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4-Amino-3-methylphenol

4-Amino-3-methylphenol Structure
4-Amino-3-methylphenol structure
CAS No.
2835-99-6
Chemical Name:
4-Amino-3-methylphenol
Synonyms
4-AMINO-3-METHYLPHENOL;4-AMINO-3-CRESOL;Phenol, 4-amino-3-methyl-;p-Hydroxy-o-toluidine;3-Methyl-4-aminophenol;JAROCOL 4A3MP;4-amino-meta-;Amino-M-Cresol;4-amino-cresol;4-amino-m-creso
CBNumber:
CB1365623
Molecular Formula:
C7H9NO
Molecular Weight:
123.15
MDL Number:
MFCD00007871
MOL File:
2835-99-6.mol
MSDS File:
SDS
Last updated:2024-12-18 14:07:02
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4-Amino-3-methylphenol Properties

Melting point 176-179 °C (lit.)
Boiling point 229.26°C (rough estimate)
Density 1.0877 (rough estimate)
refractive index 1.5380 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility soluble in Methanol
pka 10.34±0.18(Predicted)
form Powder
color Brown
Water Solubility insoluble
BRN 2078803
InChIKey QGNGOGOOPUYKMC-UHFFFAOYSA-N
LogP 0.51 at 22℃
CAS DataBase Reference 2835-99-6(CAS DataBase Reference)
EWG's Food Scores 3-6
FDA UNII 12R07I1K8C
NIST Chemistry Reference 4-Amino-3-methyl phenol(2835-99-6)
EPA Substance Registry System Phenol, 4-amino-3-methyl- (2835-99-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H315-H319-H400
Precautionary statements  P273-P301+P312+P330-P302+P352-P305+P351+P338
Hazard Codes  Xn
Risk Statements  22-36/37/38-20/21/22
Safety Statements  26-37/39-36/37/39-36-24/25
RIDADR  UN3077
WGK Germany  3
RTECS  GO6826000
F  8-10-23
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29222900
NFPA 704
1
2 0

4-Amino-3-methylphenol price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 144894 4-Amino-3-methylphenol 97% 2835-99-6 5g $44.4 2024-03-01 Buy
Sigma-Aldrich 144894 4-Amino-3-methylphenol 97% 2835-99-6 25g $155 2024-03-01 Buy
TCI Chemical A0288 4-Amino-m-cresol >98.0%(GC)(T) 2835-99-6 25g $58 2024-03-01 Buy
Alfa Aesar B23152 4-Amino-3-methylphenol, 98% 2835-99-6 100g $157.65 2024-03-01 Buy
TRC A898190 4-Amino-3-methylphenol 2835-99-6 50g $75 2021-12-16 Buy
Product number Packaging Price Buy
144894 5g $44.4 Buy
144894 25g $155 Buy
A0288 25g $58 Buy
B23152 100g $157.65 Buy
A898190 50g $75 Buy

4-Amino-3-methylphenol Chemical Properties,Uses,Production

Description

4-Amino-3-methylphenol is a metabolite of 3-methyl-4-nitrophenol. It is a major metabolite of carcinogenic o-toluidine and causes DNA damage in the presence of Cu(II).

Chemical Properties

Light gray powder

Uses

4-Amino-3-methylphenol is a useful reagent for the synthesis of piperidine (piperazine)-amide substituted derivatives as multi-target antipsychotics.
4-Amino-3-methylphenol was used in synthesis of a new type of tweezer-molecule in which a strongly preferred binding conformation is generated by convergent, intramolecular hydrogen bonding.

Application

4-Amino-m-cresol is used as an oxidative hair dye at a maximum concentration of 1.5% after mixing with peroxide.

Definition

ChEBI: 4-hydroxy-6-methylaniline is a substituted aniline in which the aniline ring carries 4-hydroxy and 6-methyl substituents; a urinary metabolite of lidocaine. It has a role as a drug metabolite. It is a member of phenols and a substituted aniline.

General Description

4-Amino-3-methylphenol is a metabolite of 3-methyl-4-nitrophenol. It is a major metabolite of carcinogenic o-toluidine and causes DNA damage in the presence of Cu(II).

Flammability and Explosibility

Not classified

Synthesis

The synthesis of 4-Amino-3-methylphenol is as follows:A mixture of the para-benzoquinone mono-oxime (1.26 mmol),SnCl2 (0.72 g, 3.80 mmol), 20 mL of CH2Cl2, and 0.2 mL of concentrated HCl, was heated to reflux for 16 h. The CH2Cl2 was removed under reduced pressure, and the residue was dissolved in ethyl acetate and washed with concentrated aqueous NaHCO3. The organic layer was dried over anhydrous Na2SO4 and the filtrate was concentrated under reduced pressure to afford the solid product.
synthesis of 4-Amino-m-cresol

Purification Methods

Crystallise it from 50% EtOH. [Beilstein 13 H 593, 13 IV 1698.]

