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4-(bromomethyl)benzaldehyde

CAS No.
51359-78-5
Chemical Name:
4-(bromomethyl)benzaldehyde
Synonyms
α-Bromo-p-Tolualdehyde;4-(BROMOMETHYL)BENZALDEHYDE;Benzaldehyde,4-(broMoMethyl)-;4-(Bromomethyl)benzaldehyde97%;4-(Bromomethyl)benzaldehyde 97%;4-Formylbenzyl bromide, alpha-Bromo-4-formyltoluene
CBNumber:
CB1708152
Molecular Formula:
C8H7BrO
Molecular Weight:
199.04
MDL Number:
MFCD08271963
MOL File:
51359-78-5.mol
Last updated:2024-07-29 17:23:31

4-(bromomethyl)benzaldehyde Properties

Melting point 99 °C
Boiling point 277.9±15.0 °C(Predicted)
Density 1.524±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystalline powder
color Pale lemon
CAS DataBase Reference 51359-78-5

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H314
Precautionary statements  P260-P280-P310
Hazard Codes  C
Safety Statements  24/25
Hazard Note  Corrosive
HS Code  29142990
NFPA 704
0
3 0

4-(bromomethyl)benzaldehyde price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC B694635 4-(Bromomethyl)benzaldehyde 51359-78-5 100mg $45 2021-12-16 Buy
Biosynth Carbosynth FB10749 4-(Bromomethyl)benzaldehyde 51359-78-5 100mg $50 2021-12-16 Buy
Biosynth Carbosynth FB10749 4-(Bromomethyl)benzaldehyde 51359-78-5 250mg $80 2021-12-16 Buy
Apolloscientific OR9193 4-(Bromomethyl)benzaldehyde 97% 51359-78-5 1g $87 2021-12-16 Buy
Biosynth Carbosynth FB10749 4-(Bromomethyl)benzaldehyde 51359-78-5 500mg $130 2021-12-16 Buy
Product number Packaging Price Buy
B694635 100mg $45 Buy
FB10749 100mg $50 Buy
FB10749 250mg $80 Buy
OR9193 1g $87 Buy
FB10749 500mg $130 Buy

4-(bromomethyl)benzaldehyde Chemical Properties,Uses,Production

Synthesis

4-(bromomethyl) benzonitrile (1 g, 5.1 mmol) was dissolved in 10 mL of dry toluene and cooled at 0 oC and a portion of 1.08 M DIBALH in hexane (2 equiv.) was added dropwise under nitrogen atmosphere. The solution was stirred for 1 h at 0 oC. The reaction mixture was first diluted with chloroform (15 mL) followed by 34 mL of 10% HCl, and the solution was stirred at room temperature for another 1 h. The organic layer separated was washed with distilled water and dried over anhydrous Na2SO4. The solvent was almost completely removed from the filtrate under reduced pressure, and the residue was washed with ice-cold n-hexane and dried at 50 oC under vacuum to afford 4-(bromomethyl)benzaldehyde. Yield: 70%; 1 H NMR (300 MHz, CDCl3, TMS): δ = 10.02 (s, 1H), 7.86 (m, 2H), 7.57 (m, 2H), 4.52 (s, 2H) ppm[1].

References

[1] Sandeep, Anjamkudy et al. “Supercoiled fibres of self-sorted donor–acceptor stacks: a turn-off/turn-on platform for sensing volatile aromatic compounds?.” Chemical Science 7 (2016): 4460–4467.

4-(bromomethyl)benzaldehyde Preparation Products And Raw materials

Global( 149)Suppliers
Supplier Tel Email Country ProdList Advantage
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View Lastest Price from 4-(bromomethyl)benzaldehyde manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-bromomethylbenzaldehyde pictures 2022-09-20 4-bromomethylbenzaldehyde
51359-78-5
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
4-(BROMOMETHYL)BENZALDEHYDE pictures 2019-12-27 4-(BROMOMETHYL)BENZALDEHYDE
51359-78-5
US $1.00 / KG 1KG 99% 200kg Career Henan Chemical Co

4-(bromomethyl)benzaldehyde Spectrum

4-(BROMOMETHYL)BENZALDEHYDE 4-(Bromomethyl)benzaldehyde 97% Benzaldehyde,4-(broMoMethyl)- 4-(Bromomethyl)benzaldehyde97% α-Bromo-p-Tolualdehyde 4-Formylbenzyl bromide, alpha-Bromo-4-formyltoluene 51359-78-5 pharmacetical Methyl Halides Phenyls & Phenyl-Het Methyl Halides Phenyls & Phenyl-Het