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hexafluorophosphate

CAS No.
870987-63-6
Chemical Name:
hexafluorophosphate
Synonyms
Ir[dF(CF3)ppy]2(dtbbpy)PF6;4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine;[Ir(dtbbpy)[dF(CF3)ppy]2]PF6;4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate;(4,4'-Di-t-butyL;bis[3,5-Difluoro-2-[5-(trifluoromethyl)-2-pyridyl]phenyl]ruthenium(1+);(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) hexafluorophosphate;(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
CBNumber:
CB13303666
Molecular Formula:
C42H34F10IrN4.PF6
Molecular Weight:
1121.91
MDL Number:
MFCD27952556
MOL File:
870987-63-6.mol
Last updated:2023-05-11 17:26:00

hexafluorophosphate Properties

Melting point >300 °C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform (Slightly)
form crystal
color yellow
CAS DataBase Reference 870987-63-6

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Risk Statements  36/37/38
Safety Statements  26
TSCA  No
HS Code  2843909000

hexafluorophosphate price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 747793 (Ir[dF(CF3)ppy]2(dtbpy))PF6 870987-63-6 100mg $151 2024-03-01 Buy
Sigma-Aldrich 747793 (Ir[dF(CF3)ppy]2(dtbpy))PF6 870987-63-6 1g $998 2024-03-01 Buy
Strem Chemicals 77-0425 (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99% 870987-63-6 50mg $59 2024-03-01 Buy
Strem Chemicals 77-0425 (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99% 870987-63-6 250mg $236 2024-03-01 Buy
Strem Chemicals 77-0425 (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99% 870987-63-6 1g $764 2024-03-01 Buy
Product number Packaging Price Buy
747793 100mg $151 Buy
747793 1g $998 Buy
77-0425 50mg $59 Buy
77-0425 250mg $236 Buy
77-0425 1g $764 Buy

hexafluorophosphate Chemical Properties,Uses,Production

Reaction

  1. Visible light photoredox-catalyzed cascade cyclizations of α-bromochalcones or α-bromocinnamates with heteroarenes.
  2. Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.
Reactions of 870987-63-6

Uses

[4,?4''-?Bis(tert-butyl)?-?2,?2''-?bipyridine]?bis[3,?5-?difluoro-?2-?[5-?(trifluoromethyl)?-?2-?pyridinyl]?phenyl]?iridium(III) hexafluorophosphate is commonly used as a catalyst in the synthesis of various compounds such as saturated N-?heterocycles from aldehydes, fosmidomycin analogue, and many more.

Uses

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.

hexafluorophosphate Preparation Products And Raw materials

Raw materials

Preparation Products

hexafluorophosphate Suppliers

Global( 85)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1803 55
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 10311 58
Accela ChemBio Inc.
+1-858-6993322 info@accelachem.com United States 17777 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 11817 58
Zhejiang Free Trade Zone Violet Trade Co., Ltd.
+8618768051816; +8615858061377 jenny@zjviolettech.com China 105 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23541 58
Labnetwork lnc.
+86-27-50766799 +8618062016861 contact@labnetwork.com China 19987 58
Alfa Chemistry
Info@alfa-chemistry.com United States 24072 58
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43340 58

View Lastest Price from hexafluorophosphate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[Ir (dF (CF3) ppy)2(dtbpy)]PF6 pictures 2024-12-23 [Ir (dF (CF3) ppy)2(dtbpy)]PF6
870987-63-6
US $0.00 / g 1g 99.90% 100kgs Zhejiang Free Trade Zone Violet Trade Co., Ltd.
(Ir[dF(CF3)ppy]2(dtbpy))PF6 pictures 2024-04-02 (Ir[dF(CF3)ppy]2(dtbpy))PF6
870987-63-6
US $0.00 / g 1g >99.00% 1g Xian confluore Biological Technology Co., Ltd.
bis[3,5-Difluoro-2-[5-(trifluoromethyl)-2-pyridyl]phenyl]ruthenium(1+) (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate (4,4'-DI-T-BUTYL-2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-TRIFLUOROMETHYL-2-PYRIDINYL-KN)PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE,99% (4,4'-Di-t-butyL (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kappaN)phenyl-kappaC]iridium(III) Hexafluorophosphate (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate 4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine Ir[dF(CF3)ppy]2(dtbbpy)PF6 [Ir(dtbbpy)[dF(CF3)ppy]2]PF6 4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate Iridium(1+), [4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC]-, (OC-6-33)-, hexafluorophosphate(1-) (1:1) (OC-6-33)-[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC]-Iridium(1+) hexafluorophosphate(1-) (1:1) (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-κN)phenyl-κC]iridium(III) Hexafluorophosphate (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-κN)phenyl-κC]iridium(III) Hexafluorophosphate (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) hexafluorophosphate (OC-6-33)-[4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC]-iridium(1+) hexafluorophosphate(1-) (1:1) 870987-63-6 C42H34F16IrN4P