Tetrabutylammonium tetrafluoroborate
- CAS No.
- 429-42-5
- Chemical Name:
- Tetrabutylammonium tetrafluoroborate
- Synonyms
- tetrabutylammonium tetrafluoborate;TETRA-N-BUTYLAMMONIUM TETRAFLUOROBORATE;SKL1461;SKL1624;N4,4,4,4BF4;ammonium TetrafL;Tetrabutylammonium fluoborate;TETRABUTYLAMMONIUM FLUOROBORATE;TETRA-N-BUTYLAMMONIUM FLUOROBORATE;Tetrabutylazanium tetrafluoroborate
- CBNumber:
- CB1273128
- Molecular Formula:
- C16H36BF4N
- Molecular Weight:
- 329.27
- MDL Number:
- MFCD00011634
- MOL File:
- 429-42-5.mol
- MSDS File:
- SDS
Melting point | 155-161 °C(lit.) |
---|---|
Flash point | >93℃ |
storage temp. | −20°C |
solubility | methanol: 0.1 g/mL, clear, colorless |
form | Crystalline Powder |
color | White |
Water Solubility | Slightly soluble |
Sensitive | Hygroscopic |
BRN | 3577508 |
InChIKey | DWWRDPSMLREDKW-UHFFFAOYSA-M |
CAS DataBase Reference | 429-42-5(CAS DataBase Reference) |
NIST Chemistry Reference | Tetrabutylammonium tetrafluoroborate(429-42-5) |
EPA Substance Registry System | 1-Butanaminium, N,N,N-tributyl-, tetrafluoroborate(1-) (429-42-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05,GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H302-H315-H318-H335 | |||||||||
Precautionary statements | P261-P280-P305+P351+P338 | |||||||||
Hazard Codes | Xi,T,Xn | |||||||||
Risk Statements | 36/37/38-41-37/38-22 | |||||||||
Safety Statements | 26-36-37/39-39 | |||||||||
RIDADR | UN 1759 8/PG III | |||||||||
WGK Germany | 3 | |||||||||
Hazard Note | Irritant/Hygroscopic | |||||||||
TSCA | Yes | |||||||||
HazardClass | TOXIC, HYGROSCOPIC | |||||||||
PackingGroup | III | |||||||||
HS Code | 29239000 | |||||||||
NFPA 704 |
|
Tetrabutylammonium tetrafluoroborate price More Price(46)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 217964 | Tetrabutylammonium tetrafluoroborate 99% | 429-42-5 | 5g | $41.1 | 2024-03-01 | Buy |
Sigma-Aldrich | 217964 | Tetrabutylammonium tetrafluoroborate 99% | 429-42-5 | 25g | $189 | 2024-03-01 | Buy |
TCI Chemical | T0914 | Tetrabutylammonium Tetrafluoroborate >98.0%(N) | 429-42-5 | 25g | $29 | 2024-03-01 | Buy |
TCI Chemical | T0914 | Tetrabutylammonium Tetrafluoroborate >98.0%(N) | 429-42-5 | 100g | $73 | 2024-03-01 | Buy |
Alfa Aesar | A16688 | Tetra-n-butylammonium tetrafluoroborate 99% | 429-42-5 | 5g | $33.65 | 2024-03-01 | Buy |
Tetrabutylammonium tetrafluoroborate Chemical Properties,Uses,Production
Chemical Properties
WHITE FINE CRYSTALLINE POWDER
Uses
TBATFB has been used as an electrolyte to understand the paraffin graphite powder modified with sweet potato tissue (PCPET) electrode response.
Uses
Tetrabutylammonium tetrafluoroborate may be used in the following studies:
- As supporting electrolyte in the voltammetric determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC).
- Synthesis of biologically relevant macrolactones, Sansalvamide A.
- As supporting electrolyte in the determination of the oxidation and reduction potentials of 5,10,15,20-tetra[3-(3-trifluoromethyl)phenoxy]porphyrin by cyclic voltammetry.
- Preparation of 1:1 adduct with 1,10-phenanthroline.
- Used to prepare other tetrabutylammonium salts in aqueous solutions.
- As electrolyte additive in the synthesis of conducting poly(thiophenes).
General Description
Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold.
Purification Methods
Recrystallise it from H2O, aqueous EtOH or from EtOAc by cooling in Dry-ice. Also recrystallise it from ethyl acetate/pentane or dry acetonitrile. Dry it at 80o under vacuum. [Detty & Jones J Am Chem Soc 109 5666 1987, Hartley & Faulkner J Am Chem Soc 107 3436 1985.] The acetate has m 118±2o (from BuCl), the bromide has m 118o (from EtOAc) and the nitrate has m 120o (from *C6H6). [Witschonka & Kraus J Am Chem Soc 69 2472 1947, Wheeler & Sandstedt J Am Chem Soc 77 2024 1955, Beilstein 4 IV 558.]
Tetrabutylammonium tetrafluoroborate Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shaanxi Dideu Medichem Co. Ltd | 18192627656 | 1012@dideu.com | China | 1297 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12462 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 16221 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21677 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
Zjartschem | +86-571-8723 8903 jocelynpan@zjarts.com | jocelynpan@zjarts.com | CHINA | 993 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; | sales@coreychem.com | China | 29902 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8828 | 58 |
View Lastest Price from Tetrabutylammonium tetrafluoroborate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-05-14 | Tetrabutylammonium tetrafluoroborate
429-42-5
|
US $33.00-53.00 / KG | 25KG | 99% | 10000KG | Shaanxi Dideu Medichem Co. Ltd | ||
2023-09-06 | Tetrabutylammonium tetrafluoroborate
429-42-5
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | ||
2023-08-18 | Tetrabutylammonium tetrafluoroborate
429-42-5
|
US $20.00 / KG | 1KG | 99% | 50000kg | Hebei Mojin Biotechnology Co., Ltd |
- Tetrabutylammonium tetrafluoroborate
429-42-5
- US $33.00-53.00 / KG
- 99%
- Shaanxi Dideu Medichem Co. Ltd
- Tetrabutylammonium tetrafluoroborate
429-42-5
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
- Tetrabutylammonium tetrafluoroborate
429-42-5
- US $20.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
Tetrabutylammonium tetrafluoroborate Spectrum
429-42-5(Tetrabutylammonium tetrafluoroborate)Related Search:
1of4