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Neodymium oxide

CAS No.
1313-97-9
Chemical Name:
Neodymium oxide
Synonyms
Neodymia;Neodymoxid;NEODYM OXIDE;Neodymium oxi;nedymium oxide;NEODYMIUM OXIDE;neodymiumtrioxide;neodymium(3+)oxide;Neodymium(Ⅲ) oxide;dineodymiumtrioxide
CBNumber:
CB1437511
Molecular Formula:
Nd2O3
Molecular Weight:
336.48
MDL Number:
MFCD00011134
MOL File:
1313-97-9.mol
MSDS File:
SDS
Last updated:2024-12-18 14:07:02

Neodymium oxide Properties

Melting point 2270 °C
Boiling point 3760℃[at 101 325 Pa]
Density 7.24 g/mL at 20 °C(lit.)
storage temp. no restrictions.
solubility insoluble in H2O; soluble in dilute acid solutions
form Sintered Lump
Specific Gravity 7.24
color light blue
Water Solubility insoluble
Crystal Structure La2O3 type
crystal system Three sides
Merck 14,6450
Space group P3m1
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.38290.38290.600290901200.0762
InChI InChI=1S/2Nd.3O
InChIKey HBPPDPSYLUIKHU-UHFFFAOYSA-N
SMILES O([Nd]=O)[Nd]=O
CAS DataBase Reference 1313-97-9(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII AYT3H319PN
EPA Substance Registry System Neodymium oxide (Nd2O3) (1313-97-9)

SAFETY

Risk and Safety Statements

Precautionary statements  P271-P261-P280
Hazard Codes  Xi
Safety Statements  24/25
WGK Germany  1
RTECS  QP0185000
3
TSCA  Yes
HS Code  28469013
Toxicity LD50 orally in Rabbit: > 5000 mg/kg
NFPA 704
0
1 0

Neodymium oxide price More Price(62)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 203858 Neodymium(III) oxide 99.99% trace metals basis 1313-97-9 10g $154 2024-03-01 Buy
Sigma-Aldrich 203858 Neodymium(III) oxide 99.99% trace metals basis 1313-97-9 50g $572 2024-03-01 Buy
Sigma-Aldrich 1.12276 Neodymium(III) oxide 99+ 1313-97-9 25g $69.9 2024-03-01 Buy
Alfa Aesar 011248 Neodymium(III) oxide, REacton?, 99.9% (REO) 1313-97-9 50g $97.8 2023-06-20 Buy
Alfa Aesar 011248 Neodymium(III) oxide, REacton?, 99.9% (REO) 1313-97-9 1kg $1252 2023-06-20 Buy
Product number Packaging Price Buy
203858 10g $154 Buy
203858 50g $572 Buy
1.12276 25g $69.9 Buy
011248 50g $97.8 Buy
011248 1kg $1252 Buy

Neodymium oxide Chemical Properties,Uses,Production

Chemical Properties

Neodymium Oxide, Nd2O3 is a blue-grey powder that is composed of the rare earth neodymium and oxygen. hygroscopic; absorbs atmospheric CO2; hexagonal; has slightly red fluorescence. Water insoluble, soluble in acids. It has special properties that make it very useful to the glass and ceramics industries. Neodymium Oxide gives a good aqua color in most glaze bases at 1-2%. At 4-7% it gives a pleasant lavender/grape color that appears as a different color under different artificial light sources. It is very strongly affected by iron, particularly in oxidation, giving a reliable perfect neutral transparent gray. Avoid trace iron impurities to achieve the brightest blue and lavender colors.
Neodymium Oxide

Physical properties

Blue powder; hexagonal crystals; fluoresces red; density 7.24 g/cm3; melts around 1,900°C; practically insoluble in water, 30 mg/L at 75°C; dissolves in acids.

Uses

Neodymium oxide (Nd2O3) is a light-blue powder used to color glass and as a pigment for ceramics. It is also used to make color TV tubes.

