Tributyl(vinyl)tin
- CAS No.
- 7486-35-3
- Chemical Name:
- Tributyl(vinyl)tin
- Synonyms
- VINYLTRIBUTYLTIN;TRIBUTYLVINYLSTANNANE;TRI-N-BUTYL(VINYL)TIN;VINYLTRI-N-BUTYLTIN;TRIBUTYLETHENYLSTANNANE;SKL992;TIN VINYLTRIBUTYL;TRIBUTYL(VINYL)TIN;tribytyl(vinyl)tin;Vinyltributyltin(IV)
- CBNumber:
- CB1354865
- Molecular Formula:
- C14H30Sn
- Molecular Weight:
- 317.1
- MDL Number:
- MFCD00009421
- MOL File:
- 7486-35-3.mol
- MSDS File:
- SDS
Melting point | <0°C |
---|---|
Boiling point | 104-106 °C/3.5 mmHg (lit.) |
Density | 1.085 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | >230 °F |
storage temp. | Refrigerator |
solubility | Chloroform (Soluble), Ethyl Acetate (Sparingly) |
form | liquid |
color | Colourless |
Specific Gravity | 1.085 |
Water Solubility | Not miscible or difficult to mix in water. |
Hydrolytic Sensitivity | 1: no significant reaction with aqueous systems |
BRN | 3537662 |
Exposure limits |
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
Stability | Light sensitive |
InChIKey | QIWRFOJWQSSRJZ-UHFFFAOYSA-N |
CAS DataBase Reference | 7486-35-3(CAS DataBase Reference) |
FDA UNII | 2FA6XM467X |
NIST Chemistry Reference | Stannane, tributylethenyl-(7486-35-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS06,GHS08,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H226-H301-H312-H315-H319-H360FD-H372-H410 | |||||||||
Precautionary statements | P210-P273-P280-P301+P310-P303+P361+P353-P305+P351+P338 | |||||||||
Hazard Codes | T,N | |||||||||
Risk Statements | 21-25-36/38-48/23/25-50/53-10 | |||||||||
Safety Statements | 35-36/37/39-45-60-61 | |||||||||
RIDADR | UN 2788 6.1/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
F | 13 | |||||||||
TSCA | No | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29312000 | |||||||||
NFPA 704 |
|
Tributyl(vinyl)tin price More Price(19)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 271438 | Tributyl(vinyl)tin 97% | 7486-35-3 | 1g | $65.8 | 2024-03-01 | Buy |
Sigma-Aldrich | 271438 | Tributyl(vinyl)tin 97% | 7486-35-3 | 5g | $212 | 2024-03-01 | Buy |
Alfa Aesar | L20215 | Tri-n-butyl(vinyl)tin 96% | 7486-35-3 | 1g | $42.7 | 2023-06-20 | Buy |
Alfa Aesar | L20215 | Tri-n-butyl(vinyl)tin 96% | 7486-35-3 | 5g | $121 | 2023-06-20 | Buy |
Sigma-Aldrich | 271438 | Tributyl(vinyl)tin 97% | 7486-35-3 | 25g | $540 | 2024-03-01 | Buy |
Tributyl(vinyl)tin Chemical Properties,Uses,Production
Chemical Properties
clear colorless to pale yellow liquid
Uses
Tributyl(vinyl)tin is used as a reagent in the palladium catalyzed synthesis of allyl and benzyl ethers. It is also a vinyl nucleophile for bromoacetylene and bromoaromatics.
Application
Tributyl(vinyl)tin is used as a vinyl nucleophile in palladium-mediated cross-coupling reactions; it is sometimes used as a vinyl lithium precursor.
Preparation
Tributyl(vinyl)tin is conveniently prepared by the reaction of Vinylmagnesium Bromide with Tri-n-butylchlorostannane.
storage
Tributyl(vinyl)tin is air- and water-stable; requires no special handling or storage. Organostannanes are toxic and should only be used in a well ventilated hood. All glassware should be rinsed in a KOH/EtOH bath during cleaning
Purification Methods
Fractionate the stannane under reduced pressure and taking the middle fraction to remove impurities such as (n-Bu)3SnCl. [Seyferth & Stone J Am Chem Soc 79 515 1957, Beilstein 16 III 1279.]
Tributyl(vinyl)tin Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of2
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8806 | 58 |
Hebei Mujin Biotechnology Co.,Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12831 | 58 |
Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7711 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18940 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Tianjin Zhongxin Chemtech Co., Ltd. | 86-22-66880623 +8618622897568 | sales@tjzxchem.com | China | 569 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29879 | 58 |
Shanghai Arbor Chemical Co., Ltd. | 021-60451682 | act@arborchemical.com | CHINA | 904 | 58 |
Biochempartner | 0086-13720134139 | candy@biochempartner.com | CHINA | 965 | 58 |
Changzhou Carman Chemical Co., Ltd. | 15061933924 | CHINA | 514 | 58 |
View Lastest Price from Tributyl(vinyl)tin manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2025-01-02 | Tributylvinyltin
7486-35-3
|
US $22.00-350.00 / g | 10g | 0.99 | 100kg | Shanghai UCHEM Inc. | ||
2024-11-13 | Tributyl(vinyl)tin
7486-35-3
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Weibang Biotechnology Co., Ltd | ||
2023-07-29 | Tributyl(vinyl)tin
7486-35-3
|
US $0.00 / Kg | 1Kg | 99% | 20ton | Hebei Mujin Biotechnology Co.,Ltd |
- Tributylvinyltin
7486-35-3
- US $22.00-350.00 / g
- 0.99
- Shanghai UCHEM Inc.
- Tributyl(vinyl)tin
7486-35-3
- US $10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- Tributyl(vinyl)tin
7486-35-3
- US $0.00 / Kg
- 99%
- Hebei Mujin Biotechnology Co.,Ltd