(7S,20α)-11,12-Dimethoxy-19α-methyl-2-oxoformosanan-16-carboxylic acid methyl ester
- CAS No.
- 20497-41-0
- Chemical Name:
- (7S,20α)-11,12-Dimethoxy-19α-methyl-2-oxoformosanan-16-carboxylic acid methyl ester
- Synonyms
- Elegantine;Elegantine【Vinca】;(7S,20α)-11,12-Dimethoxy-19α-methyl-2-oxoformosanan-16-carboxylic acid methyl ester;Spiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid, 1,2,5',5'a,7',8',10',10'a-octahydro-6,7-dimethoxy-1'-methyl-2-oxo-, methyl ester, (1'S,3S,4'aS,5'aS,10'aS)-
- CBNumber:
- CB12364338
- Molecular Formula:
- C23H28N2O6
- Molecular Weight:
- 428.48
- MDL Number:
- MOL File:
- 20497-41-0.mol
(7S,20α)-11,12-Dimethoxy-19α-methyl-2-oxoformosanan-16-carboxylic acid methyl ester Chemical Properties,Uses,Production
Description
A further alkaloid of this name has been described by Russian workers from Saussurea elegans M.B. Spreng. This base is dextrorotatory with a specific rotation of [α]D+ 75.4° (c 0.87, dimethylformamide). It forms a crystalline hydrobromide with m.p. 210°C and from the structure given and the published physical constants it is clearly not identical with that earlier described from Vinca elegantissima Hort.
References
Vashimov et al., Khim. Prir. Soedin., 4, 367 (1968)
Smirnova, Vashimov, Yunusov, ibid,S, 63 (1969)
(7S,20α)-11,12-Dimethoxy-19α-methyl-2-oxoformosanan-16-carboxylic acid methyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
(7S,20α)-11,12-Dimethoxy-19α-methyl-2-oxoformosanan-16-carboxylic acid methyl ester
Elegantine
Elegantine【Vinca】
Spiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid, 1,2,5',5'a,7',8',10',10'a-octahydro-6,7-dimethoxy-1'-methyl-2-oxo-, methyl ester, (1'S,3S,4'aS,5'aS,10'aS)-
20497-41-0