Uses

Neodymium(III) oxide is an inorganic compound containing inner transition metal neodymium from lanthanides series in +3 oxidation state and oxide in 2:3 ratio. It adopts a hexagonal crystal structure. It is also known as neodymium oxide, neodymiumtrioxide, neodymium(3+)oxide, neodymium sesquioxide and dineodymiumtrioxide. It used as ceramic capacitors, coloring glass, carbon arc-light electrodes, color TV tubes, dehydrogenation catalyst, (65%) To counteract color of iron in glass.

Production Methods

Neodymium oxide is produced from the two principal rare earth minerals, monazite, and bastnasite. The oxide is obtained as an intermediate in the recovery of neodymium metal (See Neodymium).
The oxide also may be formed by thermal dissociation of neodymium oxalate, hydroxide or carbonate:
Nd2(C2O4)3 → Nd2O3 + 6CO2
2Nd(OH)3 → Nd2O3 + 3H2O
Nd2(CO3)3 → Nd2O3 + 3CO2.

Reactions

The anhydrous oxide absorbs moisture from the air at ambient temperatures forming hydrated oxide. The oxide also absorbs carbon dioxide from air, forming neodymium carbonate.
Neodymium oxide dissolves in strong mineral acids forming corresponding neodymium salts:
Nd2O3 + 3H2SO4 → Nd2(SO4)3 + 3H2O
Reactions with acetic and other organic acids produce corresponding salts. When heated with ammonium chloride at 300 to 400°C, the oxide converts to chloride liberating ammonia and water:
Nd2O3 + 6NH4Cl → 2NdCl3 + 6NH3 + 3H2O
When heated with hydrogen fluoride, the product is neodymium fluoride:
Nd2O3 + 6HF → 2NdF3 + 3H2O
The oxide is reduced to neodymium metal when heated with hydrogen, carbon monoxide, or other reducing agents.

Flammability and Explosibility

Non flammable

Toxicology

Neodymium oxide is belong to a rare earth metal. These metals are moderately to highly toxic. The symptoms of toxicity of the rare earth elements include writhing, ataxia, labored respiration, walking on toes with arched back and sedation.

Safety Profile

Low toxicity by ingestion.

Purification Methods

Dissolve it in HClO4, precipitate it as the oxalate with doubly recrystallised oxalic acid, wash it free of soluble impurities, dry it at room temperature and ignite it in a platinum crucible at higher than 850o in a stream of oxygen. It is a blue powder. [Tobias & Garrett J Am Chem Soc 80 3532 1958.]

References

https://en.wikipedia.org/wiki/Neodymium#Neodymium_glass_for_other_applications
https://en.wikipedia.org/wiki/Neodymium(III)_oxide
https://books.google.kg/books?id=KbZkxDyeG18C&pg=PA102&dq=%22Neodymium+oxide%22&redir_esc=y#v=onepage&q=%22Neodymium%20oxide%22&f=false

Neodymium oxide Preparation Products And Raw materials

Global( 355)Suppliers
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Zhuoer Chemical Co., Ltd
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View Lastest Price from Neodymium oxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Neodymium oxide pictures 2024-12-18 Neodymium oxide
1313-97-9
US $6.00 / kg 1kg 99% 2000KG/Month HebeiShuoshengImportandExportco.,Ltd
Neodymium oxide pictures 2024-12-18 Neodymium oxide
1313-97-9
US $6.00 / KG 1KG 99% 20TONS Hebei Longbang Technology Co., Ltd
Neodymium Oxide pictures 2024-11-19 Neodymium Oxide
1313-97-9
US $60.00 / kg 1kg 99.9% 1000kg Shanghai MaiNo material technology Co.Ltd
  • Neodymium oxide pictures
  • Neodymium oxide
    1313-97-9
  • US $6.00 / kg
  • 99%
  • HebeiShuoshengImportandExportco.,Ltd
  • Neodymium oxide pictures
  • Neodymium oxide
    1313-97-9
  • US $6.00 / KG
  • 99%
  • Hebei Longbang Technology Co., Ltd
  • Neodymium Oxide pictures
  • Neodymium Oxide
    1313-97-9
  • US $60.00 / kg
  • 99.9%
  • Shanghai MaiNo material technology Co.Ltd
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