6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one
- CAS No.
- 6872-64-6
- Chemical Name:
- 6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one
- Synonyms
- Neblinine;6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one;1H,6aH,17aH-Furo[2,3-b]indolizino[8,1-cd][1,4]oxazino[2,3,4-jk]carbazol-5(4H)-one, 7,7a,9,10,15,16-hexahydro-12-methoxy-9-methyl-, (3aS,6aS,7aR,9R,14bR,17aS)-
- CBNumber:
- CB12426773
- Molecular Formula:
- C23H26N2O4
- Molecular Weight:
- 394.46
- MDL Number:
- MOL File:
- 6872-64-6.mol
6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one Chemical Properties,Uses,Production
Description
Aspidosperma neblinine Monachino yields this alkaloid which forms transparent crystals from hexane. It is laevorotatory with [α]27D - 14° (c 1.19, CHC13). Catalytic reduction furnishes the dihydro derivative, m.p. 230-3°C (dec.). The structure is that of 15-demethoxyobscurinervidine.
References
Brown, Djerassi., J. Amer. Chern. Soc., 86,2451 (1964)
6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one Preparation Products And Raw materials
Raw materials
Preparation Products
6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one
Neblinine
1H,6aH,17aH-Furo[2,3-b]indolizino[8,1-cd][1,4]oxazino[2,3,4-jk]carbazol-5(4H)-one, 7,7a,9,10,15,16-hexahydro-12-methoxy-9-methyl-, (3aS,6aS,7aR,9R,14bR,17aS)-
6872-64-6