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(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine

CAS No.
127184-05-8
Chemical Name:
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Synonyms
(+)-8;8AR)-8;8-Dichlorocamphorylsulfonyl)oxaziri dine;(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE;(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine;(+)-3,3-DICHLORO-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(+)-[(8,8-DICHLOROCAMPHORYL)-SULFONYL]-OXAZIRIDINE 97+%;(+)-(8,8-DichlorocaMphorylsulfonyl)oxaziridine >=97.0% (T);(1S,6R,8S)-7,7-dichloro-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione;(4aS,7S)-8,8-Dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
CBNumber:
CB1690604
Molecular Formula:
C10H13Cl2NO3S
Molecular Weight:
298.19
MDL Number:
MFCD00243015
MOL File:
127184-05-8.mol
Last updated:2024-06-03 16:17:09

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Properties

Melting point 181-186 °C
Boiling point 390.5±52.0 °C(Predicted)
Density 1.68±0.1 g/cm3(Predicted)
storage temp. 2-8°C
solubility Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form Solid
pka -15.63±0.60(Predicted)
color White to Off-White
optical activity [α]20/D +89±3°, c = 0.5% in chloroform
BRN 3653352
InChI InChI=1/C10H13Cl2NO3S/c1-7(2)6-3-4-8(7)5-17(14,15)13-10(8,16-13)9(6,11)12/h6H,3-5H2,1-2H3/t6-,8-,10+,13?/s3
InChIKey HAMBQYFZDBYWHU-XCDSEQPNNA-N
SMILES [C@@]123ON1S(=O)(=O)C[C@@]12CC[C@@]([H])(C1(C)C)C3(Cl)Cl |&1:0,7,10,r|

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS03,GHS07
Signal word  Danger
Hazard statements  H271-H315-H319-H335
Precautionary statements  P220-P261-P305+P351+P338
Safety Statements  22-24/25
RIDADR  1479
WGK Germany  3
8-10
HazardClass  5.1
PackingGroup  III

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 35603 (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine ≥97.0% (T) 127184-05-8 5G $282 2024-03-01 Buy
Sigma-Aldrich 35603 (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine ≥97.0% (T) 127184-05-8 25g $1210 2024-03-01 Buy
TRC D433990 (+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine 127184-05-8 1g $165 2021-12-16 Buy
TRC D433990 (+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine 127184-05-8 100mg $60 2021-12-16 Buy
TRC D433990 (+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine 127184-05-8 5g $385 2021-12-16 Buy
Product number Packaging Price Buy
35603 5G $282 Buy
35603 25g $1210 Buy
D433990 1g $165 Buy
D433990 100mg $60 Buy
D433990 5g $385 Buy

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Chemical Properties,Uses,Production

Chemical Properties

White Solid

Uses

Chiral oxidizing agent.

Purification Methods

Recrystallise the enantiomers from EtOH [Davis & Weismiller J Org Chem 55 3715 1990].

60886-80-8
127184-05-8
Synthesis of (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine from (1S)-(-)-CAMPHORSULFONYLIMINE

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Preparation Products And Raw materials

Global( 88)Suppliers
Supplier Tel Email Country ProdList Advantage
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 52925 58
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29881 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
+8613580539051 joe@yuhengpharm.com CHINA 21142 58
HANGZHOU CLAP TECHNOLOGY CO.,LTD
86-571-88216897,88216896 13588875226 sales@hzclap.com CHINA 6312 58
BOC Sciences
16314854226; +16314854226 inquiry@bocsci.com United States 19741 58
Nextpeptide Inc
+86-0571-81612335 +8613336028439 sales@nextpeptide.com China 19908 58
changzhou huayang technology co., ltd
+8615250961469 2571773637@qq.com China 9725 58

View Lastest Price from (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine >=97.0% (T) pictures 2021-07-02 (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine >=97.0% (T)
127184-05-8
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE pictures 2019-07-06 (+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE
127184-05-8
US $1.00 / kg 1kg 95%-99% 10kg Career Henan Chemical Co
(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE (+)-3,3-DICHLORO-2,N-EPOXY-EXO-10,2-BORNANESULTAM 4H-4a,7-Methanooxazirino3,2-i2,1benzisothiazole, 8,8-dichlorotetrahydro-9,9-dimethyl-, 3,3-dioxide, (2R,4aS,7S,8aR)- (+)-[(8,8-DICHLOROCAMPHORYL)-SULFONYL]-OXAZIRIDINE 97+% [2R-(2α,4aα,7α,8aR*)]-8,8-Dichlorotetrahydro-9,9-diMethyl-4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-Dioxide (+)-(8,8-DichlorocaMphorylsulfonyl)oxaziridine >=97.0% (T) (4aS,7S,8aR)-8,8-dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide (1S,6R,8S)-7,7-dichloro-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione 8AR)-8 8-Dichlorocamphorylsulfonyl)oxaziri dine (+)-8 (4aS,7S)-8,8-Dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine 127184-05-8 C10H13Cl2NO3S Hydroxylation Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Heterocycles Miscellaneous Reagents