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4-aminonaphthalene-1,6-disulfonic acid

CAS No.
85-75-6
Chemical Name:
4-aminonaphthalene-1,6-disulfonic acid
Synonyms
Dahl's acid III;1-naphthylamine-4,7-disulfonic acid;4-aminonaphthalene-1,6-disulfonic acid;4-Amino-1,6-naphthalenedisulfonic acid;4-aminonaphthalene-1,6-disulphonic acid;4-azanylnaphthalene-1,6-disulfonic acid;1,6-Naphthalenedisulfonic acid, 4-amino-
CBNumber:
CB1875757
Molecular Formula:
C10H9NO6S2
Molecular Weight:
303.31
MDL Number:
MFCD00035723
MOL File:
85-75-6.mol
Last updated:2023-11-03 13:56:55

4-aminonaphthalene-1,6-disulfonic acid Properties

Boiling point 205.8°C (rough estimate)
Density 1.6329 (rough estimate)
refractive index 1.7330 (estimate)
FDA UNII PV5B6JDG9R
EPA Substance Registry System 1,6-Naphthalenedisulfonic acid, 4-amino- (85-75-6)

SAFETY

Risk and Safety Statements

RIDADR  1759
HazardClass  8
PackingGroup  III

4-aminonaphthalene-1,6-disulfonic acid Chemical Properties,Uses,Production

Description

1-Aminonaphthalene-4,7-disulfonic acid [85-75-6]. (4-aminonaphthalene-1,6-disulfonic acid), Dahl’s acid III, C10H9NO6S2, Mr 303.3, and its sodium salt are readily soluble in water, but the calcium and barium salts are only sparingly soluble. Conversion to 1-hydroxynaphthalene-4,7-disulfonic acid is achieved by reverse-Bucherer reaction or diazotization and hydrolysis. Sulfonation (35 % oleum, 90℃) yields 1-aminonaphthalene-2,4,7-trisulfonic acid.

Production Methods

?Although separation of 4-aminonaphthalene-1,6-disulfonic acid from the mixture obtained by sulfonation of naphthionic acid is not practicable on a large scale, the 1,4,7-isomer can be obtained directly in high yield by sulfonation of 1-aminonaphthalene-7-sulfonic acid with oleum.

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1-naphthylamine-4,7-disulfonic acid 4-aminonaphthalene-1,6-disulfonic acid 4-azanylnaphthalene-1,6-disulfonic acid 4-aminonaphthalene-1,6-disulphonic acid 4-Amino-1,6-naphthalenedisulfonic acid Dahl's acid III 1,6-Naphthalenedisulfonic acid, 4-amino- 85-75-6 85-76-6