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ChemicalBook >> CAS DataBase List >>(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Structure
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE structure
CAS No.
136705-75-4
Chemical Name:
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
Synonyms
(S,S)-Me-duphos-r;(S,S)-ME-DUPHOS-RH;(R,R)-ME-DUPHOS-RH;1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO&;Bisdimethylphospholanobenzenecyclooctadienerhodiumtrifluoromethanesulf;(+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(-)-1,2-BIS-((2R,5R)DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(+)-1,2-Bis[(2S,5S)-dimethylphospholano)benzene(cyclooctadiene]rhodium(I) triflate,96%;(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CBNumber:
CB1171347
Molecular Formula:
C27H40F3O3P2RhS
Molecular Weight:
666.52
MDL Number:
MFCD00269862
MOL File:
136705-75-4.mol
Last updated:2023-04-23 13:52:06
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(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Properties

Melting point 136.0-154.7 °C
storage temp. Refrigerator (+4°C)
form crystal
color orange
Sensitive air sensitive, store cold
CAS DataBase Reference 136705-75-4

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  24/25-36/37-26
WGK Germany  3

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 675563 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate 97% 136705-75-4 100mg $111 2023-01-07 Buy
Sigma-Aldrich 675563 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate 97% 136705-75-4 500mg $519 2022-05-15 Buy
Strem Chemicals 45-0161 (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate, 98+% (S,S)-Me-DUPHOS-Rh 136705-75-4 100mg $125 2024-03-01 Buy
Strem Chemicals 45-0161 (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate, 98+% (S,S)-Me-DUPHOS-Rh 136705-75-4 500mg $531 2024-03-01 Buy
Strem Chemicals 45-0161 (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate, 98+% (S,S)-Me-DUPHOS-Rh 136705-75-4 2g $1725 2024-03-01 Buy
Product number Packaging Price Buy
675563 100mg $111 Buy
675563 500mg $519 Buy
45-0161 100mg $125 Buy
45-0161 500mg $531 Buy
45-0161 2g $1725 Buy

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production

Reactions

Catalyst for the enantioselective [2+2+2] cycloaddition of triynes. Reactions of 136705-75-4

Chemical Properties

orange crystalline powder

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Suppliers

Global( 29)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 52924 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30123 84
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44688 61
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 7195 65
Bide Pharmatech Ltd. 400-164-7117 13681763483 product02@bidepharm.com China 41462 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9171 60
Aikon International Limited 025-66113011 18112977050 sales01@aikonchem.com China 16027 58
Henan Weituxi Chemical Technology Co., Ltd. 0371-63284658 18135795563 2885349392@qq.com China 9996 58
Supplier Advantage
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
Alfa Aesar 84
Energy Chemical 61
Daicel Chiral Technologies (China)CO.,LTD 65
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
Alfa Chemistry 60
Aikon International Limited 58
Henan Weituxi Chemical Technology Co., Ltd. 58

136705-75-4((-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE)Related Search:

Cyclooctane Benzene (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE 1,2-BIS(PHOSPHINO)BENZENE
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE 1,5-Cyclooctadiene (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE

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(R,R)-ME-DUPHOS-RH (S,S)-ME-DUPHOS-RH (-)-1,2-BIS-((2R,5R)DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE (-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfon (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate Bisdimethylphospholanobenzenecyclooctadienerhodiumtrifluoromethanesulf 1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO& (S,S)-Me-duphos-r (+)-1,2-Bis[(2S,5S)-dimethylphospholano)benzene(cyclooctadiene]rhodium(I) triflate,96% (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate, 98+% (S,S)-Me-DUPHOS-Rh (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate,98+%(S,S)-Me-DUPHOS-Rh (+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate, 97% (+)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I)trifluoroMethanesulfonate (S,S)-Me-DUPHOS-Rh 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate 97% (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE,98+%(S,S)-ME-DUPHOS-RH 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate 136705-75-4 RhC8H12C18H28P2CF3SO3 C27H40F3O3P2RhS Hydrogenation New Products for Chemical Synthesis May/June 2007 Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents DuPhos/BPE Privileged Ligands and Complexes organometallic complex