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1-METHOXY-1,3-CYCLOHEXADIENE

1-METHOXY-1,3-CYCLOHEXADIENE structure

CAS No.: 2161-90-2

Chemical Name:: 1-METHOXY-1,3-CYCLOHEXADIENE

Synonyms: 2,3-DIHYDROANISOLE;1-METHOXY-1,3-CYCLOHEXADIENE;1-methoxycyclohexa-1,3-diene;1,3-Cyclohexadiene, 1-methoxy-;1,3-Cyclohexadien-1-yl methyl ether;1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65%;1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole;1-Methoxy-1,3-cyclohexadiene technical grade, 65%

CBNumber:: CB1494725

Molecular Formula:: C7H10O

Molecular Weight:: 110.15

MDL Number:: MFCD00001533

MOL File:: 2161-90-2.mol

MSDS File:: SDS

Last updated:2023-05-25 18:01:00

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1-METHOXY-1,3-CYCLOHEXADIENE Properties

Melting point	96-97 °C
Boiling point	40 °C/15 mmHg (lit.)
Density	0.929 g/mL at 25 °C (lit.)
refractive index	n20/D 1.488(lit.)
Flash point	80 °F
LogP	1.790 (est)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS07
Signal word	Warning
Hazard statements	H226-H302+H312+H332
Precautionary statements	P210-P233-P280-P301+P312-P303+P361+P353-P304+P340+P312
Hazard Codes	Xn
Risk Statements	10-20/21/22
Safety Statements	16-33-36/37/39
RIDADR	UN 1993 3/PG 3
WGK Germany	3
HazardClass	3.2
PackingGroup	III

1-METHOXY-1,3-CYCLOHEXADIENE price More Price(1)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
American Custom Chemicals Corporation	CHM0114825	1-METHOXY-1,3-CYCLOHEXADIENE 95.00%	2161-90-2	1MG	$632.21	2021-12-16	Buy

Product number	Packaging	Price	Buy
CHM0114825	1MG	$632.21	Buy

1-METHOXY-1,3-CYCLOHEXADIENE Chemical Properties,Uses,Production

Uses

1-Methoxy-1,3-cyclohexadiene was used in the following studies:

Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 4195, 1972 DOI: 10.1016/S0040-4039(01)94273-X

General Description

1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative.

1-METHOXY-1,3-CYCLOHEXADIENE Preparation Products And Raw materials

Raw materials

Preparation Products

1-methoxycyclohexene 2-METHOXY-6-METHYLBENZOIC ACID ETHYL ESTER

1-METHOXY-1,3-CYCLOHEXADIENE Suppliers

Global( 14)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	China	52849	58
GIHI CHEMICALS CO.,LIMITED	+8618058761490	info@gihichemicals.com	China	49978	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	52924	58
3B Pharmachem (Wuhan) International Co.,Ltd.	821-50328103-801 18930552037	3bsc@sina.com	China	15839	69
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44688	61
Syntechem Co.,Ltd		info@syntechem.com	China	12984	57
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51456	80
BOC Sciences	--	info@bocsci.com	USA	0	65
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd	15229059051	1027@dideu.com	China	10003	58
Shanghai Aladdin Biochemical Technology Co.,Ltd.	+86-18521732826	market@aladdin-e.com	China	48461	58

Supplier	Advantage
Dayang Chem (Hangzhou) Co.,Ltd.	58
GIHI CHEMICALS CO.,LIMITED	58
Aladdin Scientific	58
3B Pharmachem (Wuhan) International Co.,Ltd.	69
Energy Chemical	61
Syntechem Co.,Ltd	57
Sigma-Aldrich	80
BOC Sciences	65
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd	58
Shanghai Aladdin Biochemical Technology Co.,Ltd.	58

1-METHOXY-1,3-CYCLOHEXADIENE Spectrum

1-METHOXY-1,3-CYCLOHEXADIENE(2161-90-2)¹HNMR 1-METHOXY-1,3-CYCLOHEXADIENE(2161-90-2)IR 1-METHOXY-1,3-CYCLOHEXADIENE(2161-90-2)Raman 1-METHOXY-1,3-CYCLOHEXADIENE(2161-90-2)FT-IR

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1-METHOXY-1,3-CYCLOHEXADIENE 2,3-DIHYDROANISOLE 1,3-Cyclohexadien-1-yl methyl ether 1,3-Cyclohexadiene, 1-methoxy- 1-methoxycyclohexa-1,3-diene 1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65% 1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole 1-Methoxy-1,3-cyclohexadiene technical grade, 65% 2161-90-2 Building Blocks Enol Ethers Oxygen Compounds Organic Building Blocks