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2-amino-6-bromobenzonitrile

CAS No.
77326-62-6
Chemical Name:
2-amino-6-bromobenzonitrile
Synonyms
3-Bromo-2-cyanoaniline;Bromo-6-amino-benzonitrile;2-AMINO-6-BROMOBENZONITRILE;Benzonitrile, 2-amino-6-bromo-;2-Amino-6-bromobenzonitrile,95%;2-Amino-6-bromobenzonitrile 97%
CBNumber:
CB11483018
Molecular Formula:
C7H5BrN2
Molecular Weight:
197.03
MDL Number:
MFCD09834769
MOL File:
77326-62-6.mol
MSDS File:
SDS
Last updated:2024-10-11 14:01:38

2-amino-6-bromobenzonitrile Properties

Melting point 152-154℃
Boiling point 343.3±32.0 °C(Predicted)
Density 1.68
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 0.74±0.10(Predicted)
form Powder
color Off-white
CAS DataBase Reference 77326-62-6

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H312-H315-H319-H332-H335
Precautionary statements  P261-P280-P304+P340-P305+P351+P338-P405-P501a
HazardClass  IRRITANT
HazardClass  6.1
HS Code  2926907090
NFPA 704
0
2 0

2-amino-6-bromobenzonitrile price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Alfa Aesar H61927 2-Amino-6-bromobenzonitrile, 95% 77326-62-6 1g $80.2 2021-12-16 Buy
Alfa Aesar H61927 2-Amino-6-bromobenzonitrile, 95% 77326-62-6 5g $319 2021-12-16 Buy
Alfa Aesar H61927 2-Amino-6-bromobenzonitrile, 95% 77326-62-6 250mg $27 2021-12-16 Buy
TRC A578790 2-Amino-6-bromobenzonitrile 77326-62-6 5g $130 2021-12-16 Buy
Matrix Scientific 066622 2-Amino-6-bromobenzonitrile 98% 77326-62-6 25g $148 2021-12-16 Buy
Product number Packaging Price Buy
H61927 1g $80.2 Buy
H61927 5g $319 Buy
H61927 250mg $27 Buy
A578790 5g $130 Buy
066622 25g $148 Buy

2-amino-6-bromobenzonitrile Chemical Properties,Uses,Production

Uses

2-amino-6-bromobenzonitrile is a versatile building block that can be used to create a range of compounds, such as 4'-methoxy-3-(phenylethynyl)-[1,1'-biphenyl]-2-carbonitrile, etc.
Substituted phenylboronic acid (6 mmol), 2-amino-6-bromobenzonitrile (5 mmol), PdCl2(PPh3)2 (35.0 mg, 0.05 mmol) and Cs2CO3 (4.89 g, 15.0 mmol) were added in CH3CN (20 mL) and H2O (1.6 mL). The reaction mixture was stirred at 80 she℃ under an argon atmosphere for 12 h. After the reaction, the mixture was cooled to room temperature and extracted with EtOAc (40 × 3 mL). The combined organic phase was washed with brine (40 mL), and dried over anhydrous MgSO4. The solvent was removed under vacuum to give the crude product C without further purification.
2-amino-6-bromobenzonitrile

References

[1] Zhou, Nengneng et al. “TBPB-initiated cascade cyclization of 3-arylethynyl-[1,1′-biphenyl]-2-carbonitriles with sulfinic acids: access to sulfone-containing cyclopenta[gh]phenanthridines?.” Organic & Biomolecular Chemistry 9 (2020): 1733–1737.

79544-27-7
77326-62-6
Synthesis of 2-amino-6-bromobenzonitrile from 2-Bromo-6-fluorobenzonitrile
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View Lastest Price from 2-amino-6-bromobenzonitrile manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Amino-6-bromobenzonitrile pictures 2022-01-15 2-Amino-6-bromobenzonitrile
77326-62-6
US $0.00 / KG 1KG 99.3% 100 tons Honest Joy Holdings Limited
2-AMINO-6-BROMOBENZONITRILE pictures 2019-07-12 2-AMINO-6-BROMOBENZONITRILE
77326-62-6
US $1.00 / KG 1KG 99% 100kg Career Henan Chemical Co

2-amino-6-bromobenzonitrile Spectrum

2-AMINO-6-BROMOBENZONITRILE 2-Amino-6-bromobenzonitrile 97% 3-Bromo-2-cyanoaniline Bromo-6-amino-benzonitrile 2-Amino-6-bromobenzonitrile,95% Benzonitrile, 2-amino-6-bromo- 77326-62-6