 1-perfluorooctanesulfonic acid) is an eight-carbon compound in the perfluoroalkyl family of chemicals. Perfluorooctane sulfonate is used in a variety of applications, including textiles, leather products, cleaning products, and pesticides. Its main use was as a stain repellent on carpet, furniture, and other consumer products. 3M was the primary manufacturer of the chemical until it voluntarily phased it out in 2002 (USEPA, 2012). Perfluorooctane sulfonate is not manufactured any longer in the United States, but it can be imported for use in specific applications.
Application
Heptadecafluorooctanesulfonic acid may be used as an analytical reference standard for the determination of the analyte in water samples using solid-phase microextraction combined with high-performance liquid chromatography with electrospray-ion trap mass spectrometry.
Definition
ChEBI: Perfluorooctane-1-sulfonic acid is a perfluoroalkanesulfonic acid that is octane-1-sulfonic acid in which all seventeen of the hydrogens that are attached to carbons hvae been replaced by fluorines. It has a role as an antilipemic drug and a persistent organic pollutant. It is functionally related to an octane-1-sulfonic acid.
General Description
Heptadecafluorooctanesulfonic acid belongs to the class of perfluorinated alkyl acids and is emerging as persistent organic contaminants in the environment.
Health effects
Exposure to unsafe levels of PFOA/PFOS concentrations through drinking water may result in health effects including developmental effects to fetuses during pregnancy, cancer, liver effects, immune effects and thyroid effects.
Environmental considerations
Perfluorooctane sulfonic acid (PFOS) is one of a group of related chemicals known as perfluorinated alkylated substances (PFAS). These are also called perfluorochemicals (PFCs). This group of chemicals is commonly used in a wide range of industrial processes and is found in many consumer products. PFOS can enter groundwater from multiple sources, including sewage treatment plants, industrial sites, landfills, and places where it is used in firefighting foam such as airports, firefighter training sites, and military installations. Fish and shellfish can take up PFOS from water contaminated with the chemical.
References
[1] YAN YIN Gang Z. Heptadecafluorooctanesulfonic acid (C8F17SO3H) catalyzed intramolecular hydroamination of olefinic sulfonamides in fluorous biphase system (FBS)[J]. Journal of Fluorine Chemistry, 2007, 128 1: Pages 40-45. DOI:10.1016/j.jfluchem.2006.09.012.
[1] SHI M, CHEN Y, XU B, et al. Heptadecafluorooctanesulfonic acid catalyzed ring opening reactions of methylenecyclopropanes with aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide[J]. Green Chemistry, 2003, 1: 85-88. DOI:10.1039/B210988C.
https://www.sciencedirect.com/science/article/pii/S1566736707001240
https://www.p65warnings.ca.gov/fact-sheets/pfos-perfluorooctane-sulfonate-or-perfluorooctane-sulfonic-acid
https://19january2021snapshot.epa.gov/sites/static/files/2017-12/documents/ffrrofactsheet_contaminants_pfos_pfoa_11-20-17_508_0.pdf
https://www.health.state.mn.us/communities/environment/risk/docs/guidance/gw/pfosinfo.pdf
[1] PING QI. Aquatic predicted no-effect-concentration derivation for perfluorooctane sulfonic acid[J]. Environmental Toxicology and Chemistry, 2011, 30 4: 836-842. DOI:10.1002/etc.460.
Perfluorooctanesulfonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21663 | 55 |
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1377 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5738 | 58 |
Allfluoro pharmaceutical co. ltd. | 021-26137118 +8615821363818 | sales@allfluoro.com | China | 5791 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34571 | 58 |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23555 | 58 |
View Lastest Price from Perfluorooctanesulfonic acid manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2021-08-12 | HEPTADECAFLUOROOCTANESULFONIC ACID
1763-23-1
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | ||
2019-07-06 | HEPTADECAFLUOROOCTANESULFONIC ACID
1763-23-1
|
US $1.00 / KG | 1KG | 99% | 1ton | Career Henan Chemical Co |
- HEPTADECAFLUOROOCTANESULFONIC ACID
1763-23-1
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
- HEPTADECAFLUOROOCTANESULFONIC ACID
1763-23-1
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
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