4-Amino-3-methylphenol Preparation Products And Raw materials

Raw materials

Preparation Products

1H-Indazol-5-ol

4-Amino-3-methylphenol Suppliers

Global( 421)Suppliers
Supplier Tel Email Country ProdList Advantage
Taixing Foreign Trade Nanjing Co., Ltd.
+86-025-83346564; +8613182976929 sales@tx-chem.com China 122 58
Hebei Longbang Technology Co., LTD
+86-18633929156 +86-18633929156 admin@hblongbang.com China 941 58
Hebei Weibang Biotechnology Co., Ltd 		+8615531157085 abby@weibangbio.com China 8810 58
Hebei Chuanghai Biotechnology Co,.LTD 		+86-13131129325 sales1@chuanghaibio.com China 5889 58
Hebei Saisier Technology Co., LTD 		+86-18400010335 +86-18034520335 admin@hbsaisier.cn China 1015 58
HebeiShuoshengImportandExportco.,Ltd 		+86-18532138899 +86-18532138899 L18532138899@163.com China 939 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 18751 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32957 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58
Supplier Advantage
Taixing Foreign Trade Nanjing Co., Ltd.
58
Hebei Longbang Technology Co., LTD
58
Hebei Weibang Biotechnology Co., Ltd 		58
Hebei Chuanghai Biotechnology Co,.LTD 		58
Hebei Saisier Technology Co., LTD 		58
HebeiShuoshengImportandExportco.,Ltd 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58

View Lastest Price from 4-Amino-3-methylphenol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Amino-m-cresol pictures 2024-12-20 4-Amino-m-cresol
2835-99-6
 US $6.00 / kg 1kg 99% 2000KG/Month HebeiShuoshengImportandExportco.,Ltd
4-Amino-m-cresol pictures 2024-12-19 4-Amino-m-cresol
2835-99-6
 US $6.00 / kg 1kg More than 99% 2000KG/Month Hebei Longbang Technology Co., Ltd
4-Amino-m-cresol pictures 2024-11-27 4-Amino-m-cresol
2835-99-6
 US $10.00 / KG 1KG 99% 10 mt Hebei Weibang Biotechnology Co., Ltd
  • 4-Amino-m-cresol pictures
  • 4-Amino-m-cresol
    2835-99-6
  • US $6.00 / kg
  • More than 99%
  • Hebei Longbang Technology Co., Ltd

4-Amino-3-methylphenol Spectrum

4-Amino-m-cresol(2835-99-6)1HNMR4-Amino-m-cresol(2835-99-6)13CNMR4-Amino-m-cresol(2835-99-6)IR14-Amino-m-cresol(2835-99-6)Raman

2835-99-6(4-Amino-3-methylphenol )Related Search:

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2-AMINO-4-CRESOL,2-AMINO-PARA-CRESOL, 97%,O-AMINO-P-CRESOL,2-AMINO-P-CRESOL 6-NITROPIPERONAL 3-Methyl-4-nitrophenol

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4-amino-cresol 4-amino-m-creso 4-amino-m-cresol,4-hydroxy-o-toluidine,4-amino-3-methylphenol m-Cresol, 4-amino- 4-Amino-3-methylphenol,98% 4-amino-meta-cresol 4-Amino-m-cresol;4-Amino-3-methylphenol Amino-M-Cresol 4-Amino-m-methylphenol PARA-AMINO-META-CRESOL 4-AMino-M-cresol, 99+% 50GR 2-Amino-5-hydroxytoluene, 4-Amino-m-cresol, 4-Hydroxy-2-methylaniline 4-Amino-meta-cresol, 99+% 4-Amino-m-cresol,99+% 4-Amino-3-methylphenol 4-Hydroxy-2-methylaniline 4-AMINO-3-METHYLPHENOL FOR SYNTHESIS 4-AMino-3-Methylphenol, 99%, 99% 4-Amino-m-cresol C4-Amino-m-cresol 4-HYDROXY-2-METHYLANILINE 4-HYDROXY-O-TOLUIDINE 4-AMINO-M-CRESOL 2-AMINO-5-HYDROXYTOLUENE JAROCOL 4A3MP P-AMINO-M-CRESOL 2-Methyl-4-hydroxyaniline 4-amino-3-methyl-pheno 4-hydroxy-6-methylaniline 4-Amino-3-methylphenol, 98.5% 4-amino-meta- 4-Amino-m-cresol> 4-Amino-m-cresol(4AMC) Phenol, 4-amino-3-methyl- p-Hydroxy-o-toluidine 4-AMINO-3-METHYLPHENOL 4-AMINO-3-CRESOL 3-Methyl-4-aminophenol Dopexamine Impurity 13 2835-99-6 Phenols Oxygen Compounds Organic Building Blocks Building Blocks Aromatic Phenols