ChemicalBook >> CAS DataBase List >>2,2,6-Trimethyl-1,4-cyclohexandion

2,2,6-Trimethyl-1,4-cyclohexandion

CAS No.
60046-49-3
Chemical Name:
2,2,6-Trimethyl-1,4-cyclohexandion
Synonyms
(6R)-Levodione;2,2,6-Trimethyl-1,4-cyclohexandion;(R)-2,2,6-trimethyl-1,4-cyclohexanedione;1,4-Cyclohexanedione, 2,2,6-trimethyl-, (6R)-
CBNumber:
CB11448374
Molecular Formula:
C9H14O2
Molecular Weight:
154.21
MDL Number:
MOL File:
60046-49-3.mol
MSDS File:
SDS
Last updated:2023-05-15 08:29:04

2,2,6-Trimethyl-1,4-cyclohexandion Properties

solubility Dichloromethane; Methanol; Ethyl Acetate;
form Solid
color Off-white

2,2,6-Trimethyl-1,4-cyclohexandion price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC L379255 (6R)-Levodione 60046-49-3 1g $175 2021-12-16 Buy
TRC L379255 (6R)-Levodione 60046-49-3 2.5g $400 2021-12-16 Buy
TRC L379255 (6R)-Levodione 60046-49-3 5g $780 2021-12-16 Buy
Product number Packaging Price Buy
L379255 1g $175 Buy
L379255 2.5g $400 Buy
L379255 5g $780 Buy

2,2,6-Trimethyl-1,4-cyclohexandion Chemical Properties,Uses,Production

Uses

(6R)-Levodione is an intermediate used in the synthesis of Xanthoxin (X742550), which is a growth inhibitor in plants.

Definition

ChEBI: Levodione is a member of the class of cyclohexanones that is cyclohexane-1,4-dionecarrying a gem-dimethyl group at position 2 and an additional methyl substituent at position 6 (the R-enantiomer). It has a role as a bacterial metabolite. It is functionally related to a cyclohexane-1,4-dione.

Purification Methods

It is obtained from fermentation and is purified by recrystallisation from diisopropyl ether. [ORD: Leuenberger et al. Helv Chim Acta 59 1832 1976.] The racemate has m 65-67o, and the 4-(4-phenyl)semicarbazone has m 218-220o (from CH2Cl2/MeOH) [Isler et al. Helv Chim Acta 39 2041 1956, Beilstein 7 IV 2032.]

1125-21-9
55058-51-0
60046-49-3
Synthesis of 2,2,6-Trimethyl-1,4-cyclohexandion from 2,6,6-Trimethyl-2-cyclohexene-1,4-dione

2,2,6-Trimethyl-1,4-cyclohexandion Preparation Products And Raw materials

2,2,6-Trimethyl-1,4-cyclohexandion Suppliers

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Ningbo Zhenyue Pharmaceutical Technology Co., Ltd 19817745290 bd@blocksynth.com China 5642 58
2,2,6-Trimethyl-1,4-cyclohexandion (R)-2,2,6-trimethyl-1,4-cyclohexanedione (6R)-Levodione 1,4-Cyclohexanedione, 2,2,6-trimethyl-, (6R)- 60046-49-3